Use of partial load operating conditions for latent thermal energy storage management

A proper management of thermal energy storage (TES) charging and discharging processes allows the final users to optimize the performance of TES systems. In this paper, an experimental research is carried out to study how the percentage of charge in a latent heat TES system (partial load operating conditions) influences the discharge process. Several charging and discharging processes were performed at a constant heat transfer fluid (HTF) mass flow rate of 0.5 kg/s and temperature of 155 °C and 105 °C, respectively. High density polyethylene (HDPE) with a total mass of 99.5 kg was used as phase change material (PCM) in a 0.154m3 storage tank based on the shelland-tube heat exchanger concept. Five different percentages of charge have been studied: 58 %, 73 %, 83 %, 92 %, and 97 % (baseline test). Results showed that by modifying the percentage of charge, the time required for the charging process was reduced between 97.2% and 68.8% in comparison to the baseline case. However, the energy accumulated was only reduced a maximum of 35.1% and a minimum of 5.2%, while the heat transfer rates during the first 60 min of discharge were reduced a maximum of 45.8% and a minimum of 6%. Therefore, partially charging the TES system not lower than 85% of its maximum energy capacity becomes a good option if the final application accepts a maximum decrease of discharging heat transfer rates of 10% if compared to the fully charged system.The work was partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER), ENE2015-64117-C5-3-R (MINECO/FEDER), and ULLE10-4E-1305). The authors would like to thank the Catalan Government for the quality accreditation given to their research group (2014 SGR 123). GREA is certified agent TECNIO in the category of technology developers from the Government of Catalonia. This project has received funding from the European Commission Seventh Framework Programme (FP/2007-2013) under Grant agreement No. PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No. 657466 (INPATH-TES). Jaume Gasia would like to thank the Departament d'Universitats, Recerca i Societat de la Informació de la Generalitat de Catalunya for his research fellowship (2017 FI_B1 00092). Alvaro de Gracia would like to thank Ministerio de Economia y Competitividad de España for Grant Juan de la Cierva, FJCI-2014-19940. Simone Arena would like to thank the Department of Mechanical, Chemical and Materials Engineering of the University of Cagliari for funding his research grant

Two proposals for testing quantum contextuality of continuous-variable states

We investigate the violation of non-contextuality by a class of continuous variable states, including variations of entangled coherent states (ECS's) and a two-mode continuous superposition of coherent states. We generalise the Kochen-Specker (KS) inequality discussed in A. Cabello, Phys. Rev. Lett. {\bf 101}, 210401 (2008) by using effective bidimensional observables implemented through physical operations acting on continuous variable states, in a way similar to an approach to the falsification of Bell-CHSH inequalities put forward recently. We test for state-independent violation of KS inequalities under variable degrees of state entanglement and mixedness. We then demonstrate theoretically the violation of a KS inequality for any two-mode state by using pseudo-spin observables and a generalized quasi-probability function.Comment: 7 pages, 2 figures, RevTeX

Can AI help in crowdsourcing? testing alternate algorithms for idea screening in crowdsourcing contests

Crowdsourcing, while a boon to ideation, generates thousands of ideas. Screening these ideas to select a few winners is a major challenge because of the limited number, expertise, objectivity, and attention of judges. This paper compares original and extended versions of three recently published theory-based algorithms from marketing to evaluate ideas in crowdsourcing contests: Word Colocation, Content Atypicality, and Inspiration Redundancy. Each algorithm suggests predictors of winning ideas. The authors extend these predictors using two methods for searching parsimonious predictors: least average shrinkage and selection operator (LASSO) and K-sparse Exhaustive Search, for K ≤ 5. The authors test the algorithms in-sample and out-of-sample on 21 different real-world crowdsourcing contests conducted for large firms. The standard provided by management is "drop the worst 25% of ideas without sacrificing more than 15% of good ideas," as ranked by experts. Results are the following. First, of the three original algorithms, Inspiration Redundancy performs best out-of-sample, but fails to meet the 15% threshold. Second, for two of the three algorithms, the extended versions outperform the original. In particular, Topic Overlap Atypicality, a new measure, emerges as the most robust predictor. Third, when the best versions of the algorithms are used, all three contribute to the important out-of-sample prediction accuracy. Fourth, using extended versions of all three algorithms, we are able to meet Hyve’s threshold

Structure and Phase Transitions of Metastable Hexagonal Uranium Thin Films

We report a simple technique for the synthesis of uniaxially textured, metastable hexagonal close-packed-like uranium thin films with thicknesses between 175-2800 \r{A}. The initial structure and texture of the layers have been studied via X-ray diffraction and reflectivity and the time-dependent transitions of the samples into various orientations of orthorhombic ${\alpha}$-U have been mapped by similar techniques. The final crystallographic orientations of each system and the timescales on which the transitions occur are found to depend on the lattice parameters of the original layer. The absence of the ${\alpha}$-U (001) orientation in the transition products suggests that the transitions in these layers are mediated by mechanisms other than the [110] transverse acoustic phonon mode previously suggested for the cubic ${\gamma}$-U(110) to hcp-U(00.1) to ${\alpha}$-U(001) displacive phase transition. Alternative transition pathways are discussed

Experimental evaluation at pilot plant scale of multiple PCMs (cascaded) vs. single PCM configuration for thermal energy storage

The present paper provides on one hand, a literature review of the different studies available in the scientific literature where the concept of multiple phase change materials (PCM) configuration, also named cascaded or multi-stage, has been presented and on the other hand, an experimental evaluation of the advantages of using the multiple PCM configuration instead of the single PCM configuration in thermal energy storage (TES) systems at pilot plant to fill the gap of experimental and high scales studies on this concept in the literature. Two PCM with melting temperatures in a temperature range of 150 e200 C were selected due to their high value of heat of fusion and compared: d-mannitol and hydroquinone. Three configurations were evaluated: (1) single PCM with hydroquinone, (2) single PCM with dmannitol and (3) multiple PCM with hydroquinone and d-mannitol. A discussion regarding the results on the specific energy stored and effectiveness as well as the evolution of the PCM and heat transfer fluid (HTF) through the time and at different and representative locations of the facility is presented. Results showed that the multiple PCMs configuration introduced an effectiveness enhancement of 19.36% if compared with single PCM configuration as well as a higher uniformity on the HTF temperature difference between the inlet and outlet.The work is partially funded by the Spanish Government (ENE2011-22722 and ULLE10-4E-1305). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREA (2014 SGR 123). The research leading to these results has received funding from the European Union's Seventh Framework Programme (FP7/2007-2013) under grant agreement n PIRSES-GA-2013-610692 (INNOSTORAGE). Laia Miro would like to thank the Spanish Government for her research fellowship (BES-2012-051861)

Temperature distribution and heat losses in molten salts tanks for CSP plants

Solar power plants have been deployed in the last 20 years, so the interest in evaluating their performance is growing more and more. In these facilities, thermal energy storage is used to increase dispatchability of power. The two-tank molten salts storage system with “solar salt” (60 wt.% NaNO3 and 40 wt.% KNO3) is the one commercially used today. To be able to achieve a deep understanding of the two-tank solar storage systems with molten salts, in 2008 a pilot plant was built at the University of Lleida (Spain) and the experimental evaluation of the temperature distribution inside the tanks and their heat losses are presented in this paper. Therefore, this pilot plant is equipped with several temperature sensors inside the tank as well as in the different layers of external insulation. As expected, temperature is lower at the external part of the tank (near the cover, at the bottom and near the walls) and no stratification is seen. It is found that the influencing parameters in the temperature distribution of the salts inside the tank are: insulation, and the existence of different electrical resistances and the orientation and surroundings of the tank. Heat losses were measured and compared both with a simulated 1-D steady state model and previous literature. Measured heat losses were from 61 W/m2 through the bottom to 80 W/m2 through the walls (with 73 W/m2 through the cover).The research leading to these results has received funding from Spanish goverment (Fondo tecnológico IDI-20090393, ConSOLida CENIT 2008-1005) and from Abengoa Solar NT. The work is partially funded by the Spanish government (ENE2008-06687-C02-01/CON, ENE2011-22722, ENE2015-64117-C5-1-R, and ULLE10-4E-1305). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREA (2014 SGR 123). This project has received funding from the European Commission Seventh Framework Programme (FP/2007-2013) under Grant agreement N° PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). Laia Miró would like to thank the Spanish Government for her research fellowship (BES-2012-051861)

Influence of the heat transfer fluid in a CSP plant molten salts charging process

The selection of a proper heat transfer fluid (HTF) is a key factor to increase the efficiency of concentrated solar power plants and therefore, to reduce their internal associated CAPEX (capital expenditures of developing and constructing a plant, excluding any grid-connection charges) and OPEX (operating expenditures from the first year of a project's operation). This paper presents a comparative study of two commercial HTF which are widely used in different industries and CSP plants: thermal oil Therminol VP-1 and silicone fluid Syltherm 800. First, the authors theoretically studied the properties of both HTF based on the data given by the manufactures. Afterwards, the authors experimentally perform the comparison in a two-tank molten salt thermal energy storage pilot plant built at the University of Lleida (Spain). The study is focused on the plate heat exchanger of the facility during several charging processes with a counter flow arrangement. Results from both studies showed that, for the same working conditions, Therminol VP-1 is the best candidate for the above-mentioned purposes due to its higher heat transfer, lower thermal losses and lower power consumption associated to the HTF pump. However, it presents problems a low crystallization point, which should also be considered.The research leading to these results has received funding from Spanish goverment (Fondo tecnológico IDI-20090393, ConSOLida CENIT 2008-1005) and from Abengoa Solar NT. The work is partially funded by the Spanish government (ENE2008-06687-C02-01/CON, ENE2011-22722, ULLE10-4E-1305 and ENE2015-64117-C5-1-R (MINECO/FEDER)). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREA (2014 SGR 123). This project has also received funding from the European Commission Seventh Framework Programme (FP/2007-2013) under Grant agreement NºPIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). Laia Miró would like to thank the Spanish Government for her research fellowship (BES-2012-051861). Jaume Gasia would like to thank the Departament d’Universitats, Recerca i Societat de la Informació de la Generalitat de Catalunya for his research fellowship (2017FI_B1 00092). The authors would like to thank Dr. Eduard Oró from Catalonia Institute for Energy Research (Spain) and Dr. Antoni Gil from Massachusetts Institute of Technology (USA) for their help during the initial stages of the experimentation