22,095 research outputs found
The role of phase interface energy in martensitic transformations: a lattice Monte-Carlo simulation
To study martensitic phase transformation we use a micromechanical model
based on statistical mechanics. Employing lattice Monte-Carlo simulations and
realistic material properties for shape-memory alloys (SMA), we investigate the
combined influence of the external stress, temperature, and interface energy
between the austenitic and martensitic phase on the transformation kinetics and
the effective material compliance. The one-dimensional model predicts well many
features of the martensitic transformation that are observed experimentally.
Particularly, we study the influence of the interface energy on the
transformation width and the effective compliance. In perspective, the obtained
results might be helpful for the design of new SMAs for more sensitive smart
structures and more efficient damping systems.Comment: 10 pages, 3 figures, 22 reference
Differential Scanning Calorimetry (DSC) Analyses Of Superelastic And Nonsuperelastic Nickel-Titanium Orthodontic Wires
The purpose of this study was to determine the transformation temperatures for the austenitic, martensitic, and rhombohedral (R) structure phases in representative as-received commercial nitinol (NiTi) orthodontic wire alloys, to reconcile discrepancies among recent publications. Specimens were examined by differential scanning calorimetry (DSC) over a temperature range from approximately −170° C to 100° C, with a scanning rate of 10° C per minute. Two different pathways, with the intermediate R structure either absent or present, were observed for the transformation from martensitic to austenitic NiTi, whereas the reverse transformation from austenitic to martensitic NiTi always included the R structure. The enthalpy (ΔH) for the transformation from martensite to austenite ranged from 0.3 to 35 calories per gram. The lowest ΔH value for the nonsuperelastic Nitinol wire is consistent with a largely work-hardened, stable, martensitic microstructure in this product. The DSC results indicate that the transformation processes are broadly similar in superelastic, body-temperature shape-memory, and nonsuperelastic NiTi wires. Differences in bending properties for the NiTi orthodontic wires at room temperature and 37° C are due to the relative proportions of the metallurgical phases in the microstructures
Advances in martensitic transformations in Cu-based shape memory alloys achieved by in situ neutron and synchrotron X-ray diffraction methods
This article deals with the application of several X-ray and neutron diffraction methods to investigate the mechanics of a stress induced martensitic transformation in Cu-based shape memory alloy polycrystals. It puts experimental results obtained by two different research groups on different length scales into context with the mechanics of stress induced martensitic transformation in polycrystalline environment
<i>In situ</i> observation of strain and phase transformation in plastically deformed 301 austenitic stainless steel
To inform the design of superior transformation-induced plasticity (TRIP) steels, it is important to understand what happens at the microstructural length scales. In this study, strain-induced martensitic transformation is studied by in situ digital image correlation (DIC) in a scanning electron microscope. Digital image correlation at submicron length scales enables mapping of transformation strains with high confidence. These are correlated with electron backscatter diffraction (EBSD) prior to and post deformation process to get a comprehensive understanding of the strain-induced transformation mechanism. The results are compared with mathematical models for enhanced prediction of strain-induced martensitic phase transformation
Correlation between Local Structure Distortions and Martensitic Transformation in Ni-Mn-In alloys
The local structural distortions arising as a consequence of increasing Mn
content in Ni_2Mn_1+xIn_1-x (x=0, 0.3, 0.4, 0.5 and 0.6) and its effect on
martensitic transformation have been studied using Extended X-ray Absorption
Fine Structure (EXAFS) spectroscopy. Using the room temperature EXAFS at the Ni
and Mn K-edges in the above compositions, the changes associated with respect
to the local structure of these absorbing atoms are compared. It is seen that
in the alloys exhibiting martensitic transformation () there is a
significant difference between the Ni-In and Ni-Mn bond lengths even in the
austenitic phase indicating atomic volume to be the main factor in inducing
martensitic transformation in Ni-Mn-In Heusler alloys.Comment: 8 pages, 2 figure
Molecular dynamic simulation of a homogeneous bcc -> hcp transition
We have performed molecular dynamic simulations of a Martensitic bcc->hcp
transformation in a homogeneous system. The system evolves into three
Martensitic variants, sharing a common nearest neighbor vector along a bcc
direction, plus an fcc region. Nucleation occurs locally, followed by
subsequent growth. We monitor the time-dependent scattering S(q,t) during the
transformation, and find anomalous, Brillouin zone-dependent scattering similar
to that observed experimentally in a number of systems above the transformation
temperature. This scattering is shown to be related to the elastic strain
associated with the transformation, and is not directly related to the phonon
response.Comment: 11 pages plus 8 figures (GIF format); to appear in Phys. Rev.
Local atomic arrangement and martensitic transformation in NiMnIn: An EXAFS Study
Heusler alloys that undergo martensitic transformation in ferromagnetic state
are of increasing scientific and technological interest. These alloys show
large magnetic field induced strains upon martensitic phase change thus making
it a potential candidate for magneto-mechanical actuation. The crystal
structure of martensite is an important factor that affects both the magnetic
anisotropy and mechanical properties of such materials. Moreover, the local
chemical arrangement of constituent atoms is vital in determining the overall
physical properties. NiMnIn is one such ferromagnetic
shape memory alloy that displays exotic properties like large magnetoresistance
at moderate field values. In this work, we present the extended x-ray
absorption fine-structure measurements (EXAFS) on the bulk
NiMnIn which reveal the local structural change that
occurs upon phase transformation. The change in the bond lengths between
different atomic species helps in understanding the type of hybridization which
is an important factor in driving such Ni-Mn based systems towards martensitic
transformation
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