Natural and Experimental Slow Slip Observed Along Shallow Hematite Faults

Fault slip relieves stress in the shallow crust by slipping suddenly during earthquakes, but some faults also slip slowly in between earthquakes. Exhumed faults, brought up to the Earth’s surface from depth, preserve a record of fault processes and slip rates informed by fault rock structures, textures, and chemistry. Hematite, a common iron oxide mineral that precipitates on fault surfaces, exhibits crystal textures that potentially indicate past slip rate. Hematite can be dated using the radioisotopic system of (U-Th)/He thermochronometry, which constrains the time when He is trapped within a crystal, a process that is a function of temperature. Exhumed faults that are parallel and connect to the San Andreas Fault (southernmost California) at depth cut crystalline rock and contain networks of small, hematite-coated faults. Here, hematite displays crystal morphology and structures that indicate hematite formed episodically a formation, repeatedly slipped at slow rates. Hematite (U-Th)/He dates show hematite formed at shallow depths

Micro- to Macro-Scale Structural and Lithological Architecture of Basal Nonconformities: Implications for Fluid Flow and Injection Induced Seismicity

Rising incidents of earthquakes caused by human activity in the United States, known as induced earthquakes, is a growing concern. Induced earthquakes may occur when fluid and/or wastewater is injected several kilometers beneath the Earth’s surface into sedimentary rocks. Fluids and pressures can migrate from the sedimentary rocks, which are typically friendlier to fluid flow, into underlying less friendlier crystalline rocks along fluid pathways weakening and possibly reactivating preexisting faults. Understanding potential fluid pathways and/or barriers from the sedimentary rocks to crystalline rocks is crucial. I investigate the structure, composition, and heterogeneity of rocks near the contact between the sedimentary and crystalline rocks, known as nonconformities, and highlight their possible role in the transmission of fluids and porefluid pressures into the crystalline basement. To characterize nonconformities, we examined outcrop analogs and drillcore of nonconformities in New Mexico, Colorado, and Michigan. Geochemical, structural, and hydrological techniques were used to analyze the nonconformities at microscopic to megascopic scales. The nonconformities observed in this study consist of variably deformed, weathered, and altered igneous and metamorphic crystalline basement overlain by sedimentary rocks cut by outcrop- and map-scale faults. The nonconformity at the New Mexico sites includes a clay-rich weathered horizon atop deformed and jointed crystalline basement. Heterogeneity observed in the fracture and joint networks within the crystalline basement contributes to permeability heterogeneity and anisotropy. The crystalline basement adjacent to the nonconformity at the Colorado site is relatively fresh and unweathered and overlain by low permeability sandstones. The nonconformity and underlying slates in the Michigan drillcore are overprinted by hydrothermal alteration and carbonate mineralization, which provides evidence of hydrological communication between sedimentary and crystalline rocks. The nonconformities display a range of structural, hydrological, and geochemical styles and characteristics which vary over relatively small spatial extents. The geological and hydrogeological histories and complexities of nonconformity analogs provide valuable information to understand how fluids, past, and present, interact with the contact. This study introduces some of the factors that may control fluid flow adjacent to nonconformities and their possible significance to the interplay of deformation, fluid flow, and induced seismicity

Silica Fault Mirror Development Along the Cordillera Blanca Detachment Fault, Peru

Earthquakes occur along planes of geologic weakness called faults. Thin, light-reflective surfaces on faults are called fault mirrors and often considered signatures of previous earthquakes along these faults. The Cordillera Blanca mountain range in the Peruvian Andes provides a natural laboratory to explore meter scale exposures of fault mirrors. Three naturally formed fault mirror samples were collected from the Cordillera Blanca detachment fault which runs along the edge of the Cordillera Blanca mountain range. Prior work on this fault reveals that it is capable of destructive earthquakes every few thousand years and is a significant earthquake hazard to the surrounding communities. The goal of our investigation is to discover the textural and chemical properties of silica FMs and use that information to determine the deformation processes involved in their formation. Our results document multiple fault slip events, variations in grain size and a thin zone of no discernable grains directly below the fault mirror surface. Our chemical observations reveal the material the fault mirror has developed on is crystalline (quartz). This result differs from prior observations of silica fault mirrors which show they can develop on a non-crystalline to partially crystalline material. We suggest that if these fault mirrors formed during earthquake slip events, that the accommodation of slip within a small zone plays a role in propagating slip along the Cordillera Blanca detachment fault

Malignant melanoma of the urethra: a rare histologic subdivision of vulvar cancer with a poor prognosis

Malignant melanoma of the urethra is a rare tumour that is difficult to diagnose and treat, resulting in a poor prognosis. In this paper, we present the case of a 65-year-old woman who was referred to a gynaecologist because of a urethral mass that mimicked a caruncle. The tumour was removed by local excision, and a pathological analysis revealed a malignant melanoma. Distal urethrectomy was performed after three months with no evidence of residual tumour. There was no evidence of disease at a six-year followup. In this paper, we compare the epidemiology, treatment, staging, and prognosis of vulvar cancer in general to malignant melanoma of the vulva in particular

EVOLUTION OF THE SUBCONTINENTAL LITHOSPHERE DURING MESOZOIC TETHYAN RIFTING: CONSTRAINTS FROM THE EXTERNAL LIGURIAN MANTLE SECTION (NORTHERN APENNINE, ITALY)

Our study is focussed on mantle bodies from the External Ligurian ophiolites, within the Monte Gavi and Monte Sant'Agostino areas. Here, two distinct pyroxenite-bearing mantle sections were recognized, mainly based on their plagioclase-facies evolution. The Monte Gavi mantle section is nearly undeformed and records reactive melt infiltration under plagioclase-facies conditions. This process involved both peridotites (clinopyroxene-poor lherzolites) and enclosed spinel pyroxenite layers, and occurred at 0.7–0.8 GPa. In the Monte Gavi peridotites and pyroxenites, the spinel-facies clinopyroxene was replaced by Ca-rich plagioclase and new orthopyroxene, typically associated with secondary clinopyroxene. The reactive melt migration caused increase of TiO2 contents in relict clinopyroxene and spinel, with the latter also recording a Cr2O3 increase. In the Monte Gavi peridotites and pyroxenites, geothermometers based on slowly diffusing elements (REE and Y) record high temperature conditions (1200-1250 °C) related to the melt infiltration event, followed by subsolidus cooling until ca. 900°C. The Monte Sant'Agostino mantle section is characterized by widespread ductile shearing with no evidence of melt infiltration. The deformation recorded by the Monte Sant'Agostino peridotites (clinopyroxene-rich lherzolites) occurred at 750–800 °C and 0.3–0.6 GPa, leading to protomylonitic to ultramylonitic textures with extreme grain size reduction (10–50 μm). Compared to the peridotites, the enclosed pyroxenite layers gave higher temperature-pressure estimates for the plagioclase-facies re-equilibration (870–930 °C and 0.8–0.9 GPa). We propose that the earlier plagioclase crystallization in the pyroxenites enhanced strain localization and formation of mylonite shear zones in the entire mantle section. We subdivide the subcontinental mantle section from the External Ligurian ophiolites into three distinct domains, developed in response to the rifting evolution that ultimately formed a Middle Jurassic ocean-continent transition: (1) a spinel tectonite domain, characterized by subsolidus static formation of plagioclase, i.e. the Suvero mantle section (Hidas et al., 2020), (2) a plagioclase mylonite domain experiencing melt-absent deformation and (3) a nearly undeformed domain that underwent reactive melt infiltration under plagioclase-facies conditions, exemplified by the the Monte Sant'Agostino and the Monte Gavi mantle sections, respectively. We relate mantle domains (1) and (2) to a rifting-driven uplift in the late Triassic accommodated by large-scale shear zones consisting of anhydrous plagioclase mylonites. Hidas K., Borghini G., Tommasi A., Zanetti A. & Rampone E. 2021. Interplay between melt infiltration and deformation in the deep lithospheric mantle (External Liguride ophiolite, North Italy). Lithos 380-381, 105855

Impact of Etna’s volcanic emission on major ions and trace elements composition of the atmospheric deposition

Mt. Etna, on the eastern coast of Sicily (Italy), is one of the most active volcanoes on the planet and it is widely recognized as a big source of volcanic gases (e.g., CO2 and SO2), halogens, and a lot of trace elements, to the atmosphere in the Mediterranean region. Especially during eruptive periods, Etna’s emissions can be dispersed over long distances and cover wide areas. A group of trace elements has been recently brought to attention for their possible environmental and human health impacts, the Technology-critical elements. The current knowledge about their geochemical cycles is still scarce, nevertheless, recent studies (Brugnone et al., 2020) evidenced a contribution from the volcanic activity for some of them (Te, Tl, and REE). In 2021, in the framework of the research project “Pianeta Dinamico”, by INGV, a network of 10 bulk collectors was implemented to collect, monthly, atmospheric deposition samples. Four of these collectors are located on the flanks of Mt. Etna, other two are in the urban area of Catania and three are in the industrial area of Priolo, all most of the time downwind of the main craters. The last one, close to Cesarò (Nebrodi Regional Park), represents the regional background. The research aims to produce a database on major ions and trace element compositions of the bulk deposition and here we report the values of the main physical-chemical parameters and the deposition fluxes of major ions and trace elements from the first year of research. The pH ranged from 3.1 to 7.7, with a mean value of 5.6, in samples from the Etna area, while it ranged between 5.2 and 7.6, with a mean value of 6.4, in samples from the other study areas. The EC showed values ranging from 5 to 1032 μS cm-1, with a mean value of 65 μS cm-1. The most abundant ions were Cl- and SO42- for anions, Na+ and Ca+ for cations, whose mean deposition fluxes, considering all sampling sites, were 16.6, 6.8, 8.4, and 6.0 mg m-2 d, respectively. The highest deposition fluxes of volcanic refractory elements, such as Al, Fe, and Ti, were measured in the Etna’s sites, with mean values of 948, 464, and 34.3 μg m-2 d-1, respectively, higher than those detected in the other sampling sites, further away from the volcanic source (26.2, 12.4, 0.5 μg m-2 d-1, respectively). The same trend was also observed for volatile elements of prevailing volcanic origin, such as Tl (0.49 μg m-2 d-1), Te (0.07 μg m-2 d-1), As (0.95 μg m-2 d-1), Se (1.92 μg m-2 d-1), and Cd (0.39 μg m-2 d-1). Our preliminary results show that, close to a volcanic area, volcanic emissions must be considered among the major contributors of ions and trace elements to the atmosphere. Their deposition may significantly impact the pedosphere, hydrosphere, and biosphere and directly or indirectly human health

Impact of geogenic degassing on C-isotopic composition of dissolved carbon in karst systems of Greece

The Earth C-cycle is complex, where endogenic and exogenic sources are interconnected, operating in a multiple spatial and temporal scale (Lee et al., 2019). Non-volcanic CO2 degassing from active tectonic structures is one of the less defined components of this cycle (Frondini et al., 2019). Carbon mass-balance (Chiodini et al., 2000) is a useful tool to quantify the geogenic carbon output from regional karst hydrosystems. This approach has been demonstrated for central Italy and may be valid also for Greece, due to the similar geodynamic settings. Deep degassing in Greece has been ascertained mainly at hydrothermal and volcanic areas, but the impact of geogenic CO2 released by active tectonic areas has not yet been quantified. The main aim of this research is to investigate the possible deep degassing through the big karst aquifers of Greece. Since 2016, 156 karst springs were sampled along most of the Greek territory. To discriminate the sources of carbon, the analysis of the isotopic composition of carbon was carried out. δ13CTDIC values vary from -16.61 to -0.91‰ and can be subdivided into two groups characterized by (a) low δ13CTDIC, and (b) intermediate to high δ13CTDIC with a threshold value of -6.55‰. The composition of the first group can be related to the mixing of organic-derived CO2 and the dissolution of marine carbonates. Springs of the second group, mostly located close to Quaternary volcanic areas, are linked to possible carbon input from deep sources