15 research outputs found

    Janus Polymer Single Crystal Nanosheet via Evaporative Crystallization

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    We show that liquid/liquid interface can guide polymer chain folding during crystallization. Evaporation-induced crystallization of telechelic dicarboxyl end-functionalized poly­(ε-caprolactone) (COOH-PCL-COOH) at a water/pentyl acetate interface produced millimeter-scale, uniform polymer single crystal (PSC) films. Due to the asymmetric nature at the interface, the PSC nanosheets exhibited a Janus structure: the two surfaces of the crystal showed distinct water contact angle, which are quantitatively confirmed by in situ nanocondensation using environmental scanning electron microscopy (ESEM)

    Deep Color-Corrected Multi-scale Retinex Network for Underwater Image Enhancement

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    The acquisition of high-quality underwater images is of great importance to ocean exploration activities. However, images captured in the underwater environment often suffer from degradation due to complex imaging conditions, leading to various issues, such as color cast, low contrast and low visibility. Although many traditional methods have been used to address these issues, they usually lack robustness in diverse underwater scenes. On the other hand, deep learning techniques struggle to generalize to unseen images, due to the challenge of learning the complicated degradation process. Inspired by the success achieved by the Retinex-based methods, we decompose the Underwater Image Enhancement (UIE) task into two consecutive procedures, including color correction and visibility enhancement, and introduce a novel deep Color-Corrected Multi-scale Retinex Network (CCMSR-Net). With regard to the two procedures, this network comprises a Color Correction subnetwork (CC-Net) and a Multi-scale Retinex subnetwork (MSR-Net), which are built on top of the Hybrid Convolution-Axial Attention Block (HCAAB) that we design. Thanks to this block, the CCMSR-Net is able to efficiently capture local characteristics and the global context. Experimental results show that the CCMSR-Net outperforms, or at least performs comparably to, 11 baselines across five test sets. We believe that these promising results are due to the effective combination of color correction methods and the multi-scale Retinex model, achieved by jointly exploiting Convolutional Neural Networks (CNNs) and Transformers.</p

    In Situ Real-Time Study on Dynamics of Microbially Induced Calcium Carbonate Precipitation at a Single-Cell Level

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    Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by <i>Sporosarcina pasteurii</i> were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation

    In Situ Real-Time Study on Dynamics of Microbially Induced Calcium Carbonate Precipitation at a Single-Cell Level

    No full text
    Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by <i>Sporosarcina pasteurii</i> were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation

    In Situ Real-Time Study on Dynamics of Microbially Induced Calcium Carbonate Precipitation at a Single-Cell Level

    No full text
    Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by <i>Sporosarcina pasteurii</i> were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation

    In Situ Real-Time Study on Dynamics of Microbially Induced Calcium Carbonate Precipitation at a Single-Cell Level

    No full text
    Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by <i>Sporosarcina pasteurii</i> were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation

    In Situ Real-Time Study on Dynamics of Microbially Induced Calcium Carbonate Precipitation at a Single-Cell Level

    No full text
    Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by <i>Sporosarcina pasteurii</i> were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation

    In Situ Real-Time Study on Dynamics of Microbially Induced Calcium Carbonate Precipitation at a Single-Cell Level

    No full text
    Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by <i>Sporosarcina pasteurii</i> were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation

    Responsive Shape Change of Sub‑5 nm Thin, Janus Polymer Nanoplates

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    Responsive shape changes in soft materials have attracted significant attention in recent years. Despite extensive studies, it is still challenging to prepare nanoscale assemblies with responsive behaviors. Herein we report on the fabrication and pH-responsive properties of sub-5 nm thin, Janus polymer nanoplates prepared via crystallization-driven self-assembly of poly­(ε-caprolactone)-<i>b</i>-poly­(acrylic acid) (PCL-<i>b</i>-PAA) followed by cross-linking and disassembly. The resultant Janus nanoplate is comprised of partially cross-linked PAA and tethered PCL brush layers with an overall thickness of ∼4 nm. We show that pronounced and reversible shape changes from nanoplates to nanobowls can be realized in such a thin free-standing film. This shape change is achieved by exceptionally small stressa few orders of magnitude smaller than conventional hydrogel bilayers. These three-dimensional ultrathin nanobowls are also mechanically stable, which is attributed to the tortoise-shell-like crystalline domains formed in the nanoconfined curved space. Our results pave a way to a new class of free-standing, ultrathin polymer Janus nanoplates that may find applications in nanomotors and nanoactuators

    Structure and Morphology of Poly(vinylidene fluoride) Nanoscrolls

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    To date the scrolled morphology of γ-phase poly­(vinylidene fluoride) (PVDF) has been witnessed via high temperature melt crystallization of crystalline thin films and through imaging of chemical etched PVDF bulk films. Here we show the first growth and characterization of free-standing γ-phase PVDF scrolls via solution crystallization. Scanning electron microscopy, transmission electron microscopy, and atomic force microscopy have been used to characterize and to further understand the fundamental preferred crystalline habit of the γ-phase of PVDF
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