Chemisorption on a model bcc metal

The system considered here is that of a single atom with one energy level chemisorbed on the (001) surface of a model bcc metal. We present the change in the density of electronic states Δn (E) due to chemisorption for two cases: one when the adatom is bound to a single substrate atom in the "on‐site" configuration and the other when it is bound to four substrate atoms in the "centered fourfold site." In principle, this change in the density of states Δn can be related to the results of photoemission measurements

Adjustment of the basin-scale circulation at 26 degrees N to variations in Gulf Stream, deep western boundary current and Ekman transports as observed by the Rapid array

The Rapid instrument array across the Atlantic Ocean along 26 degrees N provides unprecedented monitoring of the basin-scale circulation. A unique feature of the Rapid array is the combination of full-depth moorings with instruments measuring temperature, salinity, pressure time series at many depths with co-located bottom pressure measurements so that dynamic pressure can be measured from surface to bottom. Bottom pressure measurements show a zonally uniform rise (and fall) of bottom pressure of 0.015 dbar on a 5 to 10 day time scale, suggesting that the Atlantic basin is filling and draining on a short time scale. After removing the zonally uniform bottom pressure fluctuations, bottom pressure variations at 4000 m depth against the western boundary compensate instantaneously for baroclinic fluctuations in the strength and structure of the deep western boundary current so there is no basin-scale mass imbalance resulting from variations in the deep western boundary current. After removing the mass compensating bottom pressure, residual bottom pressure fluctuations at the western boundary just east of the Bahamas balance variations in Gulf Stream transport. Again the compensation appears to be especially confined close to the western boundary. Thus, fluctuations in either Gulf Stream or deep western boundary current transports are compensated in a depth independent (barotropic) manner very close to the continental slope off the Bahamas. In contrast, compensation for variations in wind-driven surface Ekman transport appears to involve fluctuations in both western basin and eastern basin bottom pressures, though the bottom pressure difference fluctuations appear to be a factor of 3 too large, perhaps due to an inability to resolve small bottom pressure fluctuations after removal of larger zonal average, baroclinic, and Gulf Stream pressure components. For 4 tall moorings where time series dynamic height (geostrophic pressure) profiles can be estimated from sea surface to ocean bottom and bottom pressure can be added, there is no general correlation between surface dynamic height and bottom pressure. Dynamic height on each mooring is strongly correlated with sea surface height from satellite observations and the variability in both dynamic height and satellite sea surface height decrease sharply as the western boundary is approached

Performance of alumina-supported Pt catalysts in an electron-beam-sustained CO2 laser amplifier

The performance of an alumina-supported Pt catalyst system used to maintain the gas purity in an electron-beam-sustained (636) isotope CO2 laser amplifier has been tested. The system characteristics using the two-zone, parallel flow reactor were determined for both continuous- and end-of-day reactor operation using on-line mass spectrometric sampling. The laser amplifier was run with an energy loading of typically 110 J-l/atm and an electron-beam current of 4 mA/sq cm. With these conditions and a pulse repetition frequency of 10 Hz for up to 10,000 shots, increases on the order of 100 ppm O2 were observed with the purifier on and 150 ppm with it off. The 1/e time recovery time was found to be approximately 75 minutes

Technique for studying chemisorption on substrates with complex band structures

Abstract Unavailabl

Silicon mirror suspensions for gravitational wave detectors

One of the most significant limits to the sensitivity of current, and future, long-baseline interferometric gravitational wave detectors is thermal displacement noise of the test masses and their suspensions. This paper reports results of analytical and experimental studies of the limits to thermal noise performance of cryogenic silicon test mass suspensions set by two constraints on suspension fibre dimensions: the minimum dimensions required to allow conductive cooling for extracting incident laser beam heat deposited in the mirrors; and the minimum dimensions of fibres (set by their tensile strength) which can support test masses of the size envisaged for use in future detectors. We report experimental studies of breaking strength of silicon ribbons, and resulting design implications for the feasibility of suspension designs for future gravitational wave detectors using silicon suspension fibres. We analyse the implication of this study for thermal noise performance of cryogenically cooled silicon suspensions

The calibration of photographic and spectroscopic films: Reciprocity failure and thermal responses of IIaO film at liquid nitrogen temperatures

Reciprocity failure was examined for IIaO spectroscopic film. The results indicate reciprocity failure occurs at three distinct minimum points in time; 15 min, 30 min and 90 min. The results are unique because theory suggests only one minimum reciprocity failure point should occur. When incubating 70mm IIaO film for 15 and 30 min at temperatures of 30, 40, 50, and 60 C and then placing in a liquid nitrogen bath at a temperature of -190 C the film demonstrated an increase of the optical density when developed at a warm-up time of 30 min. Longer warm-up periods of 1, 2 and 3 hrs yield a decrease in optical density of the darker wedge patterns; whereas, shorter warm-up times yield an overall increase in the optical densities

No evidence for feedback: Unexceptional Low-ionization winds in Host galaxies of Low Luminosity Active Galactic Nuclei at Redshift z ~1

We study winds in 12 X-ray AGN host galaxies at z ~ 1. We find, using the low-ionization Fe II 2586 absorption in the stacked spectra, that the probability distribution function (PDF) of the centroid velocity shift in AGN has a median, 16th and 84th percentiles of (-87, -251, +86) km/s respectively. The PDF of the velocity dispersion in AGN has a median, 84th and 16th percentile of (139, 253, 52) km/s respectively. The centroid velocity and the velocity dispersions are obtained from a two component (ISM+wind) absorption line model. The equivalent width PDF of the outflow in AGN has median, 84th and 16th percentiles of (0.4, 0.8, 0.1) Angstrom. There is a strong ISM component in Fe II 2586 absorption with (1.2, 1.5, 0.8) Angstrom, implying presence of substantial amount cold gas in the host galaxies. For comparison, star-forming and X-ray undetected galaxies at a similar redshift, matched roughly in stellar mass and galaxy inclination, have a centroid velocity PDF with percentiles of (-74, -258, +90) km/s, and a velocity dispersion PDF percentiles of (150, 259, 57) km/s. Thus, winds in the AGN are similar to star-formation-driven winds, and are too weak to escape and expel substantial cool gas from galaxies. Our sample doubles the previous sample of AGN studied at z ~ 0.5 and extends the analysis to z ~ 1. A joint reanalysis of the z ~ 0.5 AGN sample and our sample yields consistent results to the measurements above.Comment: 24 pages, 11 figures, accepted in Ap

A prototype system for observing the Atlantic Meridional Overturning Circulation - scientific basis, measurement and risk mitigation strategies, and first results

The Atlantic Meridional Overturning Circulation (MOC) carries up to one quarter of the global northward heat transport in the Subtropical North Atlantic. A system monitoring the strength of the MOC volume transport has been operating since April 2004. The core of this system is an array of moored sensors measuring density, bottom pressure and ocean currents. A strategy to mitigate risks of possible partial failures of the array is presented, relying on backup and complementary measurements. The MOC is decomposed into five components, making use of the continuous moored observations, and of cable measurements across the Straits of Florida, and wind stress data. The components compensate for each other, indicating that the system is working reliably. The year-long average strength of the MOC is 18.7±5.6 Sv, with wind-driven and density-inferred transports contributing equally to the variability. Numerical simulations suggest that the surprisingly fast density changes at the western boundary are partially linked to westward propagating planetary wave

Mid-infrared spectroscopy as a potential tool for reconstructing lake salinity

Many aquatic ecosystems in Australia are impacted or threatened by salinisation; however, there is a paucity of records detailing the changes in salinity of individual water bodies that extend beyond a few decades. One way to overcome this issue is the use of inference models, which have typically been based on biological proxies. This pilot project investigates the potential for mid-infrared spectroscopy (MIRS) to provide an alternative method of reconstructing past salinity levels in Australian lakes. A small (19 lakes) calibration dataset was used to develop a MIRS-based lake water salinity inference model (measured vs. inferred salinity, based on leave-one-out cross-validation, R2 = 0.64). This model and a previously published diatom–salinity model were both used to infer salinity levels in Tower Hill Lake in south-eastern Australia, over the last 60 years. Comparisons between these reconstructions and measured salinity data from Tower Hill Lake indicate that salinities inferred by the MIRS model more closely resembled the measured values than those produced using the diatom model, predominantly in terms of the actual values inferred, but also with regard to the trends observed. This supports the hypothesis that MIRS can provide a valuable new tool for reconstructing lake salinity.Laura Cunningham, John Tibby, Sean Forrester, Cameron Barr and Jan Skjemsta