Geomorphic signal of active faulting at the northern edge of Lut Block. Insights on the kinematic scenario of Central Iran

Recent works documented Neogene to Quaternary dextral strike-slip tectonics along the Kuh-e-Sarhangi and Kuh-e-Faghan intraplate strike-slip faults at the northern edge of the Lut Block of Central Iran, previously thought to be dominated by sinistral strike-slip deformation. This work focuses on the evidence of Quaternary activity of one of these fault systems, in order to provide new spatio-temporal constraints on their role in the active regional kinematic scenario. Through geomorphological and structural investigation, integrated with Optically Stimulated Luminescence (OSL) dating of three generations of alluvial fans and fluvial terraces (at ~53, ~25 and ~6 ka), this study documents (i) the topographic inheritance of the long-term (Myr) punctuated history of fault nucleation, propagation, and exhumation along the northern edge of Lut Block; (ii) the tectonic control on drainage network evolution, pediment formation, fluvial terraces, and alluvial-fan architecture; (iii) the minimum Holocene age of Quaternary dextral strike-slip faulting; and (iv) the evidence of Late Quaternary fault-related uplift localized along the different fault strands. The documented spatial and temporal constraints on the active dextral strike-slip tectonics at the northern edge of Lut Block provided new insights on the kinematic model for active faulting in Central Iran, which has been reinterpreted in an escape tectonic scenario

Theoretical Study on Highly Active Bifunctional Metalloporphyrin Catalysts for the Coupling Reaction of Epoxides with Carbon Dioxide

Highly active bifunctional metalloporphyrin catalysts were developed for the coupling reaction of epoxides with CO2 to produce cyclic carbonates. The bifunctional catalysts have both quaternary ammonium halide groups and a metal center. To elucidate the roles of these catalytic groups, DFT calculations were performed. Control reactions using tetrabutylammonium halide as a catalyst were also investigated for comparison. In the present article, the results of our computational studies are overviewed. The computational results are consistent with the experimental data and are useful for elucidating the structure-activity relationship. The key features responsible for the high catalytic activity of the bifunctional catalysts are as follows: 1) the cooperative action of the halide anion (nucleophile) and the metal center (Lewis acid); 2) the near-attack conformation, leading to the efficient opening of the epoxide ring in the rate-determining step; and 3) the conformational change of the quaternary ammonium cation to stabilize various anionic species generated during catalysis, in addition to the robustness (thermostability) of the catalysts

Evidence of Quaternary tectonics along Río Grande valley, southern Malargüe fold and thrust belt, Mendoza, Argentina

The Malargüe fold and thrust belt is developed in the Argentinian Andes between 34° and 37° S, through the tectonic inversion of Upper Triassic and Lower Jurassic depocenters of the Neuquén Basin, with an uplift history since the Cretaceous. Evidence of Quaternary deformation has been described in the northern part of it (34–34.5°S), potentially coeval to neotectonic activity along the eastern edge of San Rafael block. To the south, compressional and extensional structures active during the Quaternary were found in the Dorso de los Chihuidos along the Agrio fold and thrust belt front (37.5–38°S). Contrastingly, the southern segment of the Malargüe fold and thrust belt between these two areas with described neotectonic activity is partially covered by Quaternary products of the Payún Matrú volcanic field, that may hide evidence of recent deformation. In this 300 km gap of neotectonic information, the landscape imprint of two individual structures aligned in the mountain front through the Río Grande valley was analyzed. New evidence of neotectonic deformation were recognized, in particular over the western slope of the Cara Cura range, expressed by faulting and folding of Quaternary deposits and lava flows. An 40Ar/39Ar age from a deformed lava flow at the flanks of an anticline in the foothills of the Cara Cura range may suggest at least an upper Pleistocene compressional tectonic activity. Longitudinal river profile analysis revealed anomalies that show some correlation with the neotectonic structures described, especially knickpoints and concavity index changes. Meanwhile normalized steepness index values showed a moderate response to recent deformation. A proposed schematic geomorphic evolution for this segment of Río Grande river is discussed to put the neotectonic activity into the context of landscape formation. All together this evidence supports the idea of an active front through the Río Grande valley during the Quaternary, coetaneous to an active broken foreland to the east in the southern Central Andes.Fil: Colavitto, Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Sagripanti, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Fennell, Lucas Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Folguera Telichevsky, Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Costa, Carlos. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Departamento de Geología; Argentin

Opioid stimulation in the ventral tegmental area facilitates the onset of maternal behavior in rats

This research investigated the effect of an increase or decrease in opioid activity in the ventral tegmental area (VTA) on the onset of maternal behavior in rats. In Experiment 1, the latency to show maternal behavior toward foster rat pups (sensitization latency) was determined in maternally naive female rats given either nothing or a unilateral intra-VTA injection of morphine sulfate (MS) (0.0, 0.01, 0.03, 0.1 or 0.3 µg), on the first three days of a 10-day period of constant exposure to pups. Rats treated with 0.03 µg MS had significantly shorter sensitization latencies than did rats treated with 0.0 µg MS, 0.01 µg MS, or receiving no treatment (higher doses of morphine produced intermediate results). The facilitating effect of intra-VTA MS on the onset of maternal behavior was blocked by pretreatment with naltrexone hydrochloride and was found to have a specific site of action in the VTA (MS injections dorsal to the VTA were ineffective). In Experiment 2, sensitization latencies were determined in periparturitional rats given a bilateral intra-VTA injection of either the opioid antagonist naltrexone methobromide (quaternary naltrexone), its vehicle, a sham injection, or left untreated 40 min after delivery of the last pup. The mothers' own pups were removed at delivery; mothers were nonmaternal at the time of testing. Quaternary naltrexone treatment produced significantly slower sensitization to foster pups than did control conditions. Total activity and pup-directed activity did not differ significantly with treatment. The results demonstrate that increased opioid activity in the VTA facilitates the onset of maternal behavior in inexperienced nonpregnant female rats, and decreased opioid activity in the VTA disrupts the rapid onset of maternal behavior at parturition

Geomorphology of the Durmitor Mountains and surrounding plateau Jezerska Površ (Montenegro)

The geomorphological map of the northeastern Durmitor Mountains and the plateau Jezerska Povrs. (1: 10,000, 47 km(2), Montenegro, Dinaric Alps) was prepared from an intensive fieldwork campaign and remote sensing analysis, and was compiled within a GIS. The basic components of the legend are (i) processes/genesis, (ii) materials, (iii) morphometry/morphography, (iv) hydrography, (v) vegetation and (vi) anthropogenic features. The geomorphological setting of the area consists of Mesozoic limestones which are physically deformed by Quaternary glacial and periglacial activity and chemically affected during interglacials. Glacial deposits on the plateau of three middle-to-late Pleistocene glacial phases are intersected by a well-developed network of palaeo meltwater channels. In the mountains, Holocene glacier retreat left behind a series of well-preserved recessional moraines. The map serves as a valuable tool for Quaternary research in the Durmitor Mountains, and also in other mountains of the Western Balkans

The chronostratigraphy of Late Pleistocene glacial and periglacial aeolian activity in the Tuktoyaktuk Coastlands, NWT, Canada

Aeolian periglacial sand deposits are common in the Tuktoyaktuk Coastlands of Western Arctic Canada. Regionally extensive and thick aeolian sand-sheet deposits have been observed in two major stratigraphic settings: within a sand unit characterized by large aeolian dune deposits; and interbedded with glaciofluvial outwash from the Laurentide Ice Sheet (LIS). Small, localized sand sheets have also been observed along the tops of sandy bluffs, within sequences of drained thermokarst lakes deposits and as an involuted veneer above buried basal ice of the LIS. On the basis of radiocarbon and optically stimulated luminescence (OSL) dates from preserved periglacial aeolian sand sheets and dunes a regional chronostratigraphy is presented which indicates that both extensive dunes and sand sheets accumulated mainly between ca 30 and 13 ka. A switch to dominantly sand-sheet aggradation at ca 14–13 ka, with sand sheets forming widely until ca 8 ka, is attributed to (a) surface armouring by glacial deposits associated with the advance of the LIS; and (b) amelioration of the climate from cold aridity. An absence of OSL dates between ca 8 and 1 ka suggests that sand sheets stabilized during much of the Holocene. Local sand-sheet aggradation during recent centuries has occurred near sandy bluffs and on the floors of drained thermokarst lakes. The OSL dates constrain the maximum extent of the LIS in the Tuktoyaktuk Coastlands to Marine Isotope Stage 2

Tertiary-Quaternary intra-plate magmatism in Europe and its relationship to mantle dynamics

Anorogenic intra-plate magmatism was widespread in Europe from early Tertiary to Recent times, extending west to east from Spain to Bulgaria, and south to north from Sicily to northern Germany. Magmatism is spatially and temporally associated with Alpine-Pyrenean collisional tectonics, the development of an extensive lithospheric rift system in the northern foreland of the Alps, and, locally, with uplift of Variscan basement massifs (Massif Central, Rhenish Massif, Bohemian Massif). The volcanic regions vary in volume from large central volcanoes (e.g. Cantal, Massif Central;Vogelsberg, northern Germany), to small isolated plugs (e.g. Urach and Hegau provinces in southern Germany). Within the Mediterranean region, the Dinarides, the Pannonian Basin and Bulgaria, anorogenic volcanism locally post-dates an earlier phase of subduction-related magmatism. The major and trace element and Sr-Nd-Pb isotope characteristics of the most primitive mafic magmatic rocks (MgO > 6 wt %) provide important constraints on the nature of the mantle source and the conditions of partial melting.. These are predominantly sodic (melilitites, nephelinites, basanites and alkali olivine basalts); however, locally, potassic magma types (olivine leucitites, leucite nephelinites) also occur. In several localities (e.g., Sicily; Vogelsberg and the Rhine Graben, Germany; Calatrava, central Spain) olivine- and quartz-tholeiites form a significant component of the magmatism. The sodic magmas were derived by variable degrees of partial melting (~ 0.5 - 5 %) within a transitional zone between garnet-peridotite and spinel-peridotite mantle facies, close to the base of the lithosphere; the potassic magma types are interpreted as partial melts of enriched domains within the lithospheric mantle. Mantle partial melting was induced by adiabatic decompression of the asthenosphere, locally in small-scale, plume-like, diapirs which appear to upwell from ~ 400 km depth

Fire, climate and the origins of agriculture: micro-charcoal records of biomass burning during the Last Glacial Interglacial Transition in Southwest Asia

This study investigates changes in climate, vegetation, wildfire and human activity in Southwest Asia during the transition to Neolithic agriculture between ca. 16 and ca. 9 ka. In order to trace the fire history of this region, we use microscopic charcoal from lake sediment sequences, and present two new records: one from south central Turkey (Akgo¨ l) and the other from the southern Levant (Hula). These are interpreted primarily as the result of regional-scale fire events, with the exception of a single large event ca. 13 ka at Akgo¨ l, which phytolith analysis shows was the result of burning of the local marsh vegetation. Comparison between these and other regional micro-charcoal, stable isotope and pollen records shows that wildfires were least frequent when the climate was cold and dry (glacial, Lateglacial Stadial) and the vegetation dominated by chenopod–Artemisia steppe, and that they became more frequent and/or bigger at times of warmer, wetter but seasonally dry climate (Lateglacial Interstadial, early Holocene). Warmer and wetter climates caused an increase in biomass availability, with woody matter appearing to provide the main fuel source in sites from the Levant, while grass fires predominated in the interior uplands of Anatolia. Southwest Asia’s grasslands reached their greatest extent during the early Holocene, and they were maintained by dry-season burning that helped to delay the spread of woodland by up to 3 ka, at the same time as Neolithic settlement became established across this grass parkland landscape. Although climatic changes appear to have acted as the principal ‘pacemaker’ for fire activity through the last glacial–interglacial climatic transition (LGIT), human actions may have amplified shifts in biomass burning. Fire regimes therefore changed markedly during this time period, and both influenced, and were influenced by, the cultural-economic transition from hunter-foraging to agriculture and village lif

Localization of Quaternary slip rates in an active rift in 10(5) years: an example from central Greece constrained by U-234-Th-230 coral dates from uplifted paleoshorelines

Mapping, dating, and modeling of paleoshorelines uplifted in the footwall of the 1981 Gulf of Corinth earthquake fault, Greece (Ms 6.9–6.7), are used to assess its slip rate history relative to other normal faults in the area and study strain localization. The 234U-230Th coral ages from Cladocora caespitosa date uplifted shoreface sediments, and paleoshorelines from glacioeustatic sea level highstands at 76, (possibly) 100, 125, 175, 200, 216, 240, and 340 ka. Uplifted Quaternary and Holocene paleoshorelines decrease in elevation toward the western tip of the fault, exhibiting larger tilt angles with age, showing that uplift is due to progressive fault slip. Since 125 ka, uplift rates varied from 0.25 to 0.52 mm/yr over a distance of 5 km away from the fault tip. Tilting was also occurring prior to 125 ka, but uplift rates were lower because the 125 ka paleoshoreline is at 77% of the elevation of the 240 ka paleoshoreline despite being nearly half its age. Comparison of paleoshoreline elevations and sedimentology with the Quaternary sea level curve shows that slip rates increased by a factor of 3.2 ± 0.2 at 175 ± 75 ka, synchronous with cessation of activity on a neighboring normal fault at 382–112 ka. We suggest that the rapid localization of up to 10–15 mm/yr of extension into the narrow gulf (∼30 km wide) resulted from synchronous fault activity on neighboring faults followed by localization rather than sequential faulting, with consequences for the mechanism controlling localization of extension

Reflections on the Use of Ecological Attributes and Traits in Quaternary Botany

There has been an upsurge of interest and research activity in trait-based approaches in ecology, biogeography, and macroecology. I discuss if this upsurge has impacted Quaternary botany (the study of plant remains preserved in sediments). I show that ecological attributes (including traits) have played and continue to play an integral part in the interpretation of Quaternary botanical data in terms of reconstructing past environments and interpreting long-term changes in plant assemblages. This use started over 120 years ago and continues to the present. It is unclear if a “new” Quaternary botany based on traits will develop because of the taxonomic limitations of much Quaternary botanical data.publishedVersio