Mechanical Chameleon through Dynamic Real-Time Plasmonic Tuning

The development of camouflage methods, often through a general resemblance to the background, has recently become a subject of intense research. However, an artificial, active camouflage that provides fast response to color change in the full-visible range for rapid background matching remains a daunting challenge. To this end, we report a method, based on the combination of bimetallic nanodot arrays and electrochemical bias, to allow for plasmonic modulation. Importantly, our approach permits real-time light manipulation readily matchable to the color setting in a given environment. We utilize this capability to fabricate a biomimetic mechanical chameleon and an active matrix display with dynamic color rendering covering almost the entire visible region

Ultrafast Self-Healing Nanocomposites via Infrared Laser and Their Application in Flexible Electronics

The continuous evolution toward flexible electronics with mechanical robust property and restoring structure simultaneously places high demand on a set of polymeric material substrate. Herein, we describe a composite material composed of a polyurethane based on Diels–Alder chemistry (PU-DA) covalently linked with functionalized graphene nanosheets (FGNS), which shows mechanical robust and infrared (IR) laser self-healing properties at ambient conditions and is therefore suitable for flexible substrate applications. The mechanical strength can be tuned by varying the amount of FGNS and breaking strength can reach as high as 36 MPa with only 0.5 wt % FGNS loading. On rupture, the initial mechanical properties are restored with more than 96% healing efficiency after 1 min irradiation time by 980 nm IR laser. Especially, this is the highest value of healing efficiency reported in the self-healable materials based on DA chemistry systems until now, and the composite exhibits a high volume resistivity up to 5.6 × 10¹¹ Ω·cm even the loading of FGNS increased to 1.0 wt %. Moreover, the conductivity of the broken electric circuit which was fabricated by silver paste drop-cast on the healable composite substrate was completely recovered via IR laser irradiating bottom substrate mimicking human skin. These results demonstrate that the FGNS-PU-DA nanocomposite can be used as self-healing flexible substrate for the next generation of intelligent flexible electronics

High-Strength, Tough, Fatigue Resistant, and Self-Healing Hydrogel Based on Dual Physically Cross-Linked Network

Hydrogels usually suffer from low mechanical strength, which largely limit their application in many fields. In this Research Article, we prepared a dual physically cross-linked hydrogel composed of poly­(acrylamide-<i>co</i>-acrylic acid) (PAM-<i>co</i>-PAA) and poly­(vinyl alcohol) (PVA) by simple two-steps methods of copolymerization and freezing/thawing. The hydrogen bond-associated entanglement of copolymer chains formed as cross-linking points to construct the first network. After being subjected to the freezing/thawing treatment, PVA crystalline domains were formed to serve as knots of the second network. The hydrogels were demonstrated to integrate strength and toughness (1230 ± 90 kPa and 1250 ± 50 kJ/m³) by the introduction of second physically cross-linked network. What̀s more, the hydrogels exhibited rapid recovery, excellent fatigue resistance, and self-healing property. The dynamic property of the dual physically cross-linked network contributes to the excellent energy dissipation and self-healing property. Therefore, this work provides a new route to understand the toughness mechanism of dual physically cross-linked hydrogels, hopefully promoting current hydrogel research and expanding their applications