Water UV-shielding in the terrestrial planet-forming zone: Implications for carbon dioxide emission

Carbon Dioxide is an important tracer of the chemistry and physics in the terrestrial planet forming zone. Using a thermo-chemical model that has been tested against the mid-infrared water emission we re-interpret the CO2 emission as observed with Spitzer. We find that both water UV-shielding and extra chemical heating significantly reduce the total CO2 column in the emitting layer. Water UV-shielding is the more efficient effect, reducing the CO2 column by $\sim$ 2 orders of magnitude. These lower CO2 abundances lead to CO2-to-H2O flux ratios that are closer to the observed values, but CO2 emission is still too bright, especially in relative terms. Invoking the depletion of elemental oxygen outside of the water mid-plane iceline more strongly impacts the CO2 emission than it does the H2O emission, bringing the CO2-to-H2O emission in line with the observed values. We conclude that the CO2 emission observed with Spitzer-IRS is coming from a thin layer in the photo-sphere of the disk, similar to the strong water lines. Below this layer, we expect CO2 not to be present except when replenished by a physical process. This would be visible in the $^{13}$CO2 spectrum as well as certain $^{12}$CO2 features that can be observed by JWST-MIRI.Comment: 8 pages, 4 figures, accepted for publication in ApJ

Searching for Inflow Towards Massive Starless Clump Candidates Identified in the Bolocam Galactic Plane Survey

Recent Galactic plane surveys of dust continuum emission at long wavelengths have identified a population of dense, massive clumps with no evidence for on-going star formation. These massive starless clump candidates are excellent sites to search for the initial phases of massive star formation before the feedback from massive star formation effects the clump. In this study, we search for the spectroscopic signature of inflowing gas toward starless clumps, some of which are massive enough to form a massive star. We observed 101 starless clump candidates identified in the Bolocam Galactic Plane Survey (BGPS) in HCO+ J = 1-0 using the 12m Arizona Radio Observatory telescope. We find a small blue excess of E = (Nblue - Nred)/Ntotal = 0.03 for the complete survey. We identified 6 clumps that are good candidates for inflow motion and used a radiative transfer model to calculate mass inflow rates that range from 500 - 2000 M /Myr. If the observed line profiles are indeed due to large-scale inflow motions, then these clumps will typically double their mass on a free fall time. Our survey finds that massive BGPS starless clump candidates with inflow signatures in HCO+ J = 1-0 are rare throughout our Galaxy.Comment: 14 pages, 9 figure

UV-driven Chemistry as a Signpost for Late-stage Planet Formation

The chemical reservoir within protoplanetary disks has a direct impact on planetary compositions and the potential for life. A long-lived carbon-and nitrogen-rich chemistry at cold temperatures (<=50K) is observed within cold and evolved planet-forming disks. This is evidenced by bright emission from small organic radicals in 1-10 Myr aged systems that would otherwise have frozen out onto grains within 1 Myr. We explain how the chemistry of a planet-forming disk evolves from a cosmic-ray/X-ray-dominated regime to an ultraviolet-dominated chemical equilibrium. This, in turn, will bring about a temporal transition in the chemical reservoir from which planets will accrete. This photochemical dominated gas phase chemistry develops as dust evolves via growth, settling and drift, and the small grain population is depleted from the disk atmosphere. A higher gas-to-dust mass ratio allows for deeper penetration of ultraviolet photons is coupled with a carbon-rich gas (C/O > 1) to form carbon-bearing radicals and ions. This further results in gas phase formation of organic molecules, which then would be accreted by any actively forming planets present in the evolved disk.Comment: Accepted to Nature Astronomy, Published Dec 8th 202

The TW Hya Rosetta Stone Project. I. Radial and Vertical Distributions of DCN and DCO⁺

Molecular D/H ratios are frequently used to probe the chemical past of solar system volatiles. Yet it is unclear which parts of the solar nebula hosted an active deuterium fractionation chemistry. To address this question, we present 0farcs2–0farcs4 Atacama Large Millimeter/submillimeter Array (ALMA) observations of DCO⁺ and DCN 2–1, 3–2, and 4–3 toward the nearby protoplanetary disk around TW Hya, taken as part of the TW Hya Rosetta Stone project, augmented with archival data. DCO⁺ is characterized by an excitation temperature of ~40 K across the 70 au radius pebble disk, indicative of emission from a warm, elevated molecular layer. Tentatively, DCN is present at even higher temperatures. Both DCO⁺ and DCN present substantial emission cavities in the inner disk, while in the outer disk the DCO⁺ and DCN morphologies diverge: most DCN emission originates from a narrow ring peaking around 30 au, with some additional diffuse DCN emission present at larger radii, while DCO⁺ is present in a broad structured ring that extends past the pebble disk. Based on a set of simple parametric disk abundance models, these emission patterns can be explained by a near-constant DCN abundance exterior to the cavity, and an increasing DCO⁺ abundance with radius. In conclusion, the ALMA observations reveal an active deuterium fractionation chemistry in multiple disk regions around TW Hya, but not in the cold planetesimal-forming midplane and in the inner disk. More observations are needed to explore whether deuterium fractionation is actually absent in these latter regions, and if its absence is a common feature or something peculiar to the old TW Hya disk

The TW Hya Rosetta Stone Project. II. Spatially Resolved Emission of Formaldehyde Hints at Low-temperature Gas-phase Formation

Formaldehyde (H₂CO) is an important precursor to organics like methanol (CH₃OH). It is important to understand the conditions that produce H₂CO and prebiotic molecules during star and planet formation. H₂CO possesses both gas-phase and solid-state formation pathways, involving either UV-produced radical precursors or CO ice and cold ( 20 K) dust grains. To understand which pathway dominates, gaseous H₂CO's ortho-to-para ratio (OPR) has been used as a probe, with a value of 3 indicating "warm" conditions and <3 linked to cold formation in the solid state. We present spatially resolved Atacama Large Millimeter/submillimeter Array observations of multiple ortho- and para-H₂CO transitions in the TW Hya protoplanetary disk to test H₂CO formation theories during planet formation. We find disk-averaged rotational temperatures and column densities of 33 ± 2 K, (1.1 ± 0.1) × 10¹² cm⁻² and 25 ± 2 K, (4.4 ± 0.3) × 10¹¹ cm⁻² for ortho- and para-H₂CO, respectively, and an OPR of 2.49 ± 0.23. A radially resolved analysis shows that the observed H₂CO emits mostly at rotational temperatures of 30–40 K, corresponding to a layer with z/R ≥ 0.25. The OPR is consistent with 3 within 60 au, the extent of the pebble disk, and decreases beyond 60 au to 2.0 ± 0.5. The latter corresponds to a spin temperature of 12 K, well below the rotational temperature. The combination of relatively uniform emitting conditions, a radial gradient in the OPR, and recent laboratory experiments and theory on OPR ratios after sublimation, led us to speculate that gas-phase formation is responsible for the observed H₂CO across the TW Hya disk

Molecules with ALMA at Planet-forming Scales (MAPS). VIII. CO gap in AS 209-gas depletion or chemical processing?

Funding: I.C. was supported by NASA through the NASA Hubble Fellowship grant HST-HF2-51405.001-A awarded by the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., for NASA, under contract NAS5-26555. J.D.I. acknowledges support from the Science and Technology Facilities Council of the United Kingdom (STFC) under ST/T000287/1. C.W. acknowledges financial support from the University of Leeds, SFTC, and UKRI (grant Nos. ST/R000549/1, ST/T000287/1, and MR/T040726/1).Emission substructures in gas and dust are common in protoplanetary disks. Such substructures can be linked to planet formation or planets themselves. We explore the observed gas substructures in AS 209 using thermochemical modeling with RAC2D and high-spatial-resolution data from the Molecules with ALMA at Planet-forming Scales (MAPS) program. The observations of C18O J = 2-1 emission exhibit a strong depression at 88 au overlapping with the positions of multiple gaps in millimeter dust continuum emission. We find that the observed CO column density is consistent with either gas surface-density perturbations or chemical processing, while C2H column density traces changes in the C/O ratio rather than the H2 gas surface density. However, the presence of a massive planet (>0.2 MJup) would be required to account for this level of gas depression, which conflicts with constraints set by the dust emission and the pressure profile measured by gas kinematics. Based on our models, we infer that a local decrease of CO abundance is required to explain the observed structure in CO, dominating over a possible gap-carving planet present and its effect on the H2 surface density. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.Publisher PDFPeer reviewe

Molecules with ALMA at planet-forming scales. XX. The massive disk around GM Aurigae

Funding: K.R.S., K.Z., J.B., J.H., and I.C. acknowledge the support of NASA through Hubble Fellowship Program grants HST-HF2-51419.001, HST-HF2-51401.001, HST-HF2-51427.001-A, HST-HF2-51460.001-A, and HST-HF2-51405.001-A awarded by the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., for NASA, under contract NAS5-26555. J.D.I. acknowledges support from the Science and Technology Facilities Council of the United Kingdom (STFC) under ST/T000287/1. C.W. acknowledges financial support from the University of Leeds, STFC and UKRI (grant numbers ST/R000549/1, ST/T000287/1, MR/T040726/1).Gas mass remains one of the most difficult protoplanetary disk properties to constrain. With much of the protoplanetary disk too cold for the main gas constituent, H2, to emit, alternative tracers such as dust, CO, or the H2 isotopologue HD are used. However, relying on disk mass measurements from any single tracer requires assumptions about the tracer's abundance relative to H2 and the disk temperature structure. Using new Atacama Large Millimeter/submillimeter Array (ALMA) observations from the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program as well as archival ALMA observations, we construct a disk physical/chemical model of the protoplanetary disk GM Aur. Our model is in good agreement with the spatially resolved CO isotopologue emission from 11 rotational transitions with spatial resolution ranging from 0"15 to 0"46 (24-73 au at 159 pc) and the spatially unresolved HD J = 1-0 detection from Herschel. Our best-fit model favors a cold protoplanetary disk with a total gas mass of approximately 0.2 M⊙, a factor of 10 reduction in CO gas inside roughly 100 au and a factor of 100 reduction outside of 100 au. Despite its large mass, the disk appears to be on the whole gravitationally stable based on the derived Toomre Q parameter. However, the region between 70 and 100 au, corresponding to one of the millimeter dust rings, is close to being unstable based on the calculated Toomre Q of <1.7. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.Publisher PDFPeer reviewe

Molecules with ALMA at Planet-forming Scales (MAPS). XVI. Characterizing the impact of the molecular wind on the evolution of the HD 163296 system

Funding: I.C. was supported by NASA through the NASA Hubble Fellowship grant HST-HF2-51405.001-A awarded by the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., for NASA, under contract NAS5-26555. J.D.I. acknowledges support from the Science and Technology Facilities Council of the United Kingdom (STFC) under ST/T000287/1. C.W. acknowledges financial support from the University of Leeds, STFC, and UKRI (grant Nos. ST/R000549/1, ST/T000287/1, MR/T040726/1).During the main phase of evolution of a protoplanetary disk, accretion regulates the inner-disk properties, such as the temperature and mass distribution, and in turn, the physical conditions associated with planet formation. The driving mechanism behind accretion remains uncertain; however, one promising mechanism is the removal of a fraction of angular momentum via a magnetohydrodynamic (MHD) disk wind launched from the inner tens of astronomical units of the disk. This paper utilizes CO isotopologue emission to study the unique molecular outflow originating from the HD 163296 protoplanetary disk obtained with the Atacama Large Millimeter/submillimeter Array. HD 163296 is one of the most well-studied Class II disks and is proposed to host multiple gas-giant planets. We robustly detect the large-scale rotating outflow in the 12CO J = 2 - 1 and the 13CO J = 2 - 1 and J = 1 - 0 transitions. We constrain the kinematics, the excitation temperature of the molecular gas, and the mass-loss rate. The high ratio of the rates of ejection to accretion (5-50), together with the rotation signatures of the flow, provides solid evidence for an MHD disk wind. We find that the angular momentum removal by the wind is sufficient to drive accretion though the inner region of the disk; therefore, accretion driven by turbulent viscosity is not required to explain HD 163296's accretion. The low temperature of the molecular wind and its overall kinematics suggest that the MHD disk wind could be perturbed and shocked by the previously observed high-velocity atomic jet. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.Publisher PDFPeer reviewe