Coherent Quantum Optical Control with Subwavelength Resolution

We suggest a new method for quantum optical control with nanoscale resolution. Our method allows for coherent far-field manipulation of individual quantum systems with spatial selectivity that is not limited by the wavelength of radiation and can, in principle, approach a few nanometers. The selectivity is enabled by the nonlinear atomic response, under the conditions of Electromagnetically Induced Transparency, to a control beam with intensity vanishing at a certain location. Practical performance of this technique and its potential applications to quantum information science with cold atoms, ions, and solid-state qubits are discussed.Comment: 4 pages, 2 figures. V2: changes in presentation (text, figures, tables) and new references - final version as published in Phys. Rev. Lett

The envenomation of general physiology throughout the last century.

Toxins are the poisonous products of organisms. Toxins serve vital defensive and offensive functions for those that harbor them: stinging scorpions, pesticidal plants, sanguinary snakes, fearless frogs, sliming snails, noxious newts, and smarting spiders. For physiologists, toxins are integral chemical tools that hijack life's fundamental processes with remarkable molecular specificity. Our understanding of electrophysiological phenomena has been transformed time and time again with the help of some terrifying toxins. For this reason, studies of toxin mechanism are an important and enduring facet of The Journal of General Physiology (JGP). This Milestone in Physiology reflects on toxins studied in JGP over its first 100 years, what they have taught us, and what they have yet to reveal

CAutoCSD-evolutionary search and optimisation enabled computer automated control system design

This paper attempts to set a unified scene for various linear time-invariant (LTI) control system design schemes, by transforming the existing concept of 'Computer-Aided Control System Design' (CACSD) to the novel 'Computer-Automated Control System Design' (CAutoCSD). The first step towards this goal is to accommodate, under practical constraints, various design objectives that are desirable in both time and frequency-domains. Such performance-prioritised unification is aimed to relieve practising engineers from having to select a particular control scheme and from sacrificing certain performance goals resulting from pre-committing to the adopted scheme. With the recent progress in evolutionary computing based extra-numeric, multi-criterion search and optimisation techniques, such unification of LTI control schemes becomes feasible, analytically and practically, and the resultant designs can be creative. The techniques developed are applied to, and illustrated by, three design problems. The unified approach automatically provides an integrator for zero-steady state error in velocity control of a DC motor, meets multiple objectives in designing an LTI controller for a non-minimum phase plant and offers a high-performing LTI controller network for a nonlinear chemical process

EFFECT OF METAL OXIDE ADDITIONS TO V-BASED COMPLEX OXIDE CATALYSTS ON OXIDATIVE DEHYDROGENATION OF BUT-1-ENE

Buta-1,3-diene (BD), one of the most important products in the petrochemical industry, is mainly produced through the endothermic steam cracking of naphtha. Recently, the oxidative dehydrogenation (ODH) of n-butene (n-C₄H₈) has emerged as an attractive alternative due to the energy savings it offers. The ODH of n-C₄H₈ is reportedly improved by the addition of V-based complex oxide catalysts. In this study, we added metal oxides to V-based complex oxide catalysts and examined the effects of this addition on the ODH of 1-C₄H₈. The addition of Mg and Co to the V-based complex oxides resulted in the highest BD yield of 22.5% with the lattice oxygen of the catalyst. Moreover, this catalyst also exhibited high ODH activity under an O₂ atmosphere

Laser-induced isotopic selectivity in the resonance ionization of Os

Isotope selective effects in resonance ionization mass spectrometry (RIMS) pose a potentially serious limitation to the application of this technique to the precise and reproducible measurement of isotope ratios. In order to identify some of the underlying causes of isotope selectivity in RIMS and to establish procedures for minimizing these effects, we investigated laser-induced isotope selectivity in the resonance ionization of Os. A single-color, one-photon resonant ionization scheme was used for several different transitions to produce Os photoions from a thermal atomization source. Variations in Os isotope ratios were studied as a function of laser parameters such as wavelength, bandwidth, power and polarization state. Isotope selectivity is strongly dependent on laser power and wavelength, even when the bandwidth of the laser radiation is much larger than the optical isotope shift. Variations in the ^(190)Os/^(188)Os ratio of ≈20% for a detuning of 0.8 cm^(−1) were observed on a transition with a small oscillator strength. Large even—odd isotope selectivity with a 13% depletion of ^(189)Os was observed on a ΔJ = +1 transition at low laser intensity; the odd mass Os isotopes are systematically depleted. For ΔJ = −1 and 0 transitions the isotope selectivity was reduced by polarization scrambling and for strongly saturating conditions. A technique employing the wavelength dependence of even—even isotope selectivity as an internal wavelength standard was developed to permit accurate and reproducible wavelength adjustment of the laser radiation. This technique provides control over laser-induced isotope selectivity for single-color ionization and enabled us to obtain reproducible measurements of ^(192)Os/^(188)Os and ^(189)Os/^(190)Os ratios in the saturation regime for a ΔJ = +1 transition with a precision of better than 0.5%. The application of this wavelength-tuning procedure should significantly improve the quality of RIMS isotope ratio data for many elements

A Holistic Investigation on Terahertz Propagation and Channel Modeling Toward Vertical Heterogeneous Networks

User-centric and low latency communications can be enabled not only by small cells but also through ubiquitous connectivity. Recently, the vertical heterogeneous network (V-HetNet) architecture is proposed to backhaul/fronthaul a large number of small cells. Like an orchestra, the V-HetNet is a polyphony of different communication ensembles, including geostationary orbit (GEO), and low-earth orbit (LEO) satellites (e.g., CubeSats), and networked flying platforms (NFPs) along with terrestrial communication links. In this study, we propose the Terahertz (THz) communications to enable the elements of V-HetNets to function in harmony. As THz links offer a large bandwidth, leading to ultra-high data rates, it is suitable for backhauling and fronthauling small cells. Furthermore, THz communications can support numerous applications from inter-satellite links to in-vivo nanonetworks. However, to savor this harmony, we need accurate channel models. In this paper, the insights obtained through our measurement campaigns are highlighted, to reveal the true potential of THz communications in V-HetNets.Comment: It has been accepted for the publication in IEEE Communications Magazin

Designing materials for electrochemical carbon dioxide recycling

Electrochemical carbon dioxide recycling provides an attractive approach to synthesizing fuels and chemical feedstocks using renewable energy. On the path to deploying this technology, basic and applied scientific hurdles remain. Integrating catalytic design with mechanistic understanding yields scientific insights and progresses the technology towards industrial relevance. Catalysts must be able to generate valuable carbon-based products with better selectivity, lower overpotentials and improved current densities with extended operation. Here, we describe progress and identify mechanistic questions and performance metrics for catalysts that can enable carbon-neutral renewable energy storage and utilization

Failure and Strategic Projects: Australias Asia-Pacific Vision

This paper uses Australia’s 1980s shift to a new accumulation strategy of ‘international competitiveness’ to examine the role of failure in shaping state strategic projects. The paper argues that the Australian strategy’s gradual shift from an interventionist to a market-led orientation played out in competing representations of failure. Whether particular policies were perceived as failures depended not only on their material effects, but also on the ways in which failure was defined and on the values underpinning those definitions. As representations of failure establish the boundaries between the incremental adaptations that stabilise an accumulation strategy and the more radical failures characteristic of crisis, they illuminate how processes of discursive selectivity ‘fix’ state projects’ temporal, scalar and spatial dimension