Synthesis and photophysical characterization of novel triphenylamine-benzimidazole derivatives

Research on organic luminescent materials has been intensely pursued due to their importance in technological applications related to signaling, fluorescent biosensory/chemosensory materials, molecular switches and organic light emitting diodes (OLEDs). Organic fluorophores such as triphenylamine and benzimidazole derivatives have attracted a particular attention owing to their high emission efficiency being widely used as electron transporters and emitting layers for OLEDs.1 Recently, we have been investigating the potential of heterocyclic systems bearing functionalized (benz)imidazole derivatives exhibiting high thermal stability, interesting emissive and chemosensory properties.2 In this communication we report the synthesis and photophysical characterization of triphenylamine-benzimidazoles (compounds 1a-d) which were synthesized by a one step reaction through the Na2S2O4 reduction of several commercially available o-nitroanilines in the presence of triphenylamine aldehyde in DMSO at 120 °C. Compounds 1a-d bear different functionalization at position 5 of the benzimidazole with electron-donor or acceptor groups (Figure 1). A comprehensive spectral and photophysical investigation of these compounds including absorption, fluorescence and triplet-triplet absorption spectra, together with quantum yields of fluorescence, internal conversion, intersystem crossing and singlet oxygen and rate constants for the radiative and radiationless processes has been undertaken in solution at room temperature. It is shown that compounds 1a-d exhibit high fluorescence quantum yields (0.70-0.78). Additionally, a comparison between the optical and photophysical properties of 1a-d will be also presented and discussed.Fundação para a Ciência e a Tecnologia (FCT

Análise da produção brasileira de frutas a partir do armazém de dados da fruticultura.

Armazém de dados da fruticultura. Integração dos dados de produção de frutas. Análise da produção brasileira de frutas.bitstream/CNPTIA/9872/1/comuntec18_0.pd

Fluorescence Enhancement of the Water- Soluble Poly{1,4-phenylene-[9,9-bis- (4-phenoxybutylsulfonate)]fluorene-2,7-diyl} Copolymer in n-Dodecylpentaoxyethylene Glycol Ether Micelles

http://dx.doi.org/10.1021/ma048780

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O objetivo geral do Programa é elevar os padrões de qualidade e competitividade da fruticultura brasileira ao patamar de excelência requerido pelo mercado internacional, paradigma que será efetivado com o avanço da capacidade produtiva e gerencial dos produtores de frutas e a ampliação dos mercados interno e externo. São contempladas ações em diversas áreas, como inovação tecnológica, capacitação de fruticultores, controle de pragas na fruticultura, campanha para promoção das frutas brasileiras, entre outras.bitstream/CNPTIA/9175/1/COMNICADOTEC2.pd