Controlled Formation of Polyamine Crystalline Layers on Glass Surfaces and Successive Fabrication of Hierarchically Structured Silica Thin Films

The formation of silica films on the glass plate whose surface was precoated by crystalline linear poly(ethylenimine) (LPEI) in advance was systematically investigated via controlling the surface-specific crystallization of the LPEI on the glass plate. Immersing glass substrates into a hot aqueous solution of LPEI containing additives such as transition metal ions and acidic compounds and retaining them on 30 °C for desired periods resulted in the formation of crystalline LPEI layers on the substrates. Subsequently dipping this LPEI-coated glass into silica source solutions afforded successfully hierarchically structured silica film which coated continuously the surface of the substrates. In this two-step process, we found that the formation of hierarchically structured silica films strongly depended on the LPEI layer formed from the LPEI aqueous solutions containing different additives. The LPEI layer formed by changing the kinds of additives and their concentrations provides the differently structured silica films composed of turbine-like structures flatly lying-on and/or vertically standing-on as well as ribbon network structures on the surface of the substrates. Moreover, we functionalized these silica films by the introduction of hydrophobic alkyl chains or emissive Eu(III) complexes and investigated their wettability and emission properties

Lipid-Packaged Linear Iron(II) Triazole Complexes in Solution: Controlled Spin Conversion via Solvophobic Self-Assembly

Lipid-Packaged Linear Iron(II) Triazole Complexes in Solution: Controlled Spin Conversion via Solvophobic Self-Assembl

Exploring the Impact of Linkage Structure in Ferroelectric Nematic and Smectic Liquid Crystals

The liquid crystal molecule 3-fluoro-4-(3,4,5-trifluorophenyl)phenyl 2,6-difluoro-4-(trans-5-n-propyl-1,3-dioxane-2-yl)benzoate (DIO) has attracted considerable interest owing to its unique ferroelectric nematic phase and extraordinarily high dielectric constant. To expand the DIO series, novel analogs with 1,3-dioxane units converted to ester units (EST analogs) were synthesized, and their physical properties were characterized. The EST analogs exhibited ferroelectric phases similar to those of the corresponding DIO analogs. Interestingly, an EST analogue featuring a defluorinated benzoate unit exhibited a ferroelectric smectic A phase, despite its smaller longitudinal dipole moment of 6.9 D. This result diverges from the common knowledge that the formation of large longitudinal dipoles is traditionally effective in the emergence of ferroelectric phases. Unlike the DIO series, the EST analogs can be readily obtained without the formation of undesired geometric isomers, which is advantageous for practical applications. The results of this study provide valuable insights into the design of liquid-crystalline materials expressing ferroelectric phases