77 research outputs found

    Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products

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    The solid electrolyte interphase (SEI) passivating layer that grows on all battery electrodes during cycling is critical to the long-term capacity retention of lithium-ion batteries. Yet, it is inherently difficult to study because of its nanoscale thickness, amorphous composite structure, and air sensitivity. Here, we employ an experimental strategy using <sup>1</sup>H, <sup>7</sup>Li, <sup>19</sup>F, and <sup>13</sup>C solid-state nuclear magnetic resonance (ssNMR) to gain insight into the decomposition products in the SEI formed on silicon electrodes, the uncontrolled growth of the SEI representing a major failure mechanism that prevents the practical use of silicon in lithium-ion batteries. The voltage dependent formation of the SEI is confirmed, with the SEI growth correlating with irreversible capacity. By studying both conductive carbon and mixed Si/C composite electrodes separately, a correlation with increased capacity loss of the composite system and the low-voltage silicon plateau is demonstrated. Using selective <sup>13</sup>C labeling, we detect decomposition products of the electrolyte solvents ethylene carbonate (EC) and dimethyl carbonate (DMC) independently. EC decomposition products are present in higher concentrations and are dominated by oligomer species. Lithium semicarbonates, lithium fluoride, and lithium carbonate products are also seen. Ab initio calculations have been carried out to aid in the assignment of NMR shifts. ssNMR applied to both rinsed and unrinsed electrodes show that the organics are easily rinsed away, suggesting that they are located on the outer layer of the SEI

    Preventing Structural Rearrangements on Battery Cycling: A First-Principles Investigation of the Effect of Dopants on the Migration Barriers in Layered Li<sub>0.5</sub>MnO<sub>2</sub>

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    Layered LiMnO<sub>2</sub> is a potential Li ion cathode material that is known to undergo a layered to spinel transformation upon delithiation, as a result of Mn migration. A common strategy to improve the structural stability of LiMnO<sub>2</sub> has been to replace Mn with a range of metal dopants, although the mechanism by which each dopant stabilizes the structure is not well understood. In this work we characterize ion-migration barriers using hybrid eigenvector-following (EF) and density functional theory to study how trivalent dopants (Al<sup>3+</sup>, Cr<sup>3+</sup>, Fe<sup>3+</sup>, Ga<sup>3+</sup>, Sc<sup>3+</sup>, and In<sup>3+</sup>) affect Mn migration during the initial stage of the layered to spinel transformation in Li<sub>0.5</sub>MnO<sub>2</sub>. We demonstrate that dopants with small ionic radii, such as Al<sup>3+</sup> and Cr<sup>3+</sup>, can increase the barrier for migration, but only when they are located in the first cation coordination sphere of Mn. We also demonstrate how the hybrid EF approach can be used to study the migration barriers of dopant species within the structure of Li<sub>0.5</sub>MnO<sub>2</sub> efficiently. The transition state searching methodology described in this work will be useful for studying the effects of dopants on structural transformation mechanisms in a wide range of technologically interesting energy materials

    Insights into Electrochemical Sodium Metal Deposition as Probed with <i>in Situ</i> <sup>23</sup>Na NMR

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    Sodium batteries have seen a resurgence of interest from researchers in recent years, owing to numerous favorable properties including cost and abundance. Here we examine the feasibility of studying this battery chemistry with <i>in situ</i> NMR, focusing on Na metal anodes. Quantification of the NMR signal indicates that Na metal deposits with a morphology associated with an extremely high surface area, the deposits continually accumulating, even in the case of galvanostatic cycling. Two regimes for the electrochemical cycling of Na metal are apparent that have implications for the use of Na anodes: at low currents, the Na deposits are partially removed on reversing the current, while at high currents, there is essentially no removal of the deposits in the initial stages. At longer times, high currents show a significantly greater accumulation of deposits during cycling, again indicating a much lower efficiency of removal of these structures when the current is reversed

    Probing Cation and Vacancy Ordering in the Dry and Hydrated Yttrium-Substituted BaSnO<sub>3</sub> Perovskite by NMR Spectroscopy and First Principles Calculations: Implications for Proton Mobility

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    Hydrated BaSn<sub>1ā€“<i>x</i></sub>Y<sub><i>x</i></sub>O<sub>3ā€“<i>x</i>/2</sub> is a protonic conductor that, unlike many other related perovskites, shows high conductivity even at high substitution levels. A joint multinuclear NMR spectroscopy and density functional theory (total energy and GIPAW NMR calculations) investigation of BaSn<sub>1ā€“<i>x</i></sub>Y<sub><i>x</i></sub>O<sub>3ā€“<i>x</i>/2</sub> (0.10 ā‰¤ <i>x</i> ā‰¤ 0.50) was performed to investigate cation ordering and the location of the oxygen vacancies in the dry material. The DFT energetics show that Y doping on the Sn site is favored over doping on the Ba site. The <sup>119</sup>Sn chemical shifts are sensitive to the number of neighboring Sn and Y cations, an experimental observation that is supported by the GIPAW calculations and that allows clustering to be monitored: Y substitution on the Sn sublattice is close to random up to <i>x</i> = 0.20, while at higher substitution levels, Yā€“Oā€“Y linkages are avoided, leading, at <i>x</i> = 0.50, to strict Yā€“Oā€“Sn alternation of B-site cations. These results are confirmed by the absence of a ā€œYā€“Oā€“Yā€ <sup>17</sup>O resonance and supported by the <sup>17</sup>O NMR shift calculations. Although resonances due to six-coordinate Y cations were observed by <sup>89</sup>Y NMR, the agreement between the experimental and calculated shifts was poor. Five-coordinate Sn and Y sites (i.e., sites next to the vacancy) were observed by <sup>119</sup>Sn and <sup>89</sup>Y NMR, respectively, these sites disappearing on hydration. More five-coordinated Sn than five-coordinated Y sites are seen, even at <i>x</i> = 0.50, which is ascribed to the presence of residual Snā€“Oā€“Sn defects in the cation-ordered material and their ability to accommodate O vacancies. High-temperature <sup>119</sup>Sn NMR reveals that the O ions are mobile above 400 Ā°C, oxygen mobility being required to hydrate these materials. The high protonic mobility, even in the high Y-content materials, is ascribed to the Yā€“Oā€“Sn cation ordering, which prevents proton trapping on the more basic Yā€“Oā€“Y sites

    The Morphology of TiO<sub>2</sub> (B) Nanoparticles

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    The morphology of a nanomaterial (geometric shape and dimension) has a significant impact on its physical and chemical properties. It is, therefore, essential to determine the morphology of nanomaterials so as to link shape with performance in specific applications. In practice, structural features with different length scales are encoded in a specific angular range of the X-ray or neutron total scattering pattern of the material. By combining small- and wide-angle scattering (typically X-ray) experiments, the full angular range can be covered, allowing structure to be determined accurately at both the meso- and the nanoscale. In this Article, a comprehensive morphology analysis of lithium-ion battery anode material, TiO<sub>2</sub> (B) nanoparticles (described in Ren, Y.; Liu, Z.; Pourpoint, F.; Armstrong, A. R.; Grey, C. P.; Bruce, P. G. <i>Angew. Chem. Int. Ed.</i> <b>2012</b>, <i>51</i>, 2164), incorporating structure modeling with small-angle X-ray scattering (SAXS), pair distribution function (PDF), and X-ray powder diffraction (XRPD) techniques, is presented. The particles are oblate-shaped, contracted along the [010] direction, this particular morphology providing a plausible rationale for the excellent electrochemical behavior of these TiO<sub>2</sub>(B) nanoparticles, while also provides a structural foundation to model the strain-driven distortion induced by lithiation. The work demonstrates the importance of analyzing various structure features at multiple length scales to determine the morphologies of nanomaterials

    Identification of Cation Clustering in Mgā€“Al Layered Double Hydroxides Using Multinuclear Solid State Nuclear Magnetic Resonance Spectroscopy

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    A combined X-ray diffraction and magic angle spinning nuclear magnetic resonance (MAS NMR) study of a series of layered double hydroxides (LDHs) has been utilized to identify cation clustering in the metal hydroxide layers. High resolution (multiple quantum, MQ) <sup>25</sup>Mg NMR spectroscopy was successfully used to resolve different Mg local environments in nitrate and carbonate-containing layered double hydroxides with various Al for Mg substitution levels, and it provides strong evidence for cation ordering schemes based around Alā€“Al avoidance (in agreement with <sup>27</sup>Al NMR), the ordering increasing with an increase in Al content. <sup>1</sup>H MAS double quantum NMR spectroscopy verified the existence of small Mg<sub>3</sub>OH and Mg<sub>2</sub>AlOH clusters within the same metal hydroxide sheet and confirmed that the cations gradually order as the Al concentration is increased to form a honeycomb-like Al distribution throughout the metal hydroxide layer. The combined use of these multinuclear NMR techniques provides a structural foundation with which to rationalize the effects of different cation distributions on properties such as anion binding and retention in this class of materials

    Materialsā€™ Methods: NMR in Battery Research

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    Improving electrochemical energy storage is one of the major issues of our time. The search for new battery materials together with the drive to improve performance and lower cost of existing and new batteries is not without its challenges. Success in these matters is undoubtedly based on first understanding the underlying chemistries of the materials and the relations between the components involved. A combined application of experimental and theoretical techniques has proven to be a powerful strategy to gain insights into many of the questions that arise from the ā€œhow do batteries work and why do they failā€ challenge. In this Review, we highlight the application of solid-state nuclear magnetic resonance (NMR) spectroscopy in battery research: a technique that can be extremely powerful in characterizing local structures in battery materials, even in highly disordered systems. An introduction on electrochemical energy storage illustrates the research aims and prospective approaches to reach these. We particularly address ā€œNMR in battery researchā€ by giving a brief introduction to electrochemical techniques and applications as well as background information on both <i>in</i> and <i>ex situ</i> solid-state NMR spectroscopy. We will try to answer the question ā€œIs NMR suitable and how can it help me to solve my problem?ā€ by shortly reviewing some of our recent research on electrodes, microstructure formation, electrolytes and interfaces, in which the application of NMR was helpful. Finally, we share hands-on experience directly from the lab bench to answer the fundamental question ā€œWhere and how should I start?ā€ to help guide a researcherā€™s way through the manifold possible approaches

    Understanding the Conduction Mechanism of the Protonic Conductor CsH<sub>2</sub>PO<sub>4</sub> by Solid-State NMR Spectroscopy

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    Local dynamics and hydrogen bonding in CsH<sub>2</sub>PO<sub>4</sub> have been investigated by <sup>1</sup>H, <sup>2</sup>H, and <sup>31</sup>P solid-state NMR spectroscopy to help provide a detailed understanding of proton conduction in the paraelectric phase. Two distinct environments are observed by <sup>1</sup>H and <sup>2</sup>H NMR, and their chemical shifts (<sup>1</sup>H) and quadrupolar coupling constants (<sup>2</sup>H) are consistent with one strong and one slightly weaker H-bonding environment. Two different protonic motions are detected by variable-temperature <sup>1</sup>H MAS NMR and <i>T</i><sub>1</sub> spinā€“lattice relaxation time measurements in the paraelectric phase, which we assign to librational and long-range translational motions. An activation energy of 0.70 Ā± 0.07 eV is extracted for the latter motion; that of the librational motion is much lower. <sup>31</sup>P NMR line shapes are measured under MAS and static conditions, and spinā€“lattice relaxation time measurements have been performed as a function of temperature. Although the <sup>31</sup>P line shape is sensitive to the protonic motion, the reorientation of the phosphate ions does not lead to a significant change in the <sup>31</sup>P CSA tensor. Rapid protonic motion and rotation of the phosphate ions is seen in the superprotonic phase, as probed by the <i>T</i><sub>1</sub> measurements along with considerable line narrowing of both the <sup>1</sup>H and the <sup>31</sup>P NMR signals
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