Measurement of Retention Efficiency of Filters against Nanoparticles in Liquids using an Aerosolization Technique

An aerosolization technique has been developed to measure liquid-borne nanoparticles down to 30 nm and applied to evaluate retention efficiencies of liquid filters. This technique involves dispersing nanoparticle suspensions into air-borne form and measuring the size and concentration by a differential mobility analyzer coupled to a condensation particle counter. Polystyrene latex particles larger and smaller than 70 nm in diameter were dispersed by a constant output atomizer, COA, and an electrospray aerosol generator, ES, respectively, to avoid the interference from residue particles. With the ES, residue particles can be controlled to be less than 10 nm, allowing latex particles as small as 30 nm to be clearly distinguished from the size distribution measurements. Calibrations with 30, 50, 125, and 200 nm latex particles showed that liquid-borne and air-borne particle concentrations are proportionally related. This provides an effective way to quantify liquid-borne particles as small as 30 nm, which cannot be analyzed by state-of-the-art liquid particle counters. An application of this technique is to evaluate the nanoparticle retention performance of liquid filters. Both 200 and 400 nm rated Nuclepore filters were challenged with latex particles of different sizes, and retention efficiency as a function of particle size was determined by comparing the particle concentrations upstream and downstream of the tested filters. The results are comparable with the nominal pore size stated by the manufacturer if sieving is the dominant filtration mechanism and demonstrate the feasibility of using the aerosolization technique to evaluate the retention efficiency of filters against nanoparticles in liquids

Comparison of Methods for Online Measurement of Diesel Particulate Matter

Gravimetric analysis is the regulatory method for diesel particulate mass measurement. Because of issues such as adsorption/volatilization artifacts, it faces obstacles in measuring ultra low level emissions from modern diesel engines. Alternative methods of suspended particle mass measurement have been developed that show improvements in time resolution, sensitivity, and accuracy. Three size-resolved methods were considered here. Two methods rely on converting number size distributions obtained using a scanning mobility particle sizer (SMPS). Conversion techniques were based on effective density measurements and the Lall–Friedlander aggregate model. The third method employs the Universal Nanoparticle Analyzer (UNPA) to measure the aggregate size distribution from which mass is calculated. Results were compared with mass concentrations obtained using gravimetric analysis. The effective density conversion resulted in mass concentrations that were highly correlated (R2 >0.99) with filter mass. The ratios to filter mass concentration were found to be 0.99 ± 0.04, 0.45 ± 0.03, and 0.45 ± 0.19 for the effective density conversion, the Lall–Friedlander conversion, and the UNPA, respectively, for a wide range of engine operating conditions. In addition, the diesel aerosol mass distributions measured by the online techniques are in agreement to within 15–20% with respect to the mass median diameter, while discrepancies were observed in the mass concentration

Laboratory and On-Road Evaluations of Cabin Air Filters Using Number and Surface Area Concentration Monitors

An automotive cabin air filter’s effectiveness for removing airborne particles was determined both in a laboratory wind tunnel and in vehicle on-road tests. The most penetrating particle size for the test filter was ∼350 nm, where the filtration efficiency was 22.9 and 17.4% at medium and high fan speeds, respectively. The filtration efficiency increased for smaller particles and was 43.9% for 100 nm and 72.0% for 20 nm particles at a medium fan speed. We determined the reduction in passenger exposure to particles while driving in freeway traffic caused by a vehicle ventilation system with a cabin air filter installed. Both particle number and surface area concentration measurements were made inside the cabin and in the surrounding air. At medium fan speed, the number and surface area concentration-based exposure reductions were 65.6 ± 6.0% and 60.6 ± 9.4%, respectively. To distinguish the exposure reduction contribution from the filter alone and the remainder of the ventilation system, we also performed tests with and without the filter in place using the surface area monitors. The ventilation system operating in the recirculation mode with the cabin air filter installed provided the maximum protection, reducing the cabin particle concentration exponentially over time and usually taking only 3 min to reach 10 µm2/cm3 (a typical office air condition) under medium fan speed

Integrated Photocatalytic Filtration Array for Indoor Air Quality Control

Photocatalytic and filtration technologies were integrated to develop a hybrid system capable of removing and oxidizing organic pollutants from an air stream. A fluidized bed aerosol generator (FBAG) was adapted to prepare TiO2-loaded ventilation filters for the photodegradation of gas phase ethanol. Compared to a manually loaded filter, the ethanol photodegradation rate constant for the FBAG coated filter increased by 361%. Additionally, the presence of the photogenerated intermediate product, acetaldehyde, was reduced and the time for mineralization to CO2 was accelerated. These improvements were attributed to the FBAG system providing a more uniform distribution of TiO2 particles across the filter surface leading to greater accessibility by the UV light. A dual-UV-lamp system, as opposed to a single-lamp system, enhanced photocatalytic filter performance demonstrating the importance of high light irradiance and light distribution across the filter surface. Substituting the blacklight blue lamps with a UV-light-emitting-diode (UV-LED) array led to further improvement as well as suppressed the electrical energy per order (EE/O) by a factor of 6. These improvements derived from the more uniform distribution of light irradiance as well as the higher efficiency of UV-LEDs in converting electrical energy to photons

Penetration of Sub-50 nm Nanoparticles Through Electret HVAC Filters Used in Residence

<div><p>Pleated electret HVAC filters are often used in residence to mitigate the particles that originate both indoors and outdoors. These filters are usually tested with particles larger than 300 nm. However, residential particles can contain a significant amount of nanoparticles with size below 50 nm due to cooking, smoking, cleaning, wood burning, and outdoor infiltration. In order to characterize the nanoparticle removal by electret HVAC filters, penetrations of 3–50 nm silver nanoparticles through five different flat sheet electret media used in commercial residential HVAC filters were tested with face velocities of 0.05, 0.5, and 1.0 m s⁻¹. Experimental results showed that all media had significantly high penetrations with 0.35–0.8 at the most penetrating particle sizes (MPPSs) for all three velocities, which were in the sizes of 10–30 nm. A model based on single fiber theory for particle penetration predictions was used and compared with the experimental data. Results showed that the model predicted the nanoparticle penetrations very well for all media and all face velocities tested. According to the model, for enhancing the nanoparticle efficiency of the current commercial HVAC filters, the fiber diameter should be reduced or the number of pleats should be increased. However, by doing these, pressure drop and cost may be largely increased. On the other hand, this study found the existing commercial mechanical HVAC filters were much capable for sub-50 nm nanoparticle removal when their minimum efficiency reporting values (MERVs) were larger than 13 and it is concluded mechanical HVAC filters can do a better job than electret ones. However, the quality factor analysis showed electret filters could be regarded as the best filter media for removing particles smaller than 300 nm.</p><p>Copyright © 2015 American Association for Aerosol Research</p></div

All-Nanofiber-Based Ultralight Stretchable Triboelectric Nanogenerator for Self-Powered Wearable Electronics

The flexible and stretchable electronics have been considered as next-generation electronics. Stretchable triboelectric nanogenerators (S-TENGs) with both multifunction and comfort have become a hot field of research for wearable electronic devices recently. Here, we designed an all-nanofiber-based, ultralight, S-TENG that could be softly attached on skins for motion energy harvesting and self-powered biomechanical monitoring. The S-TENG consisted of only two nanofiber membranes: a polyvinylidene fluoride nanofiber membrane (PVDFNM) supported by thermoplastic polyurethane nanofiber membrane (TPUNM) was used as the frictional layer, and a multiwalled carbon nanotube (MWCNT) conductive material screen-printed on the TPUNM was used as the electrode layer. Due to the excellent stretchability of TPUNM, the S-TENG could generate electricity under various types of deformation, and regains its original performance after intense mechanical extension, even if it is partially cut or damaged. Owing to the great electronegativity of PVDFNM, the device generated a maximum voltage of 225 V and a current of 4.5 μA with an electrode area of 6 × 1 cm2. The S-TENG has great potential applications in self-powered wearable devices, electronic skins, and smart sensor networks

All-Nanofiber-Based Ultralight Stretchable Triboelectric Nanogenerator for Self-Powered Wearable Electronics

The flexible and stretchable electronics have been considered as next-generation electronics. Stretchable triboelectric nanogenerators (S-TENGs) with both multifunction and comfort have become a hot field of research for wearable electronic devices recently. Here, we designed an all-nanofiber-based, ultralight, S-TENG that could be softly attached on skins for motion energy harvesting and self-powered biomechanical monitoring. The S-TENG consisted of only two nanofiber membranes: a polyvinylidene fluoride nanofiber membrane (PVDFNM) supported by thermoplastic polyurethane nanofiber membrane (TPUNM) was used as the frictional layer, and a multiwalled carbon nanotube (MWCNT) conductive material screen-printed on the TPUNM was used as the electrode layer. Due to the excellent stretchability of TPUNM, the S-TENG could generate electricity under various types of deformation, and regains its original performance after intense mechanical extension, even if it is partially cut or damaged. Owing to the great electronegativity of PVDFNM, the device generated a maximum voltage of 225 V and a current of 4.5 μA with an electrode area of 6 × 1 cm². The S-TENG has great potential applications in self-powered wearable devices, electronic skins, and smart sensor networks

All-Nanofiber-Based Ultralight Stretchable Triboelectric Nanogenerator for Self-Powered Wearable Electronics

The flexible and stretchable electronics have been considered as next-generation electronics. Stretchable triboelectric nanogenerators (S-TENGs) with both multifunction and comfort have become a hot field of research for wearable electronic devices recently. Here, we designed an all-nanofiber-based, ultralight, S-TENG that could be softly attached on skins for motion energy harvesting and self-powered biomechanical monitoring. The S-TENG consisted of only two nanofiber membranes: a polyvinylidene fluoride nanofiber membrane (PVDFNM) supported by thermoplastic polyurethane nanofiber membrane (TPUNM) was used as the frictional layer, and a multiwalled carbon nanotube (MWCNT) conductive material screen-printed on the TPUNM was used as the electrode layer. Due to the excellent stretchability of TPUNM, the S-TENG could generate electricity under various types of deformation, and regains its original performance after intense mechanical extension, even if it is partially cut or damaged. Owing to the great electronegativity of PVDFNM, the device generated a maximum voltage of 225 V and a current of 4.5 μA with an electrode area of 6 × 1 cm². The S-TENG has great potential applications in self-powered wearable devices, electronic skins, and smart sensor networks

All-Nanofiber-Based Ultralight Stretchable Triboelectric Nanogenerator for Self-Powered Wearable Electronics

The flexible and stretchable electronics have been considered as next-generation electronics. Stretchable triboelectric nanogenerators (S-TENGs) with both multifunction and comfort have become a hot field of research for wearable electronic devices recently. Here, we designed an all-nanofiber-based, ultralight, S-TENG that could be softly attached on skins for motion energy harvesting and self-powered biomechanical monitoring. The S-TENG consisted of only two nanofiber membranes: a polyvinylidene fluoride nanofiber membrane (PVDFNM) supported by thermoplastic polyurethane nanofiber membrane (TPUNM) was used as the frictional layer, and a multiwalled carbon nanotube (MWCNT) conductive material screen-printed on the TPUNM was used as the electrode layer. Due to the excellent stretchability of TPUNM, the S-TENG could generate electricity under various types of deformation, and regains its original performance after intense mechanical extension, even if it is partially cut or damaged. Owing to the great electronegativity of PVDFNM, the device generated a maximum voltage of 225 V and a current of 4.5 μA with an electrode area of 6 × 1 cm². The S-TENG has great potential applications in self-powered wearable devices, electronic skins, and smart sensor networks