Template-Directed Olefin Cross Metathesis

A template containing two secondary dialkylammonium ion recognition sites for encirclement by olefin-bearing dibenzo[24]crown-8 derivatives has been used to promote olefin cross metatheses with ruthenium-alkylidene catalysts. For monoolefin monomers, the rates of metatheses and yields of the dimers are both amplified in the presence of the template. Likewise, for a diolefin monomer, the yield of the dimer is enhanced in the presence of the template under conditions where higher oligomers are not formed

Magic Ring Catenation by Olefin Metathesis

Olefin metathesis has been employed in the efficient syntheses of a [2]catenane with the templation being provided by the recognition between a secondary ammonium ion and a crown ether. In one approach, a crown ether precursor has been clipped around an NH2+ center situated in a macrocyclic ring, yielding the mechanically interlocked compound. In the other approach, the reversible nature of olefin metathesis allows for a magic ring synthesis to occur wherein two free macrocycles can be employed as the stationary materials, leading to the formation of the same [2]catenane

A Lagerstätte from Australia provides insight into the nature of Miocene mesic ecosystems

Reduced precipitation in the Miocene triggered the geographic contraction of rainforest ecosystems around the world. In Australia, this change was particularly pronounced; mesic rainforest ecosystems that once dominated the landscape transformed into the shrublands, grasslands, and deserts of today. A lack of well-preserved fossils has made it difficult to understand the nature of Australian ecosystems before the aridification. Here, we report on an exceptionally well-preserved rainforest biota from New South Wales, Australia. This Konservat-Lagerstätte hosts a rich diversity of microfossils, plants, insects, spiders, and vertebrate remains preserved in goethite. We document evidence for several species interactions including predation, parasitism, and pollination. The fossils are indicative of an oxbow lake in a mesic rainforest and suggest that rainforest distributions have shifted since the Miocene. The variety of fossils preserved, together with high fidelity of preservation, allows for unprecedented insights into the mesic ecosystems that dominated Australia during the Miocene

On becoming (un)committed: A taxonomy and test of newcomer on-boarding scenarios

How does the bond between the newcomer and the organization develop over time? Process research on temporal patterns of newcomer's early commitment formation has been very scarce because theory and appropriate longitudinal research designs in this area are lacking. From extant research we extract three process-theoretical accounts regarding how the newcomer adjustment process evolves over time: (1) Learning to Love; (2) Honeymoon Hangover; and (3) High Match, Moderate Match, or Low Match. From these scenarios we develop a taxonomy of newcomer adjustment scenarios. Further, we empirically verify these different scenarios by examining naturally occurring "trajectory classes," which are found to display strengthening, weakening, or stabilizing of the employee-organization linkage. For this, we use a sample of 72 Ph. D. graduates whose organizational commitment history was recorded in their first 25 consecutive weeks of new employment. In closing, we discuss the theoretical and practical implications of the scenario-based approach

Combined search for the Standard Model Higgs boson in pppp collisions at s=7\sqrt{s} = 7 TeV with the ATLAS detector

A combined search for the Standard Model Higgs boson with the ATLAS detector at the LHC is presented. The datasets used correspond to integrated luminosities from 4.6 fb^-1 to 4.9 fb^-1 of proton-proton collisions collected at sqrt(s) = 7 TeV in 2011. The Higgs boson mass ranges of 111.4 GeV to 116.6 GeV, 119.4 GeV to 122.1 GeV, and 129.2 GeV to 541 GeV are excluded at the 95% confidence level, while the range 120 GeV to 560 GeV is expected to be excluded in the absence of a signal. An excess of events is observed at Higgs boson mass hypotheses around 126 GeV with a local significance of 2.9 standard deviations (sigma). The global probability for the background to produce an excess at least as significant anywhere in the entire explored Higgs boson mass range of 110-600 GeV is estimated to be ~15%, corresponding to a significance of approximately one sigma.Peer Reviewe

Measurement of the differential cross-section of B+B^{+} meson production in pp collisions at s\sqrt{s} = 7 TeV at ATLAS

The production cross-section of B+ mesons is measured as a function of transverse momentum pT and rapidity y in proton--proton collisions at center-of-mass energy sqrt(s) = 7 TeV, using 2.4 fb-1 of data recorded with the ATLAS detector at the Large Hadron Collider. The differential production cross-sections, determined in the range 9<pT<120 GeV and y<2.25, are compared to next-to-leading-order theoretical predictions.Peer Reviewe

Study of heavy-flavor quarks produced in association with top-quark pairs at s=7\sqrt{s}=7 TeV using the ATLAS detector

Using a sample of dilepton top-quark pair ($t\bar{t}$) candidate events, a study is performed of the production of top-quark pairs together with heavy-flavor (HF) quarks, the sum of $t\bar{t}+b+X$ and $t\bar{t}$+c+X, collectively referred to as $t\bar{t}$ + HF. The data set used corresponds to an integrated luminosity of 4.7  $fb{−1}$ of proton-proton collisions at a center-of-mass energy of 7 TeV recorded by the ATLAS detector at the CERN Large Hadron Collider. The presence of additional HF (b or c) quarks in the $t\bar{t}$ sample is inferred by looking for events with at least three b-tagged jets, where two are attributed to the b quarks from the $t\bar{t}$ decays and the third to additional HF production. The dominant background to $t\bar{t}$ + HF in this sample is $t\bar{t}$+jet events in which a light-flavor jet is misidentified as a heavy-flavor jet. To determine the heavy- and light-flavor content of the additional b-tagged jets, a fit to the vertex mass distribution of b-tagged jets in the sample is performed. The result of the fit shows that 79 ± 14 (stat) ± 22 (syst) of the 105 selected extra b-tagged jets originate from HF quarks, 3 standard deviations away from the hypothesis of zero $t\bar{t}$+ HF production. The result for extra HF production is quoted as a ratio (RHF) of the cross section for $t\bar{t}$ + HF production to the cross section for $t\bar{t}$ production with at least one additional jet. Both cross sections are measured in a fiducial kinematic region within the ATLAS acceptance. RHF is measured to be [6.2±1.1(stat)±1.8(syst)]% for jets with $p_T$ > 25  GeV and |η| < 2.5, in agreement with the expectations from Monte Carlo generators.Peer Reviewe

Measurement of the cross-section for W boson production in association with b-jets in pp collisions at s\sqrt{s} = 7 TeV with the ATLAS detector

This paper reports a measurement of the W+b-jets (W+b+X and W+$b\bar{b}$ +X) production cross-section in proton-proton collisions at a centre-of-mass energy of 7 TeV at the LHC. These results are based on data corresponding to an integrated luminosity of 4.6 fb$^{-1}$, collected with the ATLAS detector. Cross-sections are presented as a function of jet multiplicity and of the transverse momentum of the leading b-jet for both the muon and electron decay modes of the W boson. The W+b-jets cross-section, corrected for all known detector eects, is quoted in a limited kinematic range. Combining the muon and electron channels, the ducial cross-section for W+b-jets is measured to be 7.1 $\pm$ 0.5 (stat) $\pm$ 1.4 (syst) pb, consistent with the next-to-leading order QCD prediction, corrected for non-perturbative and double-parton interactions (DPI) contributions, of 4.7 $\pm$ 0.09 (stat) $^{+0.60}_{-0.49}$ (scale) $\pm$ 0.06 (PDF) $\pm$ 0.16 (non-pert) $^{+0.52}_{-0.38}$ (DPI) pb.Peer Reviewe

Dynamics of isolated-photon plus jet production in pp collisions at (s)=7\sqrt(s)=7 TeV with the ATLAS detector

The dynamics of isolated-photon plus jet production in pp collisions at a centre-of-mass energy of 7 TeV has been studied with the ATLAS detector at the LHC using an integrated luminosity of 37 pb^-^1. Measurements of isolated-photon plus jet bin-averaged cross sections are presented as functions of photon transverse energy, jet transverse momentum and jet rapidity. In addition, the bin-averaged cross sections as functions of the difference between the azimuthal angles of the photon and the jet, the photon-jet invariant mass and the scattering angle in the photon-jet centre-of-mass frame have been measured. Next-to-leading-order QCD calculations are compared to the measurements and provide a good description of the data, except for the case of the azimuthal opening angle.Peer Reviewe

Measurement of the correlation between flow harmonics of different order in lead-lead collisions at sNN\sqrt{s_{NN}}=2.76 TeV with the ATLAS detector

Correlations between the elliptic or triangular flow coefficients vm (m=2 or 3) and other flow harmonics vn (n=2 to 5) are measured using sNN=2.76 TeV Pb+Pb collision data collected in 2010 by the ATLAS experiment at the LHC, corresponding to an integrated luminosity of 7 μb−1. The vm-vn correlations are measured in midrapidity as a function of centrality, and, for events within the same centrality interval, as a function of event ellipticity or triangularity defined in a forward rapidity region. For events within the same centrality interval, v3 is found to be anticorrelated with v2 and this anticorrelation is consistent with similar anticorrelations between the corresponding eccentricities, ε2 and ε3. However, it is observed that v4 increases strongly with v2, and v5 increases strongly with both v2 and v3. The trend and strength of the vm-vn correlations for n=4 and 5 are found to disagree with εm-εn correlations predicted by initial-geometry models. Instead, these correlations are found to be consistent with the combined effects of a linear contribution to vn and a nonlinear term that is a function of v22 or of v2v3, as predicted by hydrodynamic models. A simple two-component fit is used to separate these two contributions. The extracted linear and nonlinear contributions to v4 and v5 are found to be consistent with previously measured event-plane correlations.Peer Reviewe