5 research outputs found

    Scaling from single-point sap velocity measurements to stand transpiration in a multispecies deciduous forest: Uncertainty sources, stand structure effect, and future scenarios

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    9 páginas.-- 5 figuras.-- 2 tablas.-- 58 referencias[EN] A major challenge in studies estimating stand water use in mixed-species forests is how to effectively scale data from individual trees to the stand. This is the case for forest ecosystems in the northeastern USA where differences in water use among species and across different size classes have not been extensively studied, despite their relevance for a wide range of ecosystem services. Our objectives were to assess the importance of different sources of variability on transpiration upscaling and explore the potential impacts of future shifts in species composition on the forest water budget. We measured sap velocity in five tree species (Fagus grandifolia Ehrh., Acer rubrum L., Acer saccharum Marsh., Betula alleghaniensis Britton, and Betula papyrifera Marsh.) in a mature stand and a young stand in New Hampshire, USA. Our results showed that the greatest potential source of error was radial variability and that tree size was more important than species in determining sap velocity. Total sapwood area was demonstrated to exert a strong controlling influence on transpiration, varying depending on tree size and species. We conclude that the effect of potential species shifts on transpiration will depend on the sap velocity, determined not only by radial variation and tree size, but also by the sapwood area distribution in the stand.[FR] Les études dont le but est d'estimer l'utilisation de l'eau a` l'échelle du peuplement dans les forêts mélangées font face a` un défi majeur : comment passer efficacement de l'échelle des arbres individuels a` l'échelle du peuplement. C'est le cas pour les écosystèmes forestiers dans le nord-est des États-Unis où les différences dans l'utilisation de l'eau entre les espèces et parmi les différentes catégories de taille n'ont pas fait l'objet d'études approfondies malgré leur pertinence pour une vaste gamme de services de l'écosystème. Nos objectifs consistaient a` évaluer l'importance des différentes sources de variation sur l'extrapolation de la transpiration et a` explorer les impacts potentiels des changements futurs dans la composition en espèces sur le bilan hydrique de la forêt. Nous avons mesuré la vitesse de la sève chez cinq espèces d'arbre (Fagus grandifolia Ehrh., Acer rubrum L., Acer saccharum Marsh., Betula alleghaniensis Britton et Betula papyrifera Marsh.) dans un peuplement mature et dans un jeune peuplement au New Hampshire (É.-U.). Nos résultats ont montré que la plus grande source potentielle d'erreur était la variation radiale et que la vitesse de la sève était davantage déterminée par la taille des arbres que par l'espèce. La surface totale de bois d'aubier avait un effet très déterminant sur la transpiration qui variait selon la taille et l'espèce d'arbre. Nous concluons que l'effet des changements potentiels dans la composition en espèces sur la transpiration dépendra de la vitesse de la sève qui est principalement déterminée par la variation radiale et la taille des arbres mais aussi de la distribution de la surface de bois d'aubier dans le peuplement.This work was funded by the University of New Hampshire and the New Hampshire Agricultural Experiment Station. The Bartlett Experimental Forest is operated by the USDA Forest Service Northern Research Station. S. Mcgraw, P. Pellissier, C. Breton, S. Alvarado-Barrientos, R. Snyder, and Z. Aldag assisted in the field and in the lab. The 2011 stand inventory was led by S. Goswami. Tree heights were measured and compiled by C. Blodgett, T. Fahey, and L. Liu. A. Richardson shared meteorology and solar radiation data from the Bartlett Amerflux tower. The stands used in this experiment are maintained and monitored by the MELNHE project under the direction of R. Yanai and M. Fisk, with funding from NSF grants DEB 0235650 and DEB 0949324Peer reviewe

    Improving the Electrode Performance of Ge through Ge@C Core–Shell Nanoparticles and Graphene Networks

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    Germanium is a promising high-capacity anode material for lithium ion batteries, but it usually exhibits poor cycling stability because of its huge volume variation during the lithium uptake and release process. A double protection strategy to improve the electrode performance of Ge through the use of Ge@C core–shell nanostructures and reduced graphene oxide (RGO) networks has been developed. The as-synthesized Ge@C/RGO nanocomposite showed excellent cycling performance and rate capability in comparison with Ge@C nanoparticles when used as an anode material for Li ion batteries, which can be attributed to the electronically conductive and elastic RGO networks in addition to the carbon shells and small particle sizes of Ge. The strategy is simple yet very effective, and because of its versatility, it may be extended to other high-capacity electrode materials with large volume variations and low electrical conductivities

    Structure of Amorphous Selenium: Small Ring, Big Controversy

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    Selenium (Se) discovered in 1817 belongs to the family of chalcogens. Surprisingly, despite the long history of over two centuries and the chemical simplicity of Se, the structure of amorphous Se (a-Se) remains controversial to date regarding the dominance of chains versus rings. Here, we find that vapor-deposited a-Se is composed of disordered rings rather than chains in melt-quenched a-Se. We further reveal that the main origin of this controversy is the facile transition of rings to chains arising from the inherent instability of rings. This transition can be inadvertently triggered by certain characterization techniques themselves containing above-bandgap illumination (above 2.1 eV) or heating (above 50 °C). We finally build a roadmap for obtaining accurate Raman spectra by using above-bandgap excitation lasers with low photon flux (below 1017 phs m–2 s–1) and below-bandgap excitation lasers measured at low temperatures (below −40 °C) to minimize the photoexcitation- and heat-induced ring-to-chain transitions

    General Space-Confined On-Substrate Fabrication of Thickness-Adjustable Hybrid Perovskite Single-Crystalline Thin Films

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    Organic–inorganic hybrid perovskite single-crystalline thin films (SCTFs) are promising for enhancing photoelectric device performance due to high carrier mobility, long diffusion length, and carrier lifetime. However, bulk perovskite single crystals available today are not suitable for practical device application due to the unfavorable thickness. Herein, we report a facile space-confined solution-processed strategy to on-substrate grow various hybrid perovskite SCTFs in a size of submillimeter with adjustable thicknesses from nano- to micrometers. These SCTFs exhibit photoelectric properties comparable to bulk single crystals with low defect density and good air stability. The clear thickness-dependent colors allow fast visual selection of SCTFs with a suitable thickness for specific device application. The present substrate-independent growth of perovskite SCTFs opens up opportunities for on-chip fabrication of diverse high-performance devices

    Thermal Evaporation and Characterization of Sb<sub>2</sub>Se<sub>3</sub> Thin Film for Substrate Sb<sub>2</sub>Se<sub>3</sub>/CdS Solar Cells

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    Sb<sub>2</sub>Se<sub>3</sub> is a promising absorber material for photovoltaic cells because of its optimum band gap, strong optical absorption, simple phase and composition, and earth-abundant and nontoxic constituents. However, this material is rarely explored for photovoltaic application. Here we report Sb<sub>2</sub>Se<sub>3</sub> solar cells fabricated from thermal evaporation. The rationale to choose thermal evaporation for Sb<sub>2</sub>Se<sub>3</sub> film deposition was first discussed, followed by detailed characterization of Sb<sub>2</sub>Se<sub>3</sub> film deposited onto FTO with different substrate temperatures. We then studied the optical absorption, photosensitivity, and band position of Sb<sub>2</sub>Se<sub>3</sub> film, and finally a prototype photovoltaic device FTO/Sb<sub>2</sub>Se<sub>3</sub>/CdS/ZnO/ZnO:Al/Au was constructed, achieving an encouraging 2.1% solar conversion efficiency
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