Tensor products of finitely cocomplete and abelian categories

The purpose of this article is to study the existence of Deligne's tensor product of abelian categories by comparing it with the well-known ten- sor product of finitely cocomplete categories. The main result states that the former exists precisely when the latter is an abelian category, and moreover in this case both tensor products coincide. An example of two abelian categories whose Deligne tensor product does not exist is given.Comment: 14 page

Commutativity

We describe a general framework for notions of commutativity based on enriched category theory. We extend Eilenberg and Kelly's tensor product for categories enriched over a symmetric monoidal base to a tensor product for categories enriched over a normal duoidal category; using this, we re-find notions such as the commutativity of a finitary algebraic theory or a strong monad, the commuting tensor product of two theories, and the Boardman-Vogt tensor product of symmetric operads.Comment: 48 pages; final journal versio

Dynamics of a rational system of difference equations in the plane

We consider a rational system of first order difference equations in the plane with four parameters such that all fractions have a common denominator. We study, for the different values of the parameters, the global and local properties of the system. In particular, we discuss the boundedness and the asymptotic behavior of the solutions, the existence of periodic solutions and the stability of equilibria

Long-lived oscillatory incoherent electron dynamics in molecules: trans-polyacetylene oligomers

We identify an intriguing feature of the electron-vibrational dynamics of molecular systems via a computational examination of \emph{trans}-polyacetylene oligomers. Here, via the vibronic interactions, the decay of an electron in the conduction band resonantly excites an electron in the valence band, and vice versa, leading to oscillatory exchange of electronic population between two distinct electronic states that lives for up to tens of picoseconds. The oscillatory structure is reminiscent of beating patterns between quantum states and is strongly suggestive of the presence of long-lived molecular electronic coherence. Significantly, however, a detailed analysis of the electronic coherence properties shows that the oscillatory structure arises from a purely incoherent process. These results were obtained by propagating the coupled dynamics of electronic and vibrational degrees of freedom in a mixed quantum-classical study of the Su-Schrieffer-Heeger Hamiltonian for polyacetylene. The incoherent process is shown to occur between degenerate electronic states with distinct electronic configurations that are indirectly coupled via a third auxiliary state by the vibronic interactions. A discussion of how to construct electronic superposition states in molecules that are truly robust to decoherence is also presented

Lax orthogonal factorisation systems

This paper introduces lax orthogonal algebraic weak factorisation systems on 2-categories and describes a method of constructing them. This method rests in the notion of simple 2-monad, that is a generalisation of the simple reflections studied by Cassidy, H\'ebert and Kelly. Each simple 2-monad on a finitely complete 2-category gives rise to a lax orthogonal algebraic weak factorisation system, and an example of a simple 2-monad is given by completion under a class of colimits. The notions of KZ lifting operation, lax natural lifting operation and lax orthogonality between morphisms are studied.Comment: 59 page

Hopf measuring comonoids and enrichment

We study the existence of universal measuring comonoids $P(A,B)$ for a pair of monoids $A$, $B$ in a braided monoidal closed category, and the associated enrichment of a category of monoids over the monoidal category of comonoids. In symmetric categories, we show that if $A$ is a bimonoid and $B$ is a commutative monoid, then $P(A,B)$ is a bimonoid; in addition, if $A$ is a cocommutative Hopf monoid then $P(A,B)$ always is Hopf. If $A$ is a Hopf monoid, not necessarily cocommutative, then $P(A,B)$ is Hopf if the fundamental theorem of comodules holds; to prove this we give an alternative description of the dualizable $P(A,B)$-comodules and use the theory of Hopf (co)monads. We explore the examples of universal measuring comonoids in vector spaces and graded spaces.Comment: 30 pages. Version 2: re-arrangement of material; expansion of previous section 6, splitting into current sections 6,7,8; fix of graded algebras example, section 11; appendix removed; other minor fixes and edit

Reduced purities as measures of decoherence in many-electron systems

A hierarchy of measures of decoherence for many-electron systems that is based on the purity and the hierarchy of reduced electronic density matrices is presented. These reduced purities can be used to characterize electronic decoherence in the common case when the many-body electronic density matrix is not known and only reduced information about the electronic subsystem is available. Being defined from reduced electronic quantities, the interpretation of the reduced purities is more intricate than the usual (many-body) purity. This is because the nonidempotency of the $r$-body reduced electronic density matrix that is the basis of the reduced purity measures can arise due to decoherence or due to electronic correlations. To guide the interpretation, explicit expressions are provided for the one-body and two-body reduced purities for a general electronic state. Using them, the information content and structure of the one-body and two-body reduced purities is established, and limits on the changes that decoherence can induce are elucidated. The practical use of the reduced purities to understand decoherence dynamics in many-electron systems is exemplified through an analysis of the electronic decoherence dynamics in a model molecular system.Comment: 10 pages, 3 figure