Kinetic modelling of epitaxial film growth with up- and downward step barriers

The formation of three-dimensional structures during the epitaxial growth of films is associated to the reflection of diffusing particles in descending terraces due to the presence of the so-called Ehrlich-Schwoebel (ES) barrier. We generalize this concept in a solid-on-solid growth model, in which a barrier dependent on the particle coordination (number of lateral bonds) exists whenever the particle performs an interlayer diffusion. The rules do not distinguish explicitly if the particle is executing a descending or an ascending interlayer diffusion. We show that the usual model, with a step barrier in descending steps, produces spurious, columnar, and highly unstable morphologies if the growth temperature is varied in a usual range of mound formation experiments. Our model generates well-behaved mounded morphologies for the same ES barriers that produce anomalous morphologies in the standard model. Moreover, mounds are also obtained when the step barrier has an equal value for all particles independently if they are free or bonded. Kinetic roughening is observed at long times, when the surface roughness w and the characteristic length $\xi$ scale as $w ~ t^\beta$ and $\xi ~ t^\zeta$ where $\beta \approx 0.31$ and $\zeta \approx 0.22$, independently of the growth temperature.Comment: 15 pages, 7 figure

Shelf-Ocean material exchange influencing the Atlantic chemical composition off NW Iberian margin since the last glaciation

Rivers are the main conduit of sediment to the shelf. The basin geology, the drainage area and the discharge rate are the major factors that determine their sediment load (Milliman and Syvistski, 1992). Besides suspended particles, dissolved components may also give some information on the eroded crust. Sr isotopes in carbonate shells of biological organisms have been used to study, in the geological record, the influence exerted by the chemical weathering of the continental crust on the seawater composition (Macdougall, 1991). In this work, Sr isotope ratios obtained in tests of foraminifera representing the last 40 ka are presented and discussed in the scope of the palaeogeographical evolution of NW Iberia. This work aims to present and discuss the results of Sr isotope analyses (performed, by TIMS, in the Isotope Geology Laboratory of the University of Aveiro) of tests of two species of foraminifera, from nine samples taken along the OMEX core KC 024-19 (181 cm; 42°08’98’’N, 10°29´96’’W, and 2765m), collected in the Galicia Bank area, off Galicia. Taking into account that Sr contained in the carbonate tests is usually considered as preserving the signature of the contemporaneous seawater, one planktonic species (Globigerina bulloides) and one benthic species (Cibicides wuellerstorfi) were selected in order to try to detect Sr isotope variations both through time and between two different levels of the water column. The core age model, which records the last 40 ka, is based on a combination of oxygen isotope stratigraphy, eight AMS 14C datings and the synchronisation of the last four Heinrich Events in the Iberian Margin sedimentary records. As a whole, the obtained 87Sr/86Sr ratios vary between 0.709209 and 0.709108, with a mean 2σ error of 0.000025. These values lie within the range of modern marine Sr isotope ratios (0.70910-0.70922), as previously defined using analyses of both seawater and marine carbonates (see compilation by Faure and Mensing, 2005). Despite their small variation, the 87Sr/86Sr ratios obtained in G. bulloides seem to indicate that Sr dissolved in seawater at the KC 024-19 core site became slightly less radiogenic after the Last Glacial Maximum (LGM). This decrease is concomitant with diminishing amounts of the detrital components in the sediments (Fig. 1). Therefore, both the composition of dissolved Sr, as revealed by results on tests of planktonic foraminifera, and the proportions of suspended terrigenous particulate material arriving at the KC 024-19 site point to a decreasing importance of the contribution of the erosion of the Iberian Variscan crust since the Last Glacial Maximum and in the Holocene. The 87Sr/86Sr ratios measured in tests of benthic foraminifera (C. wuellerstorfi) are more erratic and no correlation can be established with palaeogeographical/palaeoclimatic constraints. The difference between the behaviour of Sr compositions in G. bulloides and C. wuellerstorfi may indicate that whilst the planktonic foraminifera should reproduce very closely the seawater composition, the benthic organisms should, in addition to the major role of seawater, also be affected by some sort of interaction with the sediments. As such, planktonic foraminifera are probably more reliable indicators of seawater composition in studies involving very small periods and corresponding very slight variations of the 87Sr/86Sr ratios. Taking into account that G. bulloides is a common planktonic species (living mostly in the first 50m of the water column), whose tests seem to be in equilibrium with sea water composition, variations in its 87Sr/86Sr ratios can be related with changes in the chemical composition of the water of the Atlantic Ocean off NW Iberian Margin. The highest 87Sr/86Sr values are contemporaneous with a period of low sea level (about -140 m; Dias et al., 2000) during the LGM. According to Dias et al. (2000) at 18 ka BP the shoreline was close to the shelf break. The summital parts of the Gerês and Estrela mountains were covered by local glaciers and close to the coast freezing occurred frequently. The river catchments, which extended far to the shelf, received more rainfall due to a longer, compared to present day conditions, wet season, which promoted both physical and chemical weathering. Higher pluviosity combined with the effect of spring ice melting maintained high river discharge and consequently caused very important sediment supply to the coastal zone. The extremely narrow shelf was a very energetic environment due to sea bottom inclination and very limited long wave refraction. Therefore, at that time, a long wet season and very competent rivers should have caused important erosion of the Variscan basement in NW Iberia. Additionally, then, the shoreline was much closer to the KC 024-19 site. The combination of all these factors favoured an important deposition of terrigenous sediments and the local slight enrichment in radiogenic Sr of the seawater. With sea level rise, after the deglaciation and during the Holocene, the river estuaries became progressively far away from the shelf break. Their competence of transport also became progressively reduced and the offshore transport of detrital sediments became progressively lower. Conversely the biogenic carbonate proportion in the sediments increased, due to lower dilution by the terrigenous particles. Simultaneously, the values of 87Sr/86Sr in the seawater at the KC 024-19 site became lower, as a consequence of a complete homogenization with the ocean global composition, which was now more effective with the increasing distance towards shoreline

Unveiling the simulacri corpus sanctae: the case study of Saint Aurelius Martyr (Oporto, Portugal)

The post-Tridentine Church promoted the cult of the martyrs’ relics exhumed from the Roman catacombs by exhibiting them to the veneration of the faithful in life-sized sumptuous reliquary-images (simulacri corpus sanctae). They functioned as powerful ways of dissemination of the Catholic faith and a mean of fighting Protestantism. During three centuries, the cult of the catacomb saints or holy bodies (corpi santi) spread throughout the Christian world. In recent years, a relatively large number of studies regarding the catacomb saints and their full body reliquaries (simulacra) have emerged on publications, oral presentations, and academic research. Despite being a promising topic receiving increasing attention, these reliquaries are still largely unknown in most countries, including Portugal. An overview of the first scientific approach performed on historic textiles, the skeletal remains, and the constructive system of the 18th century reliquary of Saint Aurelius Martyr from Oporto’s cathedral is presented.info:eu-repo/semantics/publishedVersio

On Minimum Violations Ranking in Paired Comparisons

Ranking a set of objects from the most dominant one to the least, based on the results of paired comparisons, proves to be useful in many contexts. Using the rankings of teams or individuals players in sports to seed tournaments is an example. The quality of a ranking is often evaluated by the number of violations, cases in which an object is ranked lower than another that it has dominated in a comparison, that it contains. A minimum violations ranking (MVR) method, as its name suggests, searches specifically for rankings that have the minimum possible number of violations which may or may not be zero. In this paper, we present a method based on statistical physics that overcomes conceptual and practical difficulties faced by earlier studies of the problem.Comment: 10 pages, 10 figures; typos corrected (v2

Farinha de carne e ossos bovina e suína como fonte de proteína para suínos.

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Farinha de carne e ossos bovina e suína como fonte de proteína para suínos em crescimento e terminação.

bitstream/item/59329/1/CUsersPiazzonDocuments23.pd

Spherical Scalar Field Halo in Galaxies

We study a spherically symmetric fluctuation of scalar dark matter in the cosmos and show that it could be the dark matter in galaxies, provided that the scalar field has an exponential potential whose overall sign is negative and whose exponent is constrained observationally by the rotation velocities of galaxies. The local space-time of the fluctuation contains a three dimensional space-like hypersurface with surplus of angle.Comment: 5 REVTeX pages, no figures. Contains important suggestions provided by the referee. Final version, to appear in Phys. Rev.

Structure and Stability of Keplerian MHD Jets

MHD jet equilibria that depend on source properties are obtained using a simplified model for stationary, axisymmetric and rotating magnetized outflows. The present rotation laws are more complex than previously considered and include a Keplerian disc. The ensuing jets have a dense, current-carrying central core surrounded by an outer collar with a return current. The intermediate part of the jet is almost current-free and is magnetically dominated. Most of the momentum is located around the axis in the dense core and this region is likely to dominate the dynamics of the jet. We address the linear stability and the non-linear development of instabilities for our models using both analytical and 2.5-D numerical simulation's. The instabilities seen in the simulations develop with a wavelength and growth time that are well matched by the stability analysis. The modes explored in this work may provide a natural explanation for knots observed in astrophysical jets.Comment: 35 pages, accepted by the Ap

Anharmonic transitions in nearly dry L-cysteine I

Two special dynamical transitions of universal character have been recently observed in macromolecules at $T_{D}\sim 180 - 220$ K and $T^{*}\sim 100$ K. Despite their relevance, a complete understanding of the nature of these transitions and their consequences for the bio-activity of the macromolecule is still lacking. Our results and analysis concerning the temperature dependence of structural, vibrational and thermodynamical properties of the orthorhombic polymorph of the amino acid L-cysteine (at a hydration level of 3.5%) indicated that the two referred temperatures define the triggering of very simple and specific events that govern all the biochemical interactions of the biomolecule: activation of rigid rotors ($T<T^{*}$), phonon-phonon interactions with phonons of water dimer ($T^{*}<T<T_{D}$), and water rotational barriers surpassing ($T>T_{D}$).Comment: 4 pages, 4 figures, submitted to Physical Review Letter