Datação U-Pb, sistemática isotópica Lu-Hf e química de zircão do metatraquidacito do Morro do Polvilho: contribuição para fonte do magmatismo e para a idade deposicional do Grupo São Roque

Este trabalho apresenta novos dados geocronológicos in situ das rochas metavulcânicas ácidas da sequência inferior do Grupo São Roque, São Paulo, Brasil, confirmando que esta é mais jovem que as rochas metamórficas de mais alto grau do Grupo Serra do Itaberaba. A idade do metatraquidacito do Morro do Polvilho foi estabelecida em 1760 ± 17 Ma, com resultados sugerindo que o vulcanismo bimodal da formação Boturuna teve magma parental proveniente de uma crosta continental antiga (Arqueana a Paleoproterozoica), que foi gerado em ambiente intraplaca. A química de elementos-traço em zircão sugere semelhanças com magmas de alta temperatura (T Zrsat = 900-915ºC) como a de granitos do tipo-A (pronunciada EuN/EuN* negativa e moderada CeN/CeN* positiva), provenientes de fontes continentais geradas em condições redutoras.We present new in situ geochronological data of controversial silicic metavolcanic rocks from the lower terrigenous-metavolcanic sequence of the São Roque Group, Ribeira Belt, confirming that they are older than the rocks of higher-metamorphic grade sequences of the Serra do Itaberaba Group. The age of the Polvilho meta-trachydacite was established at 1760 ± 17 Ma, furthermore the results suggest that the bi-modal volcanism of the Boturuna Formation has parent melts from an old (Archean to Paleoproterozoic) continental crust that was melted in a within-plate environment. Trace-element chemistry of zircon, suggests similarities with high-temperature melts (T Zrsat = 900–915ºC) similar to A-type granites (high negative EuN/EuN* and moderate positive CeN/CeN*) from continental sources under reducing conditions

Gestão ambiental e desagregação das relações intergovernamentais no Brasil: dos desencontros normativos à necessária pactuação federativa

O presente estudo busca estudar a relação entre o perfil institucional do atual arranjo federativo brasileiro e a gestão fiscal ambiental dos municípios da região Nordeste. Percorre-se, dessa forma, a discussão sobre as concepções de centralização e descentralização na teoria federativa, investigando-se como e como isso impacta na gestão fiscal ambiental dos entes municipais. A pesquisa traz uma análise descritiva de dados secundários sobre as transferências voluntárias de natureza ambiental entre os entes federativos. As análises demonstram um baixo índice de integração entre os diferentes níveis de governo, sendo a autonomia institucional concentrada nos níveis estadual e federal, enquanto a incu

Paleoproterozoic source contributions to the São Roque Group sedimentation: LA-MC-ICPMS U-Pb dating and Sm-Nd systematics of clasts from metaconglomerates of the Boturuna Formation

The São Roque Group is characterized by volcano-sedimentary sequences, in which deposition probably started in the late Paleoproterozoic. U-Pb dating by LA-MC-ICPMS of zircons extracted from predominantly equigranular monzogranites clasts from Morro Doce and Morro do Polvilho regions, yield paleoproterozoic ages of 2199 ± 8.5 Ma and 2247 ± 13 Ma, respectively. These represent the ages for the main source of granite for the metaconglomerates from the Boturuna Formation (basal unit of São Roque Group). Its polycyclic history is reinforced by the presence of inherited Archean zircons (2694 ± 29 Ma) found within the clasts. Moreover, these clasts have also been affected by the Neoproterozoic overprinting event as indicated by their lower intercept Concordia ages. Sm-Nd isotope data for the main clast varieties from the Morro Doce metaconglomerates yield T DM ages of 2.6 to 2.7 Ga, demonstrating that these granites are the recycling products of an Archean crustal component. The metaconglomerate arkosean framework yields slightly lower εNd(t) values than those for the clasts, indicating that a younger and/or more primitive source also contributed to the Boturuna Formation.O Grupo São Roque é caracterizado por uma sequência vulcanossedimentar com deposição provavelmente iniciada no Paleoproterozoico tardio. Datações U-Pb obtidas por LA-MC-ICPMS de zircões extraídos das variedades predominantes dos clastos de monzogranitos equigranulares, das regiões do Morro Doce e Morro do Polvilho, mostram idades paleoproterozoicas de 2199 ± 8,5 Ma e 2247 ± 13 Ma, respectivamente. Estas representam as idades da principal fonte de granito da Formação Boturuna (unidade basal do Grupo São Roque). A história policíclica deste domínio é reforçada pela presença de zircões arqueanos herdados (2694 ± 29 Ma), encontrados nos clastos. Além disso, tais clastos também foram afetados pelo evento Neoproterozoico, conforme indicado pelo intercepto inferior das idades concórdia. Dados isotópicos Sm-Nd para os principais clastos do metaconglomerado do Morro Doce têm idades T DM entre 2,6 a 2,7 Ga, demonstrando que estes granitos são produtos da reciclagem de um componente crustal arqueano. O arcabouço dos metaconglomerados, quando comparado com os clastos, mostra valores mais baixos de εNd(t), indicando contribuições de fontes mais jovens e/ou primitivas para a Formação Boturuna

Characterization of Buriti (Mauritia flexuosa) Foam for Thermal Insulation and Sound Absorption Applications in Buildings

Exploring new construction materials with low environmental impact leads to innovation in buildings and also to the expansion of environmental sustainability in the construction industry. In this perspective, the thermal insulation and the sound absorption performances of Buriti (Mauritia flexuosa) foam were analyzed for potential application in buildings. This material is of plant origin, it is natural, renewable, abundant, and has a low environmental impact. In this research, characterizations were made by scanning electron microscopy (SEM), apparent density, thermogravimetry (TGA and DTG), thermal conductivity, and sound absorption. The SEM analysis revealed a predominantly porous, small, and closed-cell morphology in the vegetable foam. Due to its porosity and lightness, the material has an apparent density similar to other thermal insulating and sound-absorbing materials used commercially. The evaluation of thermogravimetric (TGA/DTG) results demonstrated thermal stability at temperatures that attest to the use of Buriti foam as a building material. Based on the thermal conductivity test, the Buriti foam was characterized as an insulating material comparable to conventional thermal insulation materials and in the same range as other existing thermal insulators of plant origin. Concerning sound absorption, the Buriti foam presented a low performance in the analyzed frequency range, mainly attributed to the absence of open porosity in the material. Therefore, understanding the sound absorption mechanisms of Buriti foam requires further studies exploring additional ways of processing the material

Effect of Different Numbers of Interset Antagonist Proprioceptive Neuromuscular Facilitation Stretching on the Total Number of Repetitions for the Agonists

International Journal of Exercise Science 15(4): 498-506, 2022. Recent studies have observed that stretching applied to antagonist muscles can promote improvement in agonist muscle performance. The purpose of this study was to investigate the effect of different numbers of interset proprioceptive neuromuscular facilitation (PNF) stretching for the antagonists on the total number of repetitions completed for the agonists (quadriceps) in the leg extension exercise. Fourteen physically active individuals (age: 29.35 ± 10.5 years; body mass: 79.1 ± 11.34 kg; height: 170.4 ± 8.7 cm) participated in this study. The following experimental protocols were performed: 1) Traditional protocol (Traditional) – without previous stretching; 2) PNF with lesser duration (PNF1—3 sets of 20 secs.); 3) PNF with greater duration (PNF2—3 sets of 30 secs.). Within the experimental protocols (PNF1 and PNF2), stretching exercises for the antagonists were performed before and between the four sets of the unilateral leg extension exercise. All tests were performed on the dominant limb only. The results showed that there was a significant difference in the total number of repetitions for the PNF2 protocol versus the Traditional protocol (p = 0.026). However, there was no significant difference between the PNF1 protocol versus the Traditional protocol (p = 0.577). In conclusion, in the leg extension exercise, an extended duration of interset PNF stretching for the hamstrings, promoted greater contractile performance for the quadriceps as demonstrated by significantly greater total repetitions over four sets

Paleoproterozoic source contributions to the São Roque Group sedimentation: LA-MC-ICPMS U-Pb dating and Sm-Nd systematics of clasts from metaconglomerates of the Boturuna Formation

The So Roque Group is characterized by volcano-sedimentary sequences, in which deposition probably started in the late Paleoproterozoic. U-Pb dating by LA-MC-ICPMS of zircons extracted from predominantly equigranular monzogranites clasts from Morro Doce and Morro do Polvilho regions, yield paleoproterozoic ages of 2199 8.5 Ma and 2247 13 Ma, respectively. These represent the ages for the main source of granite for the metaconglomerates from the Boturuna Formation (basal unit of So Roque Group). Its polycyclic history is reinforced by the presence of inherited Archean zircons (2694 29 Ma) found within the clasts. Moreover, these clasts have also been affected by the Neoproterozoic overprinting event as indicated by their lower intercept Concordia ages. Sm-Nd isotope data for the main clast varieties from the Morro Doce metaconglomerates yield TDM ages of 2.6 to 2.7 Ga, demonstrating that these granites are the recycling products of an Archean crustal component. The metaconglomerate arkosean framework yields slightly lower ENd(t) values than those for the clasts, indicating that a younger and/or more primitive source also contributed to the Boturuna Formation

Rehabilitative treatment of cleft lip and palate: experience of the Hospital for Rehabilitation of Craniofacial Anomalies - USP (HRAC-USP) - Part 2: Pediatric Dentistry and Orthodontics

The aim of this article is to present the pediatric dentistry and orthodontic treatment protocol of rehabilitation of cleft lip and palate patients performed at the Hospital for Rehabilitation of Craniofacial Anomalies - University of São Paulo (HRAC-USP). Pediatric dentistry provides oral health information and should be able to follow the child with cleft lip and palate since the first months of life until establishment of the mixed dentition, craniofacial growth and dentition development. Orthodontic intervention starts in the mixed dentition, at 8-9 years of age, for preparing the maxillary arch for secondary bone graft procedure (SBGP). At this stage, rapid maxillary expansion is performed and a fixed palatal retainer is delivered before SBGP. When the permanent dentition is completed, comprehensive orthodontic treatment is initiated aiming tooth alignment and space closure. Maxillary permanent canines are commonly moved mesially in order to substitute absent maxillary lateral incisors. Patients with complete cleft lip and palate and poor midface growth will require orthognatic surgery for reaching adequate anteroposterior interarch relationship and good facial esthetics

Brain zinc chelation by diethyldithiocarbamate increased the behavioral and mitochondrial damages in zebrafish subjected to hypoxia

The increase in brain levels of chelatable zinc (Zn) in dysfunctions involving oxygen deprivation has stimulated the treatment with Zn chelators, such as diethyldithiocarbamate (DEDTC). However, DEDTC is a redox-active compound and it should be better evaluated during hypoxia. We use the hypoxia model in zebrafish to evaluate DEDTC effects. The exploratory behavior, chelatable Zn content, activities of mitochondrial dehydrogenases, reactive species levels (nitric oxide, superoxide anion, hydroxyl radical scavenger capacity) and cellular antioxidants (sulfhydryl, superoxide dismutase) of zebrafish brain were assessed after recovery, with or without 0.2mM DEDTC. The increased brain levels of chelatable Zn induced by hypoxia were mitigated by DEDTC. However, the novel tank task indicated that DEDTC did further enhance the exploratory deficit caused by hypoxia. Furthermore, these behavioral impairments caused by DEDTC were more associated with a negative action on mitochondrial activity and brain oxidative balance. Thus, due to apparent pro-oxidant action of DEDTC, our data do not support its use for neuroprotection in neuropathologies involving oxygen deprivation

Transcriptomic analysis of changes in gene expression during flowering induction in sugarcane under controlled photoperiodic conditions

Flowering is of utmost relevance for the agricultural productivity of the sugarcane bioeconomy, but data and knowledge of the genetic mechanisms underlying its photoperiodic induction are still scarce. An understanding of the molecular mechanisms that regulate the transition from vegetative to reproductive growth in sugarcane could provide better control of flowering for breeding. This study aimed to investigate the transcriptome of +1 mature leaves of a sugarcane cultivar subjected to florally inductive and non-inductive photoperiodic treatments to identify gene expression patterns and molecular regulatory modules. We identified 7,083 differentially expressed (DE) genes, of which 5,623 showed significant identity to other plant genes. Functional group analysis showed differential regulation of important metabolic pathways involved in plant development, such as plant hormones (i.e., cytokinin, gibberellin, and abscisic acid), light reactions, and photorespiration. Gene ontology enrichment analysis revealed evidence of upregulated processes and functions related to the response to abiotic stress, photoprotection, photosynthesis, light harvesting, and pigment biosynthesis, whereas important categories related to growth and vegetative development of plants, such as plant organ morphogenesis, shoot system development, macromolecule metabolic process, and lignin biosynthesis, were downregulated. Also, out of 76 sugarcane transcripts considered putative orthologs to flowering genes from other plants (such as Arabidopsis thaliana, Oryza sativa, and Sorghum bicolor), 21 transcripts were DE. Nine DE genes related to flowering and response to photoperiod were analyzed either at mature or spindle leaves at two development stages corresponding to the early stage of induction and inflorescence primordia formation. Finally, we report a set of flowering-induced long non-coding RNAs and describe their level of conservation to other crops, many of which showed expression patterns correlated against those in the functionally grouped gene network

Rehabilitative treatment of cleft lip and palate: experience of the Hospital for Rehabilitation of Craniofacial Anomalies - USP (HRAC-USP) - part 3: Oral and Maxillofacial Surgery

This paper presents the treatment protocol of maxillofacial surgery in the rehabilitation process of cleft lip and palate patients adopted at HRAC-USP. Maxillofacial surgeons are responsible for the accomplishment of two main procedures, alveolar bone graft surgery and orthognathic surgery. The primary objective of alveolar bone graft is to provide bone tissue for the cleft site and then allow orthodontic movements for the establishment of an an adequate occlusion. When performed before the eruption of the maxillary permanent canine, it presents high rates of success. Orthognathic surgery aims at correcting maxillomandibular discrepancies, especially anteroposterior maxillary deficiencies, commonly observed in cleft lip and palate patients, for the achievement of a functional occlusion combined with a balanced face