Interpretation of photocurrent transients at semiconductor electrodes:Effects of band-edge unpinning

The transient photocurrent response of semiconductor electrodes to chopped illumination often shows spikes and overshoots that are usually interpreted as evidence that surface recombination is occurring. In the case of the high intensities used for light-driven water splitting, the interpretation is less straightforward since the electron transfer reactions are so slow that the minority carrier concentration at or near the surface increases to high values that modify the potential drop across the Helmholtz layer in the electrolyte, leading to ‘band edge unpinning’. In addition, changes in chemical composition of the surface or local changes in pH may also alter the potential distribution across the semiconductor/electrolyte junction. A quantitative theory of band edge unpinning due to minority carrier build up is presented, and numerical calculations of transient photocurrent responses are compared with experimental examples for n-type Fe2O3 and p-type lithium-doped CuO electrodes. It is shown that the apparently high reaction orders (up to third order) with respect to hole concentration reported for hematite photoanodes can be explained as arising from an acceleration of hole transfer by the increased voltage drop across the Helmholtz layer associated with band edge unpinning. The limitations of the band edge unpinning model are discussed considering additional effects associated with modification of the potential distribution brought about by light-induced changes in surface composition, surface dipoles and surface ionic charge.</p

Solvatochromic covalent organic frameworks.

Covalent organic frameworks (COFs) are an emerging class of highly tuneable crystalline, porous materials. Here we report the first COFs that change their electronic structure reversibly depending on the surrounding atmosphere. These COFs can act as solid-state supramolecular solvatochromic sensors that show a strong colour change when exposed to humidity or solvent vapours, dependent on vapour concentration and solvent polarity. The excellent accessibility of the pores in vertically oriented films results in ultrafast response times below 200 ms, outperforming commercially available humidity sensors by more than an order of magnitude. Employing a solvatochromic COF film as a vapour-sensitive light filter, we demonstrate a fast humidity sensor with full reversibility and stability over at least 4000 cycles. Considering their immense chemical diversity and modular design, COFs with fine-tuned solvatochromic properties could broaden the range of possible applications for these materials in sensing and optoelectronics

First Observation of barB0 to D*0 pi+pi+pi-pi- Decays

We report on the observation of B0bar -> D*0 pi+ pi+ pi- pi- decays. The branching ratio is (0.30 +/- 0.07 +/- 0.06)%. Interest in this particular mode was sparked by Ligeti, Luke and Wise who propose it as a way to check the validity of factorization tests in B0bar -> D*+ pi+ pi- pi- pi0 decays.Comment: 11 pages postscript, also available through http://w4.lns.cornell.edu/public/CLNS, Version to appear in Phys. Rev.

A Search for Charmless B→VVB\to VV Decays

We have studied two-body charmless decays of the $B$ meson into the final states $\rho^0 \rho^0$, $K^{*0} \rho^0$, $K^{*0} K^{*0}$, $K^{*0} \bar{K^{*0}}$, $K^{*+} \rho^0$, $K^{*+} \bar{K^{*0}}$, and $K^{*+} K^{*-}$ using only decay modes with charged daughter particles. Using 9.7 million $B \bar{B}$ pairs collected with the CLEO detector, we place 90% confidence level upper limits on the branching fractions, $(0.46-7.0)\times 10^{-5}$, depending on final state and polarization.Comment: 8 pages postscript, also available through http://w4.lns.cornell.edu/public/CLN

Measurements of the Branching Fractions and Helicity Amplitudes in B --> D* rho Decays

Using 9.1 fb-1 of e+ e- data collected at the Upsilon(4S) with the CLEO detector using the Cornell Electron Storage Ring, measurements are reported for both the branching fractions and the helicity amplitudes for the decays B- -> D*0 rho- and B0bar -> D*+ rho-. The fraction of longitudinal polarization in B0bar -> D*+ rho- is found to be consistent with that in B0bar -> D*+ l- nubar at q^2 = M^2_rho, indicating that the factorization approximation works well. The longitudinal polarization in the B- mode is similar. The measurements also show evidence of non-trivial final-state interaction phases for the helicity amplitudes.Comment: 11 pages postscript, also available through http://w4.lns.cornell.edu/public/CLNS, submitted to PR

Correlated /\c-/\cbar production in e+e- annihilations at sqrt{s}~10.5 GeV

Using 13.6/fb of continuum two-jet e+e- -> ccbar events collected with the CLEO detector, we have searched for baryon number correlations at the primary quark level. We have measured the likelihood for a /\c+ charmed baryon to be produced in the hemisphere opposite a /\c- relative to the likelihood for a /\c+ charmed baryon to be produced opposite an anticharmed meson Dbar; in all cases, the reconstructed hadrons must have momentum greater than 2.3 GeV/c. We find that, given a /\c- (reconstructed in five different decay modes), a /\c+ is observed in the opposite hemisphere (0.72+/-0.11)% of the time (not corrected for efficiency). By contrast, given a Dbar in one hemisphere, a /\c+ is observed in the opposite hemisphere only (0.21+/-0.02)% of the time. Normalized to the total number of either /\c- or Dbar ``tags'', it is therefore 3.52+/-0.45+/-0.42 times more likely to find a /\c+ opposite a /\c- than a Dbar meson. This enhancement is not observed in the JETSET 7.3 e+e- -> ccbar Monte Carlo simulation.Comment: 19 pages, Latex, one figure separat

Bounds on the CP Asymmetry in Like-Sign Dileptons from B0Bˉ0B^{0}\bar{B}^{0} Meson Decays

We have measured the charge asymmetry in like-sign dilepton yields from B^0 B^0-bar meson decays using the CLEO detector at the Cornell Electron Storage Ring. We find a_ll = [N(l+l+) - N(l-l-)]/[N(l+l+) + N[l-l-)] = +0.013 +/- 0.050 +/- 0.005 . We combine this result with a previous, independent measurement and obtain Re(epsilon_B)/(1+|epsilon_B|^2) = +0.0035 +/- 0.0103 +/- 0.0015 (uncertainties are statistical and systematic, respectively) for the CP impurity parameter, epsilon_B.Comment: 11 pages postscript, also available through http://w4.lns.cornell.edu/public/CLN

Rate Measurement of D0→K+π−π0D^{0}\to K^{+}\pi^{-}\pi^{0} and Constraints on D0−D0‾D^{0} - \overline{D^{0}} Mixing

We present an observation and rate measurement of the decay D0 -> K+pi-pi0 produced in 9/fb of e+e- collisions near the Upsilon(4S) resonance. The signal is inconsistent with an upward fluctuation of the background by 4.9 standard deviations. We measured the rate of D0 -> K+pi-pi0 normalized to the rate of D0bar -> K+pi-pi0 to be 0.0043 +0.0011 -0.0010 (stat) +/- 0.0007 (syst). This decay can be produced by doubly-Cabibbo-suppressed decays or by the D0 evolving into a D0bar through mixing, followed by a Cabibbo-favored decay to K+pi-pi0. We also found the CP asymmetry A=(8 +25 -22)% to be consistent with zero.Comment: 10 pages postscript, also available through http://w4.lns.cornell.edu/public/CLN

Measurement of Inclusive B --> psi Production

Using the combined CLEO II and CLEO II.V data sets of 9.1 fb^{-1} at the Upsilon(4S), we measure properties of Psi mesons produced directly from decays of the B meson, where ``B'' denotes an admixture of B+, B-, B0, and B0bar, and ``Psi'' denotes either J/Psi or Psi(2S). We report first measurements of Psi polarization in B -> Psi(direct) X: alpha(J/Psi) = -0.30 {+0.07 -0.06 stat} {+-0.04 syst} and alpha(Psi(2S)) = -0.45 {+0.22 -0.19 stat} {+-0.04 syst}. We also report improved measurements of the momentum distributions of Psi produced directly from B decays, correcting for measurement smearing. Finally, we report measurements of the inclusive branching fraction for B -> Psi X and B -> Chi_c1 X.Comment: 8 pages postscript, also available through http://w4.lns.cornell.edu/public/CLNS, submitted to PR

Study of Charmless Hadronic B Meson Decays to Pseudoscalar-Vector Final States

We report results of searches for charmless hadronic B meson decays to pseudoscalar(pi^+-,K^+-,Pi^0 or Ks^0)-vector(Rho, K* or Omega) final states. Using 9.7 million BBbar pairs collected with the CLEO detector, we report first observation of B^- --> Pi^-Rho^0, B^0 --> Pi^+-Rho^-+ and B^- --> Pi^-Omega, which are expected to be dominated by hadronic b --> u transitions. The measured branching fractions are (10.4+3.3-3.4+-2.1)x10^-6, (27.6+8.4-7.4+-4.2)x10^-6 and (11.3+3.3-2.9+-1.4)x10^-6, respectively. Branching fraction upper limits are set for all the other decay modes investigated.Comment: 10 pages postscript, also available through http://w4.lns.cornell.edu/public/CLN