Regional Aquifer-System Analysis Program of the U.S. Geological Survey; Summary of Projects, 1978-84

The Regional Aquifer-System Analysis Program of the U.S. Geological Survey was initiated in 1978 as a result of specifications of the appropriations bill of the 95th Congress, prompted by the 1977 drought. The purpose of this program is to define the regional hydrology and geology and to establish a framework of background information of geology, hydrology, and geochemistry of the Nation \u27s important aquifer systems. This information is critically needed to develop an understanding of groundwater flow systems, and to support better groundwater resources management. As of 1984, investigations of seven regional aquifer systems were completed, nine regional aquifer systems were still being studied, and three new studies were started. This report summarizes the status of each investigation of the regional aquifer systems under the program from 1978 through 1984. The nature of the summaries differs somewhat from study to study. For those studies which either have been completed or are near completion, summaries of results are presented. For projects that are not near completion or have just been started, discussions may be brief and focus on problem issues or hydrogeologic conditions. All reports resulting from the study as of 1984 are listed at the end of each summary. A list of project chiefs and their offices is also included in the report for those who are interested in obtaining additional information. (See also W87-07313 thru W87-07335) (Author \u27s abstract

Hydrogeochemical Modeling of Saltwater Intrusion and Water Supply Augmentation in South Florida

The Biscayne Aquifer is a primary source of water supply in Southeast Florida. As a coastal aquifer, it is threatened by saltwater intrusion (SWI) when the natural groundwater flow is altered by over-pumping of groundwater. SWI is detrimental to the quality of fresh groundwater sources, making the water unfit for drinking due to mixing and reactions with aquifer minerals. Increasing water demand and complex environmental issues thus force water utilities in South Florida to sustainably manage saltwater intrusion and develop alternative water supplies (e.g., aquifer storage and recovery, ASR). The objectives of this study were to develop and use calibrated geochemical models to estimate water quality changes during saline intrusion and during ASR in south Florida. A batch-reaction model of saltwater intrusion was developed and important geochemical reactions were inferred. Additionally, a reactive transport model was developed to assess fate and transport of major ions and trace metals (Fe, As) at the Kissimmee River ASR. Finally, a cost-effective management of saltwater intrusion that involves using abstraction and recharge wells was implemented and optimized for the case of the Biscayne Aquifer. Major processes in the SWI areas were found to be mixing and dissolution-precipitation reactions with calcite and dolomite. Most of the major ions (Cl, Na, K, Mg, SO4) behaved conservatively during ASR while Ca and alkalinity were affected by carbonate reactions and cation exchange. A complex set of reactions involving thermodynamic equilibrium, kinetics and surface complexation reactions was required in the ASR model to simulate observed concentrations of Fe and As. The saltwater management model aimed at finding optimal locations and flow rates for abstraction and recharge wells. Optimal solutions (i.e., minimum total salt and total cost Pareto front) were produced for the Biscayne Aquifer for scenarios of surface recharge induced by climate change-affected precipitation. In general, abstraction at the maximum rate near the coast and artificial recharge at locations much further inland were found to be optimal. Knowledge developed herein directly supports the understanding of SWI caused by anthropogenic stressors, such as over-pumping and sea level rise, on coastal aquifers

Identification of Sources of Ground Water Salinization Using Geochemical Techniques

This report deals with saltwater sources that commonly mix and deteriorate fresh groundwater. It reviews characteristics of saltwater sources and geochemical techniques that can be used to identify these sources after mixing has occurred. The report is designed to assist investigators of saltwater problems in a step-by-step fashion. Seven major sources of saltwater are distinguished: (1) Natural saline groundwater, (2) Halite solution, (3) Seawater intrusion, (4) Oil and gas field brines, (5) Agricultural effluents, (6) Saline seep, and (7) Road salting. The geographic distribution of these sources was mapped individually and together, illustrating which ones are potential sources at any given area in the United States. In separate sections, each potential source is then discussed in detail regarding physical and chemical characteristics, examples of known techniques for identification of mixtures between freshwater and that source, and known occurrences by state. Individual geochemical parameters that are used within these techniques are presented in a separate section, followed by a discussion concerning where and how to obtain them. Also provided is a description of basic graphical and statistical methods that are used frequently in saltwater studies. An extensive list of references for further study concludes this report.Bureau of Economic Geolog

Land Use Influence on the Characteristics of Groundwater Inputs to the Great Bay Estuary, New Hampshire

This research examines the sources and factors affecting nutrient-laden groundwater discharge to the Great Bay Estuary. To further understand this relationship, examination of groundwater residence time, a review of historic land uses, and nitrate source tracking strategies were used. Seven submarine groundwater discharge (SGD) sites were selected, and groundwater monitoring networks were installed to examine the relationship between land use and groundwater quality at the discharge zones. Field activities were performed in the summer and fall of 2003 and 2004. Estuarine water intrusion in groundwater discharge samples confounded the analyses for major ion chemistry and boron isotopes. CFC-derived and modeled groundwater ages in the study area averaged 23.2 years (±15.0 years). CFC analysis enabled correlation of nitrate concentrations at the SGD sites with the historic land use coverage for the years 1974 (for most of the sites) or 1962 (SGD 58.4). Two types of correlation were made: 1) between the agricultural and residential land use for all observed nitrate concentrations in the recharge areas, and 2) correlation with the nitrate concentrations between developed and undeveloped land uses. Both statistical correlations (Kendall’s Tau and Spearman’s Rho) indicated a connection between the increase of residential land use of the last three decades with the high nitrate-bearing groundwater discharging to the Great Bay (NH). The geochemical composition of the SGD water was also investigated by using simple mixing models that attempted to explain the water chemistry characteristics of the targeted SGD sites. Based on these models it was concluded that overburden groundwater comprises 75% to 95% of the groundwater discharging at the SGD sites. A significant correlation (Tau’s, p=0.021) between nitrate-bearing groundwater and CFCderived groundwater ages was detected supporting the hypothesis that high nitrate bearing groundwater will be discharged to the Great Bay in the near future accounting for the increase of residential land use of 1990’s. Continuous monitoring of SGD sites was suggested to be included as part of the periodic environmental quality monitoring activities of the Great Bay. Long-term step-wise sampling for groundwater dating is required to develop a stronger chronological evolution of groundwater nitrate inputs. Further research should concentrate on detailing the overburden water chemistry, flow paths, and nitrogen loading characteristics

Biogeochemical Cycling And Nutrient Control Strategies For Groundwater At Stormwater Infiltration Basins

Elevated concentrations of nutrients, particularly nitrate, in groundwater and springs in Florida are a growing resource management concern. Stormwater infiltration basins, which are a common stormwater management practice in the well-drained karst terrain areas of Florida, are a potentially important source of nutrients to the groundwater system because stormwater exits the basin by only evaporation or infiltration. To better understand the biogeochemical processes integrating stormwater infiltration impacts on groundwater resources in a field-scale setting, a combination of hydrologic, soil chemistry, water chemistry, dissolved and soil gas, isotope, and microbiological data was collected from 2007 through 2010 at two stormwater infiltration basins receiving runoff from predominantly residential watersheds in north-central Florida. Substantially different biogeochemical processes affecting nitrogen fate and transport were observed beneath the two stormwater infiltration basins. Differences are related to soil textural properties that deeply link hydroclimatic conditions with soil moisture variations in a humid, subtropical climate. During 2008, shallow groundwater beneath the basin with predominantly clayey soils (median 41% silt+clay content) exhibited decreases in dissolved oxygen from 3.8 to 0.1 mg/L and decreases in nitrate-nitrogen from 2.7 mg/L to less than 0.016 mg/L, followed by manganese and iron reduction, sulfate reduction, and methanogenesis. In contrast, beneath the basin with predominantly sandy soils (median 2% silt+clay content), aerobic conditions persisted from 2007 through 2009 (dissolved oxygen of 5.0†7.8 mg/L), resulting in nitrate-nitrogen of 1.3†3.3 mg/L in shallow groundwater. Soil extractable nitrate-nitrogen was significantly lower and the copper-containing nitrite reductase gene density was significantly higher beneath the clayey basin. Differences in moisture retention capacity between fine- and coarse-textured soils resulted in median volumetric gas-phase contents of 0.04 beneath the clayey basin and 0.19 beneath the sandy basin, inhibiting surface/subsurface oxygen exchange beneath the clayey basin. Subsurface biogeochemical processes at the clayey stormwater infiltration basin were further analyzed to better understand the effects of the highly variable hydrologic conditions common in humid, subtropical climates. Cyclic variations in biogeochemical processes generally coincided with wet and dry hydroclimatic conditions. Oxidizing conditions in the subsurface persisted for about one month or less at the beginning of wet periods with dissolved oxygen and nitrate showing similar temporal patterns. Reducing conditions in the subsurface evolved during prolonged flooding of the basin. At about the same time oxygen and nitrate reduction concluded, manganese, iron, and sulfate reduction began, with the onset of methanogenesis one month later. Reducing conditions persisted up to six months, continuing into subsequent dry periods until the next major oxidizing infiltration event. Evidence of denitrification in shallow groundwater at the site is supported by median nitrate-nitrogen less than 0.016 mg/L, excess nitrogen gas up to 3 mg/L progressively enriched in delta-15N during prolonged basin flooding, and isotopically heavy delta-15N and delta-18O of nitrate (up to 25 and 15 per mil, respectively). Isotopic enrichment of newly infiltrated stormwater suggests denitrification was partially completed within two days. Soil and water chemistry data suggest a biogeochemically active zone exists in the upper 1.4 m of soil, where organic carbon was the likely electron donor supplied by organic matter in soil solids or dissolved in infiltrating stormwater. The cyclic nature of reducing conditions effectively controlled the nitrogen cycle, switching nitrogen fate beneath the basin from nitrate leaching to reduction in the shallow saturated zone. Soil beneath the sandy stormwater infiltration basin was amended using biosorption activated media (BAM) to study the effectiveness of this technology in reducing inputs of nitrogen and phosphorus to groundwater. The functionalized soil amendment BAM consists of a 1.0:1.9:4.1 mixture (by volume) of tire crumb (to increase sorption capacity), silt and clay (to increase soil moisture retention), and sand (to promote sufficient infiltration), which was applied to develop an innovative best management practice (BMP) utilizing nutrient reduction and flood control sub-basins. Construction and materials costs, excluding profit and permit fees, for the innovative BMP were about $US 65 per square meter of basin bottom. Comparison of nitrate/chloride ratios for the shallow groundwater indicate that prior to using BAM, nitrate concentrations were substantially influenced by nitrification or variations in nitrate input. In contrast, for the new basin utilizing BAM, nitrate/chloride ratios indicate minor nitrification and nitrate losses with the exception of one summer sample that indicated a 45% loss. Biogeochemical indicators (denitrifier activity derived from real-time polymerase chain reaction and variations in major ions, nutrients, dissolved and soil gases, and stable isotopes) suggest nitrate losses are primarily attributable to denitrification, whereas dissimilatory nitrate reduction to ammonium and plant uptake are minor processes. Denitrification was likely occurring intermittently in anoxic microsites in the unsaturated zone, which was enhanced by increased soil moisture within the BAM layer and resultant reductions in surface/subsurface oxygen exchange that produced conditions conducive to increased denitrifier activity. Concentrations of total dissolved phosphorus and orthophosphate were reduced by more than 70% in unsaturated zone soil water, with the largest decreases in the BAM layer where sorption was the most likely mechanism for removal. Post-BAM orthophosphate/chloride ratios for shallow groundwater indicate predominantly minor increases and decreases in orthophosphate with the exception of one summer sample that indicated a 50% loss. Differences in nutrient variations between the unsaturated zone and shallow groundwater may be the result of the intensity and duration of nutrient removal processes and mixing ratios with water that had undergone little biogeochemical transformation. In order to quantify potential processes leading to observed nitrogen losses beneath the innovative BMP, an integrated infiltration basin†nitrogen reduction (IBNR) system dynamics model was developed. Based on two simulation periods, the IBNR model indicated denitrification accounted for a loss of about one-third of the total dissolved nitrogen mass inflow and was occurring predominantly in the BAM layer. The IBNR model results in combination with the field-based biogeochemical assessment demonstrated that the innovative BMP using the functionalized soil amendment BAM is a promising passive, economical, stormwater nutrient-treatment technology. Further field- and laboratory-scale research on the long-term sustainability of nutrient losses and further elucidation of causative physicochemical and biogeochemical mechanisms would contribute to improved BAM performance and green infrastructure development in the future

Argonne National Laboratory Reports

Present concepts of disposal of low-level aqueous wastes (LLAW) that contain much of the fission-product tritium from light water reactors involve dispersal to the atmosphere or to surface streams at fuel reprocessing plants. These concepts have been challenged in recent years. Deep-well injection of low-level aqueous wastes, an alternative to biospheric dispersal, is the subject of this presentation. Many factors must be considered in assessing its feasibility, including technology, costs, environmental impact, legal and regulatory constraints, and siting. Examination of these factors indicates that the technology of deep-well injection, extensively developed for other industrial wastes, would require little innovation before application to low-level aqueous wastes. Costs would be low, of the order of magnitude of 10⁻⁴ mill/kWh. The environmental impact of normal deep-well disposal would be small, compared with dispersal to the atmosphere or to surface streams; abnormal operation would not be expected to produce catastrophic results. Geologically suitable sites are abundant in the U.S., but a well would best be co-located with the fuel-reprocessing plant where the LLAW is produced. Legal and regulatory constraints now being developed will be the most important determinants of the feasibility of applying the method

Developing new paleoenvironmental approaches for Caribbean coastal systems - case studies from Punta de Cartas and Playa Bailen, Cuba, and Little Salt Spring, Florida

Tropical latitudes play an important role in global climate as they export moisture and energy pole-ward. Recent tests of predictive climate models against Holocene paleoclimate data show discrepancies between predicted and observed values in Tropical regions. Terrestrial paleoclimate records could help resolve these discrepancies by all allowing for better understand of the sensitive ocean-atmosphere climate dynamics in the tropics and by providing additional information from a diverse source of proxies. The Caribbean is an ideal location for study as its climate is influenced by both the Atlantic and Pacific Oceans. However, there are relatively few sources of paleoclimate proxies in this region due to its archipelagic nature. If Caribbean climate is to be thoroughly investigated, additional environments and climate proxies need to be investigated. As coastal systems are ubiquitous throughout the Caribbean, they are ideal for investigation of Holocene paleoclimate in this region. However, they can be ephemeral on millennial timescales making them challenging to use in paleoclimate analysis. This dissertation discusses new methods and basins that facilitate the study of these systems. Several important contributions have been made by this thesis. (1) Core scanning XRF data, when examined with additional proxies such as foraminifera, can be used to infer shifts in regional precipitation patterns in a coastal setting. Though these methods have been used before in deep basins, this represents the first use of core scanning XRF in a littoral setting. (2) The evolution of sinkhole sedimentation is reliant on both the morphology of the sinkhole and water level within the feature. This thesis shows that coastal systems are a viable source of paleoclimate information and which can hold valuable information for reconstructing climate.ThesisMaster of Science (MSc