Initial study on phytoextraction for recovery of metals from sorted and aged waste‐to‐energy bottom ash

Sorted and aged bottom ash from Waste‐to‐Energy plants, i.e., MIBA (the Mineral fraction of Incinerator Bottom Ash) are potential source of metals that could be utilized to meet the increased demand from society. In this work, sunflowers (Helianthus annuus) and rapeseed (Brassica napus) were cultivated in conventional MIBA to evaluate the possibility for phytoextraction, mainly of Zn, during the period of one cultivation season in the Nordic climate. The results show that metal extraction from MIBA using rapeseed and sunflowers is workable but that neither of the used plants is optimal, mainly due to the inhibited root development and low water‐ and nutrient‐holding capacities of MIBA. The addition of fertilizer is also important for growth. There was a simultaneous accumulation of numerous metals in both plant types, and the highest metal content was generally found in the roots. Calculations indicated that the ash from rapeseed root incineration contained about 2% Zn, and the contents of Co, Cu, and Pb were comparable to those in workable ores. This initial study shows that cultivation in and phytoextraction on MIBA is possible, and that the potential for increased metal extraction is high

Finding cool subdwarfs using a V-J reduced proper-motion diagram: Stellar parameters for 91 candidates

We present the results of a search for cool subdwarfs for which our candidates were drawn from a V-J reduced proper-motion diagram constructed by Salim & Gould (2002). Kinematic (U, V, and W) and self-consistent stellar parameters (Teff, log g, [Fe/H], and V_t) are derived for 91 candidate subdwarfs based on high resolution spectra. The observed stars span 3900K < Teff < 6200K and -2.63 < [Fe/H] < 0.25 including only 3 giants (log g < 4.0). Of the sample, 77 stars have MgH lines present in their spectra. With more than 56% of our candidate subdwarfs having [Fe/H] < -1.5, we show that the V-J reduced proper-motion diagram readily identifies metal-poor stars.Comment: PASP (in press

The Interstellar Rubidium Isotope Ratio toward Rho Ophiuchi A

The isotope ratio, 85Rb/87Rb, places constraints on models of the nucleosynthesis of heavy elements, but there is no precise determination of the ratio for material beyond the Solar System. We report the first measurement of the interstellar Rb isotope ratio. Our measurement of the Rb I line at 7800 A for the diffuse gas toward rho Oph A yields a value of 1.21 +/- 0.30 (1-sigma) that differs significantly from the meteoritic value of 2.59. The Rb/K elemental abundance ratio for the cloud also is lower than that seen in meteorites. Comparison of the 85Rb/K and 87Rb/K ratios with meteoritic values indicates that the interstellar 85Rb abundance in this direction is lower than the Solar System abundance. We attribute the lower abundance to a reduced contribution from the r-process. Interstellar abundances for Kr, Cd, and Sn are consistent with much less r-process synthesis for the solar neighborhood compared to the amount inferred for the Solar System.Comment: 12 pages with 2 figures and 1 table; will appear in ApJ Letter

The Perceived Support From Light and Color Before and After an Evidence-Based Design Intervention in an Emergency Department Environment: A Quasi-Experimental Study

Aim: To evaluate patients’ and family members’ perceived support from light and color before, compared with after an evidence-based design (EBD) intervention at an emergency department (ED) using a validated instrument—the Light and Color Questionnaire (LCQ). Background: EDs offer acute care day and night. Thus, a supportive physical environment where light and color is crucial for how the milieu is experienced is vital. Research is limited on how care settings are perceived as supportive by users. Methods: Quasi-experimental evaluation of the refurbishing and remodeling of an ED by an expert group of nurse managers, nursing staff, nursing researchers and architects in south Sweden. LCQ includes dimensions “maximizing awareness and orientation,” “maximizing safety and security,” “supporting functional abilities,” “providing privacy,” “opportunities for personal control” (not for LCQ-Color), and “regulation and quality of stimulation.” LCQ was analyzed and compared in 400 surveys from 100 patients and 100 family members before the intervention and 100 patients and 100 family members after the intervention. Results: The LCQ total score significantly improved after the intervention for both patients and family members. Four of the six dimensions of LCQ Light subscale scores were significantly higher for family members, and three of the six dimensions were significantly higher for patients after the intervention. The LCQ Color subscale score showed significant improvements for all five dimensions for both patients and family members after the intervention. Conclusion: This study showed improved perceived support from light and color in the physical environment for patients and family members after an EBD intervention at an emergency department using a validated instrument—the Light and Color Questionnaire

The Southern Proper Motion Program III. A Near-Complete Catalog to V=17.5

We present the third installment of the Yale/San Juan Southern Proper Motion Catalog, SPM3. Absolute proper motions, positions, and photographic B,V photometry are given for roughly 10.7 million objects, primarily stars, down to a magnitude of V=17.5. The Catalog covers an irregular area of 3700 square degrees, between the declinations of -20 and -45 degrees, excluding the Galactic plane. The proper-motion precision, for well-measured stars, is estimated to be 4.0 mas/yr. Unlike previous releases of the SPM Catalog, the proper motions are on the International Celestial Reference System by way of Hipparcos Catalog stars, and have an estimated systematic uncertainty of 0.4 mas/yr. The SPM3 Catalog is available via electronic transfer,(http://www.astro.yale.edu/astrom/) As an example of the potential of the SPM3 proper motions, we examine the Galactocentric velocities of a group of metal-poor, main-sequence A stars. The majority of these exhibit thick-disk kinematics, lending support to their interpretation as thick-disk blue stragglers, as opposed to being an accreted component.Comment: 23 pages, 10 figures, accepted for publication in Astronomical Journa

Boron in Very Metal-Poor Stars

We have observed the B I 2497 A line to derive the boron abundances of two very metal-poor stars selected to help in tracing the origin and evolution of this element in the early Galaxy: BD +23 3130 and HD 84937. The observations were conducted using the Goddard High Resolution Spectrograph on board the Hubble Space Telescope. A very detailed abundance analysis via spectral synthesis has been carried out for these two stars, as well as for two other metal-poor objects with published spectra, using both Kurucz and OSMARCS model photospheres, and taking into account consistently the NLTE effects on the line formation. We have also re-assessed all published boron abundances of old disk and halo unevolved stars. Our analysis shows that the combination of high effective temperature (Teff > 6000 K, for which boron is mainly ionized) and low metallicity ([Fe/H]<-1) makes it difficult to obtain accurate estimates of boron abundances from the B I 2497 A line. This is the case of HD 84937 and three other published objects (including two stars with [Fe/H] ~ -3), for which only upper limits can be established. BD +23 3130, with [Fe/H] ~ -2.9 and logN(B)_NLTE=0.05+/-0.30, appears then as the most metal-poor star for which a firm measurement of the boron abundance presently exists. The evolution of the boron abundance with metallicity that emerges from the seven remaining stars with Teff < 6000 K and [Fe/H]<-1, for which beryllium abundances were derived using the same stellar parameters, shows a linear increase with a slope ~ 1. Furthermore, the B/Be ratio found is constant at a value ~ 20 for stars in the range -3<[Fe/H]<-1. These results point to spallation reactions of ambient protons and alpha particles with energetic particles enriched in CNO as the origin of boron and beryllium in halo stars.Comment: 38 pages, 11 Encapsulated Postscript figures (included), uses aaspp4.sty. Accepted for publication in The Astrophysical Journal. The preprint is also available at: http://www.iac.es/publicaciones/preprints.htm

Constraining the Metallicity of the Low Density Lyman-alpha Forest Using OVI Absorption

We search for OVI absorption in a Keck HIRES spectrum of the z=3.62 quasar Q1422+231. Comparison of CIV measurements to cosmological simulations shows that \lya forest absorbers with N_HI > 10^{14.5} have [C/H]~=-2.5, for the UV background spectrum of Haardt & Madau (HM). Lower column density absorption arises in lower density gas, where OVI is the most sensitive metal tracer. Since OVI lines lie at wavelengths contaminated by Lyman series absorption, we interpret our Q1422 results by comparing to artificial spectra drawn from an SPH simulation of a Lambda-dominated CDM model. A search for deep, narrow features in Q1422 yields only a few candidate OVI lines, statistically consistent with the number in artificial spectra with no metals; spectra generated with the HM background and [O/H] >= -2.5 predict too many narrow lines. However, applying the optical depth ratio technique of Songaila (1998), we DO find significant OVI associated with CIV systems; matching Q1422 requires [O/C]~=+0.5, implying [O/H]~=-2.0. Taken together these results imply that (a) the metallicity in the low density IGM is at least a factor of three below that in the overdense regions where CIV absorption is detectable, and (b) oxygen is overabundant in these regions, consistent with the enrichment pattern of old halo stars. If the UV background is heavily truncated above 4 Ry, an implausibly high oxygen overabundance ([O/C]>+2) is required by the data; thus a majority of the volume of the universe must have undergone helium reionization by z=3.(Abridged)Comment: Submitted to ApJ, 48 pp including 14 ps figures, uses aaspp4.st

Lithium in Blanco1: Implications for Stellar Mixing

We obtain lithium abundances for G and K stars in Blanco 1, an open cluster with an age similar to, or slightly younger than, the Pleiades. We critically examine previous spectroscopic abundance analyses of Blanco 1 and conclude that while there were flaws in earlier work, it is likely that Blanco 1 is close in overall metallicity to the older Hyades cluster and more metal-rich than the Pleiades. However, we find Blanco 1 has Li abundances and rotation rates similar to the Pleiades, contradicting predictions from standard stellar evolution models, in which convective pre-main sequence (PMS) Li depletion should increase rapidly with metallicity. If the high metallicity of Blanco 1 is subsequently confirmed, our observations imply (1) that a currently unknown mechanism severely inhibits PMS Li depletion, (2) that additional non-standard mixing modes, such as those driven by rotation and angular momentum loss, are then responsible for main sequence Li depletion between the ages of Blanco 1 and the Hyades, and (3) that in clusters younger than the Hyades, metallicity plays only a minor role in determining the amount of Li depletion among G and K stars. These conclusions suggest that Li abundance remains a useful age indicator among young (less than 700 Myr) stars even when metallicities are unknown. If non-standard mixing is effective in Population I stars, the primordial Li abundance could be significantly larger than present day Population II Li abundances, due to prior Li depletion.Comment: 18 pages, 3 figs. To appear in ApJ Vol. 511 (Jan 20 1999

Personalized Nursing and Health Care: Advancing Positive Patient Outcomes in Complex and Multilevel Care Environments

This Special Issue of the Journal of Personalised Medicine invited manuscripts that further establish the current state of science relating to personalized nursing and health care [...