751 research outputs found
Hydrogen flash lamps studied
Parameters of gas pressure, type of gas, tube voltage, and electrode gap are tested on the intensity and shape of a radiation pulse from a hydrogen-filled lamp
Demonstration of a Lightguide Detector for Liquid Argon TPCs
We report demonstration of light detection in liquid argon using an acrylic
lightguide detector system. This opens the opportunity for development of an
inexpensive, large-area light collection system for large liquid argon time
projection chambers. The guides are constructed of acrylic, with TPB embedded
in a surface coating with a matching index of refraction. We study the response
to early scintillation light produced by a 5.3 MeV alpha. We measure coating
responses from 7 to 8 PE on average, compared to an ideal expectation of 10 PE
on average. We estimate the attenuation length of light along the lightguide
bar to be greater than 0.5 m. The coating response and the attenuation length
can be improved; we show, however, that these results are already sufficient
for triggering in a large detector
Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection
Over the course of several decades, organic liquid scintillators have formed
the basis for successful neutrino detectors. Gadolinium-loaded liquid
scintillators provide efficient background suppression for electron
antineutrino detection at nuclear reactor plants. In the Double Chooz reactor
antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded
scintillator is utilized for the first time. Its large scale production and
characterization are described. A new, light yield matched metal-free companion
scintillator is presented. Both organic liquids comprise the target and "Gamma
Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table
Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection
Over the course of several decades, organic liquid scintillators have formed
the basis for successful neutrino detectors. Gadolinium-loaded liquid
scintillators provide efficient background suppression for electron
antineutrino detection at nuclear reactor plants. In the Double Chooz reactor
antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded
scintillator is utilized for the first time. Its large scale production and
characterization are described. A new, light yield matched metal-free companion
scintillator is presented. Both organic liquids comprise the target and "Gamma
Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table
Two-photon spectroscopy of the biphenyl chromophore. The electronic excited states of biphenyl and fluorene below 50000 cm-1
The two-photon excitation spectra of biphenyl and fluorene in dil. soln. were measured up to 50,000 cm-1. Both spectra exhibit a medium intense band system in the range 32,000-42,000 cm-1, and a strong band above 45,000 cm-1. The lowest frequency feature is assigned to a B3 symmetry transition in biphenyl and the corresponding B2 transition in fluorene. The polarization of the higher bands leads to the assignment of 2 A states at 38,000 and 47,000 cm-1. The origin of the electronically excited states of the biphenyl chromophore is discussed by simple composite mol. considerations as well as CNDO CI calcns. The latter give a semiquant. picture of transition energies and transition probabilities for 1- and 2-photon allowed excitations. A compilation of 1-photon spectra and calcns. from the literature is included in the anal. to provide a consistent picture of the electronically excited states of the biphenyl chromophore up to 50,000 cm-1
Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection
Over the course of several decades, organic liquid scintillators have formed
the basis for successful neutrino detectors. Gadolinium-loaded liquid
scintillators provide efficient background suppression for electron
antineutrino detection at nuclear reactor plants. In the Double Chooz reactor
antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded
scintillator is utilized for the first time. Its large scale production and
characterization are described. A new, light yield matched metal-free companion
scintillator is presented. Both organic liquids comprise the target and "Gamma
Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table
Synthesis of fluorescent alanines by a rhodium catalysed conjugate addition of arylboronic acids to dehydroalanine derivatives
Several arylalanine derivatives containing fluorescent groups were prepared in good yields using a rhodium catalysed conjugate addition of arylboronic acids to N,N-diprotected and N-monoprotected dehydroalanines. The best conditions for these reactions require the use of an excess of aryl boronic acid (4 equiv.), [Rh(COD)2]BF4 as catalyst and CsF as base in dioxane:H2O (10:1) at 110 ÂșC. These conditions were also applied to several dipeptides with dehydroalanine residues. The photophysical properties of some of the arylalanines were studied in three solvents of different polarity. Due to the absence of the, double bond, the absorption and fluorescence emission of the new compounds are dominated by the photophysical properties of the polycyclic aromatic fluorophores (naphthalene, phenanthrene and pyrene). Considering the relatively high fluorescence quantum yield of these compounds, some of them may be useful as fluorescent markers for peptides and proteins.Thanks are due to the Foundation for Science and Technology (FCT, Portugal), Quadro de Referencia Estrategico Nacional (QREN), and Fundo Europeu de Desenvolvimento Regional/Uniao Europeia (FEDER/EU) for financial support through the research centers, CQ/UM [PEst-C/QUI/UI0686/2011 (FCOMP-01-0124-FEDER-022716)] and CFUM [PEst-C/FIS/UI0607/2011 (F-COMP-01-0124-FEDER-022711)], and project PTDC/QUI/81238/2006 (cofinanced by Fundo Europeu de Desenvolvimento Regional/Programa Operacional Fatores de Competitividade (FEDER/COMPETE), ref. FCOMP-01-0124-FEDER-007467). G. P. acknowledges her PhD grant from Fundacao para a Ciencia e a Tecnologia (FCT), Programa Operacional Potencial Humano/Quadro de Referencia Estrategico Nacional (POPH-QREN), Fundo Social Europeu (FSE) (SFRH/BD/38766/2007)
Prototype scintillator cell for an In-based solar neutrino detector
We describe the work carried out at MPIK to design, model, build and
characterize a prototype cell filled with a novel indium-loaded scintillator of
interest for real-time low energy solar neutrino spectroscopy. First, light
propagation in optical modules was studied with experiments and Monte Carlo
simulations. Subsequently a 5 cm x 5 cm x 100 cm prototype detector was set up
and the optical performances of several samples were measured. We first tested
a benchmark PXE-based scintillator, which performed an attenuation length of ~
4.2 m and a photo-electron yield of ~ 730 pe/MeV. Then we measured three
In-loaded samples. At an In-loading of 44 g/l, an energy resolution of ~ 11.6 %
and a spatial resolution of ~ 7 cm were attained for 477 keV recoil electrons.
The long-range attenuation length in the cell was ~1.3 m and the estimated
photo-electron yield ~ 200 pe/MeV. Light attenuation and relative light output
of all tested samples could be reproduced reasonably well by MC. All optical
properties of this system have remained stable over a period of > 1 y.Comment: 57 pages, 19 figures, 10 tables elsevier template for manuscript
submission submitted to NIMA 10 February 200
Diastereodifferentiation of novel naphthalene dyads by fluorescence quenching and excimer formation
[EN] Four new bichromophoric naphthalene dyads in form of diastereomeric pairs are synthesized and photophysically characterized. For a closely related group of compounds (NAP-NAP MNAP-NAP, MNAP-MNAP), systematic variation of the urea linker led to the observation of intramolecular fluorescence quenching for tertiary urea, but not for secondary urea. Chiral information contained in the dyads has an impact on the efficiency of this process. Furthermore, for the case of (RR)-MNAP-MNAP excimer formation in the pre-organized dyad was noted, while being absent in the corresponding (R,S) diastereomer. These differences in photophysical behavior are ascribed to the geometry of the linker and to the chiral information contained in the diastereomeric compounds. Other dyads, such as NPX-NPX, included naproxen as the chromophore. For these compounds strong excimer emission is obtained, however, only very small diastereodifferentiation is observed for the two investigated stereoisomers.We acknowledge the financial support by the Spanish Ministry of Education and Science (Grant No. CTQ 2004-03811, doctoral fellowships for S.A. and I.V., RamĂłn y Cajal grant for U.P.).Abad Fuentes, S.; VayĂĄ PĂ©rez, I.; JimĂ©nez Molero, MC.; Pischel ., U.; Miranda Alonso, MĂ. (2006). Diastereodifferentiation of novel naphthalene dyads by fluorescence quenching and excimer formation. ChemPhysChem. 7(10):2175-2183. https://doi.org/10.1002/cphc.200600337S2175218371
Transient absorption spectroscopy detection of sensitized delayed fluorescence in chiral benzophenone/naphthalene systems
Transient absorption spectroscopy has proven to be a powerful tool to investigate the formation and decay of excited singlet states upon tripletâtriplet annihilation, following TâT energy transfer from a selectively excited sensitizer. Thus, upon selective excitation of benzophenone (BZP) by laser flash photolysis (LFP) at λ = 355 nm in the presence of naphthalene (NPT), a negative band centered at 340 nm has been detected, with growth and decay in the microsecond timescale. It has been assigned to the P-type NPT delayed-fluorescence. In the case of chiral BZP/NPT systems, stereodifferentiation has been observed in the kinetics of the involved photophysical processesFinancial support from the MICINN (Grant CTQ2010-14882 and predoctoral fellowship to P. B.) is gratefully acknowledged.BonancĂa Roca, P.; JimĂ©nez Molero, MC.; Miranda Alonso, MĂ. (2011). Transient absorption spectroscopy detection of sensitized delayed fluorescence in chiral benzophenone/naphthalene systems. Chemical Physics Letters. 515(1-3):194-196. https://doi.org/10.1016/j.cplett.2011.08.096S1941965151-
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