Molecular Simulation of MoS2 Exfoliation.

A wide variety of two-dimensional layered materials are synthesized by liquid-phase exfoliation. Here we examine exfoliation of MoS2 into nanosheets in a mixture of water and isopropanol (IPA) containing cavitation bubbles. Using force fields optimized with experimental data on interfacial energies between MoS2 and the solvent, multimillion-atom molecular dynamics simulations are performed in conjunction with experiments to examine shock-induced collapse of cavitation bubbles and the resulting exfoliation of MoS2. The collapse of cavitation bubbles generates high-speed nanojets and shock waves in the solvent. Large shear stresses due to the nanojet impact on MoS2 surfaces initiate exfoliation, and shock waves reflected from MoS2 surfaces enhance exfoliation. Structural correlations in the solvent indicate that shock induces an ice VII like motif in the first solvation shell of water

Multiple Unpinned Dirac Points in Group-Va Single-layers with Phosphorene Structure

Emergent Dirac fermion states underlie many intriguing properties of graphene, and the search for them constitute one strong motivation to explore two-dimensional (2D) allotropes of other elements. Phosphorene, the ultrathin layers of black phosphorous, has been a subject of intense investigations recently, and it was found that other group-Va elements could also form 2D layers with similar puckered lattice structure. Here, by a close examination of their electronic band structure evolution, we discover two types of Dirac fermion states emerging in the low-energy spectrum. One pair of (type-I) Dirac points is sitting on high-symmetry lines, while two pairs of (type-II) Dirac points are located at generic $k$-points, with different anisotropic dispersions determined by the reduced symmetries at their locations. Such fully-unpinned (type-II) 2D Dirac points are discovered for the first time. In the absence of spin-orbit coupling, we find that each Dirac node is protected by the sublattice symmetry from gap opening, which is in turn ensured by any one of three point group symmetries. The spin-orbit coupling generally gaps the Dirac nodes, and for the type-I case, this drives the system into a quantum spin Hall insulator phase. We suggest possible ways to realize the unpinned Dirac points in strained phosphorene.Comment: 30 pages, 6 figure

Analysis of Long-Term Water Level Variations in Qinghai Lake in China

Qinghai Lake is the largest inland saline lake on the Tibetan Plateau. Climate change and catchment modifications induced by human activities are the main drivers playing a significant role in the dramatic variation of water levels in the lake (Δh); hence, it is crucial to provide a better understanding of the impacts caused by these phenomena. However, their respective contribution to and influence on water level variations in Qinghai Lake are still unclear and without characterizing them, targeted measures for a more efficient conservation and management of the lake cannot be implemented. In this paper, data monitored during the period 1960–2016 (e.g., meteorological and land use data) have been analyzed by applying multiple techniques to fill this gap and estimate the contribution of each parameter recorded to water level variations (Δh). Results obtained have demonstrated that the water level of Qinghai Lake declined between 1960 and 2004, and since then has risen continuously and gradually, due to the changes in evaporation rates, precipitation and consequently surface runoff associated with climate change effects and catchment modifications. The authors have also pinpointed that climate change is the main leading cause impacting the water level in Qinghai Lake because results demonstrated that 93.13% of water level variations can be attributable to it, while the catchment modifications are responsible for 6.87%. This is a very important outcome in the view of the fact that global warming clearly had a profound impact in this sensitive and responsive region, affecting hydrological processes in the largest inland lake of the Tibetan Plateau

Ultraquantum magnetoresistance in Kramers Weyl semimetal candidate β\beta-Ag2Se

The topological semimetal $\beta$-Ag2Se features a Kramers Weyl node at the origin in momentum space and a quadruplet of spinless Weyl nodes, which are annihilated by spin-orbit coupling. We show that single crystalline $\beta$-Ag2Se manifests giant Shubnikov-de Haas oscillations in the longitudinal magnetoresistance which stem from a small electron pocket that can be driven beyond the quantum limit by a field less than 9 T. This small electron pocket is a remainder of the spin-orbit annihilatedWeyl nodes and thus encloses a Berry-phase structure. Moreover, we observed a negative longitudinal magnetoresistance when the magnetic field is beyond the quantum limit. Our experimental findings are complemented by thorough theoretical band structure analyses of this Kramers Weyl semimetal candidate, including first-principle calculations and an effective k*p model.Comment: A new version based on arXiv:1502.0232

Energy and Spectral Efficient Wireless Communications

Energy and spectrum are two precious commodities for wireless communications. How to improve the energy and spectrum efficiency has become two critical issues for the designs of wireless communication systems. This dissertation is devoted to the development of energy and spectral efficient wireless communications. The developed techniques can be applied to a wide range of wireless communication systems, such as wireless sensor network (WSN) designed for structure health monitoring (SHM), medium access control (MAC) for multi-user systems, and cooperative spectrum sensing in cognitive radio systems. First, to improve the energy efficiency in SHM WSN, a new ultra low power (ULP) WSN is proposed to monitor the vibration properties of structures such as buildings, bridges, and the wings and bodies of aircrafts. The new scheme integrates energy harvesting, data sensing, and wireless communication into a unified process, and it achieves significant energy savings compared to existing WSNs. Second, a cross-layer collision tolerant (CT) MAC scheme is proposed to improve energy and spectral efficiency in a multi-user system with shared medium. When two users transmit simultaneously over a shared medium, a collision happens at the receiver. Conventional MAC schemes will discard the collided signals, which result in a waste of the precious energy and spectrum resources. In our proposed CT-MAC scheme, each user transmits multiple weighted replicas of a packet at randomly selected data slots in a frame, and the indices of the selected slots are transmitted in a special collision-free position slot at the beginning of each frame. Collisions of the data slots in the MAC layer are resolved by using multiuser detection (MUD) in the PHY layer. Compared to existing schemes, the proposed CT-MAC scheme can support more simultaneous users with a higher throughput. Third, a new cooperative spectrum sensing scheme is proposed to improve the energy and spectral efficiency of a cognitive radio network. A new Slepian-Wolf coded cooperation scheme is proposed for a cognitive radio network with two secondary users (SUs) performing cooperative spectrum sensing through a fusion center (FC). The proposed scheme can achieve significant performance gains compared to existing schemes

Comparative genomic analyses of Mycoplasma hyopneumoniae pathogenic 168 strain and its high-passaged attenuated strain

Background: Mycoplasma hyopneumoniae is the causative agent of porcine enzootic pneumonia (EP), a mild, chronic pneumonia of swine. Despite presenting with low direct mortality, EP is responsible for major economic losses in the pig industry. To identify the virulence-associated determinants of M. hyopneumoniae, we determined the whole genome sequence of M. hyopneumoniae strain 168 and its attenuated high-passage strain 168-L and carried out comparative genomic analyses. Results: We performed the first comprehensive analysis of M. hyopneumoniae strain 168 and its attenuated strain and made a preliminary survey of coding sequences (CDSs) that may be related to virulence. The 168-L genome has a highly similar gene content and order to that of 168, but is 4,483 bp smaller because there are 60 insertions and 43 deletions in 168-L. Besides these indels, 227 single nucleotide variations (SNVs) were identified. We further investigated the variants that affected CDSs, and compared them to reported virulence determinants. Notably, almost all of the reported virulence determinants are included in these variants affected CDSs. In addition to variations previously described in mycoplasma adhesins (P97, P102, P146, P159, P216, and LppT), cell envelope proteins (P95), cell surface antigens (P36), secreted proteins and chaperone protein (DnaK), mutations in genes related to metabolism and growth may also contribute to the attenuated virulence in 168-L. Furthermore, many mutations were located in the previously described repeat motif, which may be of primary importance for virulence. Conclusions: We studied the virulence attenuation mechanism of M. hyopneumoniae by comparative genomic analysis of virulent strain 168 and its attenuated high-passage strain 168-L. Our findings provide a preliminary survey of CDSs that may be related to virulence. While these include reported virulence-related genes, other novel virulence determinants were also detected. This new information will form the foundation of future investigations into the pathogenesis of M. hyopneumoniae and facilitate the design of new vaccines