Gallium Analogue of Soluble Prussian Blue KGa[Fe(CN)₆]·<i>n</i>H₂O: Synthesis, Characterization, and Potential Biomedical Applications

The gallium analogue of the soluble Prussian blue with the formula KGa­[Fe­(CN)₆]·<i>n</i>H₂O is synthesized and structurally characterized. A simple aqueous synthetic procedure for preparing nanoparticles of this novel coordination polymer is reported. The stability, in vitro ion exchange with ferrous ions, cytotoxicity, and cellular uptake of such nanoparticles coated with poly­(vinylpyrrolidone) are investigated for potential applications of delivering Ga³⁺ ions into cells or removing iron from cells