The kinetics of ice-lens growth in porous media

We analyse the growth rate of segregated ice (ice lenses) in freezing porous media. For typical colloidal materials such as soils we show that the commonly-employed Clapeyron equation is not valid macroscopically at the interface between the ice lens and the surrounding porous medium owing to the viscous dynamics of flow in premelted films. This gives rise to an ‘interfacial resistance’ to flow towards the growing ice which causes a significant drop in predicted ice-growth (heave) rates and explains why many previous models predict ice-growth rates that are much larger than those seen in experiments. We derive an explicit formula for the ice-growth rate in a given porous medium, and show that this only depends on temperature and on the external pressures imposed on the freezing system. This growth-rate formula contains a material-specific function which can be calculated (with a knowledge of the of the geometry and material of the porous medium), but which is also readily experimentally-measurable. We apply the formula to plate-like particles, and obtain good agreement with previous experimental data. Finally we show how the interfacial resistance explains the observation that the maximum heave rate in soils occurs in medium-grained particles such as silts, while heave rates are smaller for fine- and coarse- grained particles

Frost heave in compressible soils

We develop a mathematical model of frost heave in compressible soils based on a morphological instability of the ice–soil interface. The theory accounts for heave and soil consolidation,while avoiding the frozen fringe assumption. Using a Lie-B¨acklund transformation an analytical solution to the governing equations is found. Two solidification regimes occur: a compaction regime in which the soil consolidates to accommodate the ice lenses, and a heave regime during which the soil is fully consolidated and heaves. The rate of heave is found to be independent of the rate of freezing, consistent with field and laboratory observations

Crust formation in drying colloidal suspensions

During the drying of colloidal suspensions, the desiccation process causes the suspension near the air interface to consolidate into a connected porous matrix or crust. Fluid transport in the porous medium is governed by Darcy’s law and the equations of poroelasticity, while the equations of colloid physics govern processes in the suspension. We derive new equations describing this process, including unique boundary conditions coupling the two regions, yielding a moving-boundary model of the concentration and stress profiles during drying. A solution is found for the steady-state growth of a one-dimensional crust during constant evaporation rate from the surface. The solution is used to demonstrate the importance of the system boundary conditions on stress profiles and diffusivity in a drying crust