Fast-Response Single-Nanowire Photodetector Based on ZnO/WS₂ Core/Shell Heterostructures

The surface plays an exceptionally important role in nanoscale materials, exerting a strong influence on their properties. Consequently, even a very thin coating can greatly improve the optoelectronic properties of nanostructures by modifying the light absorption and spatial distribution of charge carriers. To use these advantages, 1D/1D heterostructures of ZnO/WS₂ core/shell nanowires with a-few-layers-thick WS₂ shell were fabricated. These heterostructures were thoroughly characterized by scanning and transmission electron microscopy, X-ray diffraction, and Raman spectroscopy. Then, a single-nanowire photoresistive device was assembled by mechanically positioning ZnO/WS₂ core/shell nanowires onto gold electrodes inside a scanning electron microscope. The results show that a few layers of WS₂ significantly enhance the photosensitivity in the short wavelength range and drastically (almost 2 orders of magnitude) improve the photoresponse time of pure ZnO nanowires. The fast response time of ZnO/WS₂ core/shell nanowire was explained by electrons and holes sinking from ZnO nanowire into WS₂ shell, which serves as a charge carrier channel in the ZnO/WS₂ heterostructure. First-principles calculations suggest that the interface layer i-WS₂, bridging ZnO nanowire surface and WS₂ shell, might play a role of energy barrier, preventing the backward diffusion of charge carriers into ZnO nanowire

Unexpected Epitaxial Growth of a Few WS₂ Layers on {11̅00} Facets of ZnO Nanowires

Core–shell nanowires are an interesting and perspective class of radially heterostructured nanomaterials where epitaxial growth of the shell can be realized even at noticeable core–shell lattice mismatch. In this study epitaxial hexagonally shaped shell consisting of WS₂ nanolayers was grown on {11̅00} facets of prismatic wurtzite-structured [0001]-oriented ZnO nanowires for the first time. A synthesis was performed by annealing in a sulfur atmosphere of ZnO/WO₃ core–shell structures, produced by reactive dc magnetron sputtering of an amorphous a-WO₃ layer on top of ZnO nanowire array. The morphology and phase composition of synthesized ZnO/WS₂ core–shell nanowires were confirmed by scanning and transmission electron microscopy (SEM and TEM), micro-Raman, and photoluminescence spectroscopy. Epitaxial growth of WS₂(0001) layer(s) on {11̅00} facets of ZnO nanowire is unexpected due to incompatibility of their symmetry and structure parameters. To relax the interfacial incoherence, we propose a model of ZnO/WS₂ interface containing WS₂ bridging groups inside and use first-principles simulations to support its feasibility

Unraveling the Structure and Properties of Layered and Mixed ReO₃–WO₃ Thin Films Deposited by Reactive DC Magnetron Sputtering

Tungsten trioxide (WO3) is a well-known electrochromic material with a wide band gap, while rhenium trioxide (ReO3) is a “covalent metal” with an electrical conductivity comparable to that of pure metals. Since both WO3 and ReO3 oxides have perovskite-type structures, the formation of their solid solutions (ReO3–WO3 or RexW1–xO3) can be expected, which may be of significant academic and industrial interest. In this study, layered WO3/ReO3, ReO3/WO3, and mixed ReO3–WO3 thin films were produced by reactive DC magnetron sputtering and subsequent annealing in air at 450 °C. The structure and properties of the films were characterized by X-ray diffraction, optical spectroscopy, Hall conductivity measurements, conductive atomic force microscopy, scanning and transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoemission spectroscopy. First-principles density functional theory calculations were performed for selected compositions of RexW1–xO3 solid solutions to model their crystallographic structure and electronic properties. The calculations predict metallic conductivity and tetragonal distortion of solid solutions in agreement with the experimental results. In contrast to previously reported methods, our approach allows us to produce the WO3–ReO3 alloy with a high Re content (>50%) at moderate temperatures and without the use of high pressures