Our astrochemical heritage

Our Sun and planetary system were born about 4.5 billion years ago. How did this happen and what is our heritage from these early times? This review tries to address these questions from an astrochemical point of view. On the one hand, we have some crucial information from meteorites, comets and other small bodies of the Solar System. On the other hand, we have the results of studies on the formation process of Sun-like stars in our Galaxy. These results tell us that Sun-like stars form in dense regions of molecular clouds and that three major steps are involved before the planet formation period. They are represented by the pre-stellar core, protostellar envelope and protoplanetary disk phases. Simultaneously with the evolution from one phase to the other, the chemical composition gains increasing complexity. In this review, we first present the information on the chemical composition of meteorites, comets and other small bodies of the Solar System, which is potentially linked to the first phases of the Solar System's formation. Then we describe the observed chemical composition in the pre-stellar core, protostellar envelope and protoplanetary disk phases, including the processes that lead to them. Finally, we draw together pieces from the different objects and phases to understand whether and how much we inherited chemically from the time of the Sun's birth.Comment: Invited review to be published in "The Astronomy and Astrophysics Review

International specialization models in Latin America: the case of Argentina

The paper compares the Argentine specialization model with that of the other major Latin American countries. Given the lack of production data at disaggregate level, we rely on trade flow information from the WTA Statistics Canada database (3-digit SITC classification), available for most Latin American countries for a rather long time span (1980-2000). Our analysis, based on the Lafay Index of international specialization, shows that Argentina concentrates its comparative advantages in raw materials, agricultural and food products and exhibits, at the same time, serious deficiencies in the production of manufactures. This specialization pattern has remained remarkably stable over the last two decades, in spite of the major reforms implemented in many different fields. These features are shared with the other major Latin American countries, with the notable exception of Mexico, whose comparative advantages have changed dramatically in the same period, from raw materials (essentially oil) towards manufactures. Moreover, the products in which Argentina is specialized are among those for which world demand growth is structurally lower; this could eventually lead to a decreasing weight of Argentina in international markets.International trade; specialization model; revealed comparative advantages

ICT accumulation and productivity growth in the United States: an analysis based on industry data

The paper analyses labour productivity and total factor productivity (TFP) dynamics in the United States using new data at the industry level on information and communications technology (ICT) catapital stock in both manufacturing and the services sector. In manufacturing, a growth accounting exercise confirms that the contribution to labour productivity of ICT accumulation has been higher in the second half of the nineties than in 1973-95. TFP has also been accelerating, even controlling for cyclical output fluctuations, especially in ICT intensive industries. We have also found evidence of a recent direct effect on TFP growth of ICT intensity, though only in ICT intensive industries. In the services sector a direct effect of ICT accumulation on the acceleration of labour productivity could be detected through both a growth accounting exercise and estimating a value added function. Moreover, we also have found evidence of a significant TFP acceleration after 1996, even controlling for cyclical effects. Econometric evidence supporting a positive effect of ICT accumulation on TFP growth is still rather weak, though some signs have emerged that computers accumulation has positively affected TFP dynamics in recent years.ICT, growth accounting

Chemistry and Radiative Transfer of Water in Cold, Dense Clouds

The Herschel Space Observatory's recent detections of water vapor in the cold, dense cloud L1544 allow a direct comparison between observations and chemical models for oxygen species in conditions just before star formation. We explain a chemical model for gas phase water, simplified for the limited number of reactions or processes that are active in extreme cold ($<$ 15 K). In this model, water is removed from the gas phase by freezing onto grains and by photodissociation. Water is formed as ice on the surface of dust grains from O and OH and released into the gas phase by photodesorption. The reactions are fast enough with respect to the slow dynamical evolution of L1544 that the gas phase water is in equilibrium for the local conditions thoughout the cloud. We explain the paradoxical radiative transfer of the H$_2$O ($1_{10}-1_{01}$) line. Despite discouragingly high optical depth caused by the large Einstein A coefficient, the subcritical excitation in the cold, rarefied H$_2$ causes the line brightness to scale linearly with column density. Thus the water line can provide information on the chemical and dynamical processes in the darkest region in the center of a cold, dense cloud. The inverse P-Cygni profile of the observed water line generally indicates a contracting cloud. This profile is reproduced with a dynamical model of slow contraction from unstable quasi-static hydrodynamic equilibrium (an unstable Bonnor-Ebert sphere).Comment: submitted to MNRA

Chemical processes in star forming regions

This paper will review the basic concepts of gas-phase and grain surface chemistry of dense molecular clouds, where low mass and high mass stars form. The chemistry of cold pre-stellar cloud cores, where molecular freeze-out and deuterium fractionation dominate, will be presented. Then, following cloud evolution after protostellar birth, hot core and shock chemistry will be discussed in view of recent observations. A brief summary of the chemistry in protoplanetary disks will also be furnished. The aim is to identify important gas tracers in the various steps of the star formation process, pointing out the main problems still open in the field of astrochemistry.Comment: Review article to appear in proceedings of the "Cores to Clusters" meeting held in Porto, Portugal, October 200

Effect of Grain Size on Differential Desorption of Volatile Species and on Non-ideal MHD Diffusivity

We developed a chemical network for modeling the chemistry and non-ideal MHD effects from the collapsing dense molecular clouds to protostellar disks. First, we re-formulated the cosmic-ray desorption rate by considering the variations of desorption rate over the grain size distribution. We find that the differential desorption of volatile species is amplified by the grains larger than 0.1 $\mu$m, because larger grains are heated to a lower temperature by cosmic-rays and hence more sensitive to the variations in binding energies. As a result, atomic nitrogen N is $\sim$2 orders of magnitude more abundant than CO; N$_2$H$^+$ also becomes a few times more abundant than HCO$^+$ due to the increased gas-phase N$_2$. However, the changes in ionization fraction due to freeze-out and desorption only have minor effects on the non-ideal MHD diffusivities. Our chemical network confirms that the very small grains (VSGs: below a few 100 $\AA$) weakens the efficiency of both ambipolar diffusion and Hall effect. In collapsing dense cores, a maximum ambipolar diffusion is achieved when truncating the MRN size distribution at 0.1 $\mu$m, and for a maximum Hall effect, the truncation occurs at 0.04 $\mu$m. We conclude that the grain size distribution is crucial to the differential depletion between CO and N$_2$ related molecules, as well as to the non-ideal MHD diffusivities in dense cores.Comment: 15 pages, 11 figures; Submitted to MNRA

Interstellar dust charging in dense molecular clouds: cosmic ray effects

The local cosmic-ray (CR) spectra are calculated for typical characteristic regions of a cold dense molecular cloud, to investigate two so far neglected mechanisms of dust charging: collection of suprathermal CR electrons and protons by grains, and photoelectric emission from grains due to the UV radiation generated by CRs. The two mechanisms add to the conventional charging by ambient plasma, produced in the cloud by CRs. We show that the CR-induced photoemission can dramatically modify the charge distribution function for submicron grains. We demonstrate the importance of the obtained results for dust coagulation: While the charging by ambient plasma alone leads to a strong Coulomb repulsion between grains and inhibits their further coagulation, the combination with the photoemission provides optimum conditions for the growth of large dust aggregates in a certain region of the cloud, corresponding to the densities $n(\mathrm{H_2})$ between $\sim10^4$ cm$^{-3}$ and $\sim10^6$ cm$^{-3}$. The charging effect of CR is of generic nature, and therefore is expected to operate not only in dense molecular clouds but also in the upper layers and the outer parts of protoplanetary discs.Comment: accepted by Ap

Detection of (15)NNH+ in L1544: non-LTE modelling of dyazenilium hyperfine line emission and accurate (14)N/(15)N values

Samples of pristine Solar System material found in meteorites and interplanetary dust particles are highly enriched in (15)N. Conspicuous nitrogen isotopic anomalies have also been measured in comets, and the (14)N/(15)N abundance ratio of the Earth is itself larger than the recognised pre-solar value by almost a factor of two. Ion--molecules, low-temperature chemical reactions in the proto-solar nebula have been repeatedly indicated as responsible for these (15)N-enhancements. We have searched for (15)N variants of the N2H+ ion in L1544, a prototypical starless cloud core which is one of the best candidate sources for detection owing to its low central core temperature and high CO depletion. The goal is the evaluation of accurate and reliable (14)N/(15)N ratio values for this species in the interstellar gas. A deep integration of the (15)NNH+ (1-0) line at 90.4 GHz has been obtained with the IRAM 30 m telescope. Non-LTE radiative transfer modelling has been performed on the J=1-0 emissions of the parent and (15)N-containing dyazenilium ions, using a Bonnor--Ebert sphere as a model for the source. A high-quality fit of the N2H+ (1--0) hyperfine spectrum has allowed us to derive a revised value of the N2H+ column density in L1544. Analysis of the observed N(15)NH+ and (15)NNH+ spectra yielded an abundance ratio N[N(15)NH+]/N[(15)NNH+] = 1.1 +/- 0.3. The obtained (14)N/(15)N ratio is ~ 1000 +/- 200, suggestive of a sizeable (15)N depletion in this molecular ion. Such a result is not consistent with the prediction of present nitrogen chemical models. As chemical models predict large (15)N fractionation of N2H+, we suggest that (15)N(14)N, or (15)N in some other molecular form, is preferentially depleted onto dust grains.Comment: 12 pages, 9 figures, manuscript accepted in A&