1,066 research outputs found
Mechanical behaviour with temperatures of aluminum matrix composites with CNTs
Aluminum is a very useful structural metal employed in different industrial sectors, in particular it is used in
large quantities in automotive, aeronautic and nautical industries. The main reasons of its wide use are: a very
good oxidation resistance, excellent ductility, low melting temperature (660 °C) and low density (2.71 g/cm3).
However, in order to reduce the emissions and fuel consumption is necessary to reduce the overall weight of
vehicles by increasing mechanical properties of the structural material. The improvement of mechanical
properties is normally achieved through use of reinforcement in materials, used like matrix, in order to improve
some specific characteristics.
In this work composites of carbon nanotubes (CNTs) dispersed in aluminum were made. The most difficulties
in the preparation of this type of composite are represented by the low wettability between metallic matrix and
fillers and the possibility of the oxidation of metal during melting with consequent decreasing of mechanical
proprieties. The composite was obtained by three consecutive step: the first one is the functionalization of
fillers surface to improve the fillers dispersion, the second one is the dispersion of fillers in the matrix by
powder mixing and the third one is the melting and casting of the mix prepared.
In particular, fillers used are multi walled carbon nanotubes (MWCNTs) with functionalized surface by
treatment with a solfonitric solution. Melting and casting are carried out with the aid of an induction furnace
with a controlled atmosphere system and centrifugal casting. Argon is the inert gas used to prevent the
oxidation of aluminium during fusion. Young’s modulus was evaluated at different temperature and correlated
with the different CNTs percentage. The dispersion rate of fillers and the microstructure of the sample were
evaluated by FESEM micrograph
A Method for Solving a Class of Multiple-Criteria Analysis Problems
AMS subject classification: 90C29.The paper proposes an interactive method solving the multiple criteria choice problem (MCCP) with a large number of discrete alternatives and a small number of
quantitative criteria. The decision maker (DM) sets his preferences in terms of
desired directions of improving or relaxing of the criteria. On this base the so
called reference cone is constructed. A small subset of relatively closed alternatives
is defined according to this cone and to the maximal deterioration of the criteria
values at each iteration. This subset is evaluated by the DM, who selects the most
preferred alternative or enters his/her new preferences.
The method suggested has user-friendly dialog. It enables the DM to explore
the set of alternatives comparatively quickly and easy. The method is included in
a DSS. It is tested by a number of real multiple criteria choice problems
Adoption, yield and profitability of tomato grafting technique in Vietnam
Theme: Families, Farms, FoodThis paper assesses the impact of AVRDC’s tomato grafting approach on yield and farm profitability in Lam Dong province and Red River Delta, Vietnam. Tomato grafting is advantageous to farmers suffering from soil-borne disease and abiotic stresses. However, there is scanty information on the extent of knowledge on adoption studies of tomato grafting technology in Vietnam. Based on a farm household survey conducted in August 2012, this paper provides detailed assessment of the adoption and profitability of introducing tomato grafting in the two study areas. Results indicate a 100% (n=225) adoption in Lam Dong province, and a 48% (n=36) adoption in the Red River Delta. The use of rootstock varieties differs in both locations to address location-specific agronomic challenges: tomato variety ‘Vimina’ (or HW7996) to address bacterial wilt (BW) problem, and eggplant EG203 variety in the Red River Delta to address both BW and waterlogging problem. Estimates from a Cobb-Douglas production function show that tomato grafting increases yield by 30% based. Marketable yield of grafted tomato was significantly larger (71.3 t/ha in Lam Dong Province and 75.0 t/ha in Red River Delta) than nongrafted (48.0 t/ha in Red River Delta). The benefit-cost ratio of grafted tomato production was higher compared to non-grafted due to increased yield and higher premium price. Nonetheless, further validation studies are required, considering the relatively small sample size in the Red River Delta and the high variability of some parameters.C.A. Genova, P. Schreinemachers, V. Afari-Sef
An analytic strategy for data processing of multimode networks
Complex network data structures are considered to capture the richness of social phenomena and real-life data settings. Multipartite networks are an example in which various scenarios are represented by different types of relations, actors, or modes. Within this context, the present contribution aims at discussing an analytic strategy for simplifying multipartite networks in which different sets of nodes are linked. By considering the connection of multimode networks and hypergraphs as theoretical concepts, a three-step procedure is introduced to simplify, normalize, and filter network data structures. Thus, a model-based approach is introduced for derived bipartite weighted networks in order to extract statistically significant links. The usefulness of the strategy is demonstrated in handling two application fields, that is, intranational student mobility in higher education and research collaboration in European framework programs. Finally, both examples are explored using community detection algorithms to determine the presence of groups by mixing up different modes
SERS of cells: What can we learn from cell lysates?
Surface-enhanced Raman spectroscopy (SERS) is a promising and emerging technique to analyze the cellular environment. We developed an alternative, rapid and label-free SERS-based method to get information about the cellular environment by analyzing cells lysates, thus avoiding the need to incorporate nanoparticles into cells. Upon sonicating and filtrating cells, we obtained lysates which, mixed with Au or Ag nanoparticles, yield stable and repeatable SERS spectra, whose overall profile depends on the metal used as substrate, but not on the buffer used for the lysis process. Bands appearing in these spectra were shown to arise mostly from the cytosol and were assigned to adenine, guanine, adenosine and reduced glutathione (GSH). Spectral differences among various cell types also demonstrated that this approach is suitable for cell type identification
Thermochemical characterization of polybenzimidazole with and without nano-ZrO2 for ablative materials application
During the ballistic atmospheric re-entry, a space vehicle has to withstand huge thermo-mechanical solicitations because of its high velocity and the friction with the atmosphere. According to the kind of the re-entry mission, the heat fluxes can be very high (in the order of some MW m−2) ;thus, an adequate thermal protection system is mandatory in order to preserve the structure of the vehicle, the payload and, for manned mission, the crew. Carbon phenolic ablators have been chosen for several missions because they are able to dissipate the incident heat flux very efficiently. Phenolic resin presents satisfying performance but also environmental drawbacks. Thus, a more environmental-friendly solution was conceived: a high-performance thermoplastic material, polybenzimidazole (PBI), was employed instead of phenolic resin. In this work PBI-ablative material samples were manufactured with and without the addition of nano-ZrO2 and tested with an oxyacetylene flame. For comparison, some carbon-phenolic ablators with the same density were manufactured and tested too. Thermogravimetric analysis on PBI samples was carried out at different heating rates, and the obtained TG data were elaborated to evaluate the activation energy of PBI and nano-filled PBI. The thermokinetics results for PBI show an improvement in thermal stability due to the addition of nano-ZrO2, while the oxyacetylene flame test enlightens how PBI ablators are able to overcome the carbon phenolic ablators performance, in particular when modified by the addition of nano-ZrO2
Shared and Distinctive Ultrastructural Abnormalities Expressed by Megakaryocytes in Bone Marrow and Spleen From Patients With Myelofibrosis
Numerous studies have documented ultrastructural abnormalities in malignant megakaryocytes from bone marrow (BM) of myelofibrosis patients but the morphology of these cells in spleen, an important extramedullary site in this disease, was not investigated as yet. By transmission-electron microscopy, we compared the ultrastructural features of megakaryocytes from BM and spleen of myelofibrosis patients and healthy controls. The number of megakaryocytes was markedly increased in both BM and spleen. However, while most of BM megakaryocytes are immature, those from spleen appear mature with well-developed demarcation membrane systems (DMS) and platelet territories and are surrounded by platelets. In BM megakaryocytes, paucity of DMS is associated with plasma (thick with protrusions) and nuclear (dilated with large pores) membrane abnormalities and presence of numerous glycosomes, suggesting a skewed metabolism toward insoluble polyglucosan accumulation. By contrast, the membranes of the megakaryocytes from the spleen were normal but these cells show mitochondria with reduced crests, suggesting deficient aerobic energy-metabolism. These distinctive morphological features suggest that malignant megakaryocytes from BM and spleen express distinctive metabolic impairments that may play different roles in the pathogenesis of myelofibrosis
Sulfate geoengineering impact on methane transport and lifetime: results from the Geoengineering Model Intercomparison Project (GeoMIP)
Abstract. Sulfate geoengineering (SG), made by sustained injection of SO2 in the tropical lower stratosphere, may impact the CH4 abundance through several photochemical mechanisms affecting tropospheric OH and hence the methane lifetime. (a) The reflection of incoming solar radiation increases the planetary albedo and cools the surface, with a tropospheric H2O decrease. (b) The tropospheric UV budget is upset by the additional aerosol scattering and stratospheric ozone changes: the net effect is meridionally not uniform, with a net decrease in the tropics, thus producing less tropospheric O(1D). (c) The extratropical downwelling motion from the lower stratosphere tends to increase the sulfate aerosol surface area density available for heterogeneous chemical reactions in the mid-to-upper troposphere, thus reducing the amount of NOx and O3 production. (d) The tropical lower stratosphere is warmed by solar and planetary radiation absorption by the aerosols. The heating rate perturbation is highly latitude dependent, producing a stronger meridional component of the Brewer–Dobson circulation. The net effect on tropospheric OH due to the enhanced stratosphere–troposphere exchange may be positive or negative depending on the net result of different superimposed species perturbations (CH4, NOy, O3, SO4) in the extratropical upper troposphere and lower stratosphere (UTLS). In addition, the atmospheric stabilization resulting from the tropospheric cooling and lower stratospheric warming favors an additional decrease of the UTLS extratropical CH4 by lowering the horizontal eddy mixing. Two climate–chemistry coupled models are used to explore the above radiative, chemical and dynamical mechanisms affecting CH4 transport and lifetime (ULAQ-CCM and GEOSCCM). The CH4 lifetime may become significantly longer (by approximately 16 %) with a sustained injection of 8 Tg-SO2 yr−1 starting in the year 2020, which implies an increase of tropospheric CH4 (200 ppbv) and a positive indirect radiative forcing of sulfate geoengineering due to CH4 changes (+0.10 W m−2 in the 2040–2049 decade and +0.15 W m−2 in the 2060–2069 decade)
Gold Nanoparticles-Functionalized Cotton as Promising Flexible and Green Substrate for Impedometric VOC Detection
This work focuses on the possible application of gold nanoparticles on flexible cotton fabric as acetone- and ethanol-sensitive substrates by means of impedance measurements. Specifically, citrate- and polyvinylpyrrolidone (PVP)-functionalized gold nanoparticles (Au NPs) were synthesized using green and well-established procedures and deposited on cotton fabric. A complete structural and morphological characterization was conducted using UV–VIS and Fourier transform infrared (FT–IR) spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). A detailed dielectric characterization of the blank substrate revealed interfacial polarization effects related to both Au NPs and their specific surface functionalization. For instance, by entirely coating the cotton fabric (i.e., by creating a more insulating matrix), PVP was found to increase the sample resistance, i.e., to decrease the electrical interconnection of Au NPs with respect to citrate functionalized sample. However, it was observed that citrate functionalization provided a uniform distribution of Au NPs, which reduced their spacing and, therefore, facilitated electron transport. Regarding the detection of volatile organic compounds (VOCs), electrochemical impedance spectroscopy (EIS) measurements showed that hydrogen bonding and the resulting proton migration impedance are instrumental in distinguishing ethanol and acetone. Such findings can pave the way for the development of VOC sensors integrated into personal protective equipment and wearable telemedicine devices. This approach may be crucial for early disease diagnosis based on nanomaterials to attain low-cost/low-end and easy-to-use detectors of breath volatiles as disease markers
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