Studying the thermal conductivity of a deep Eocene clay formation: direct measurements vs back-analysis results

An experimental study on Ypresian clays–one of the potential deep and sedimentary clay formations in Belgium for the geological disposal of heat-emitting radioactive waste–has been undertaken to systematically study its thermal conductivity using different experimental techniques. As a first step, a new experimental setup with heat flux measurement has been used and careful pre-conditioning protocols have been followed to directly measure this thermal property. The aim of these pre-conditioning tests has been ensuring a very high degree of saturation and the closure of fissures / gaps along bedding planes before the thermal tests are run under low stress conditions. Thermal tests have shown to be particularly sensitive when the thermal conductivity is determined along a direction orthogonal to these bedding planes. The study is then complemented by using a constant volume heating cell, in which heating pulse tests have been carried out under fully saturated conditions that have been ensured with a high water back-pressure. Numerical models have been used to interpret this pulse test, to exploit all the information provided by temperature measurements and to back-analyse the thermal conductivity. Direct thermal conductivity data with the improved pre-conditioning protocol allowed obtaining results consistent with the values reported when using back-analysis in the constant volume cell. The article discusses the importance of restoring full saturation conditions, particularly on retrieval of deep sedimentary clays, which may undergo opening of fissures along bedding planes that may affect the correct determination of the thermal conductivity.Peer ReviewedPostprint (author's final draft

Elastic constants of beta-eucryptite: A density functional theory study

The five independent elastic constants of hexagonal $\beta$-eucryptite have been determined using density functional theory (DFT) total energy calculations. The calculated values agree well, to within 15%, with the experimental data. Using the calculated elastic constants, the linear compressibility of $\beta$-eucryptite parallel to the c-axis, $\chi_c$, and perpendicular to it, $\chi_a$, have been evaluated. These values are in close agreement to those obtained from experimentally known elastic constants, but are in contradiction to the direct measurements based on a three-terminal technique. The calculated compressibility parallel to the c-axis was found to positive as opposed to the negative value obtained by direct measurements. We have demonstrated that $\chi_c$ must be positive and discussed the implications of a positive $\chi_c$ in the context of explaining the negative bulk thermal expansion of $\beta$-eucryptite.Comment: 3 eps figures, submitted for publicatio

Photoheliograph study for the Apollo telescope mount

Photoheliograph study for Apollo telescope moun

Method of determining the thermal deformations of astronomical mirrors

Procedures are given for calculating thermal fields and associated thermal deformations in astronomical mirrors. A technique is described for thermal strain simulation when complex thermal fields develop in astronomical mirrors. Thermal strains in pyroceramic, quartz and pyrex mirrors can be effectively determined at temperatures ranging from -70 to 150 C by this technique

The preparation and properties of a glass-ceramic with an aligned microstructure

The work described in this thesis was performed on glass-ceramics in which a random arrangement of crystals is grown as a dispersed phase. The physical properties of this material are isotropic. The technique of hot extrusion has been used to produce a material with an aligned crystal microstructure in a Li₂O-SiO₂ glass-ceramic. The extruded material consists of a glass matrix and two crystalline phases; one of these phases is aligned morphologically and crystallographically parallel to the extrusion axis. The microstructure of this extruded material was analysed statistically in terms of the volume fraction of crystalline phases, the mean crystal- crystal spacing and the distribution function of the number of crystals N(Ɵ), making an angle Ɵ with a reference direction. Control specimens of the same composition heat-treated at the same temperature and for the same time as the extruded samples were also analysed statistically. The following physical properties were measured on the control and extruded specimens: (i) the coefficient of thermal expansion (ii) Young's modulus, rupture strength and microhardness (iii) Resistivity, dielectric constant and loss tangent. In the case of the extruded samples these measurements were made in directions parallel and perpendicular to the extrusion axis; the coefficient of thermal expansion, the mechanical properties and the resistivity were found to be anisotropic for these specimens

Characterization of a CCD array for Bragg spectroscopy

The average pixel distance as well as the relative orientation of an array of 6 CCD detectors have been measured with accuracies of about 0.5 nm and 50 $\mu$rad, respectively. Such a precision satisfies the needs of modern crystal spectroscopy experiments in the field of exotic atoms and highly charged ions. Two different measurements have been performed by illuminating masks in front of the detector array by remote sources of radiation. In one case, an aluminum mask was irradiated with X-rays and in a second attempt, a nanometric quartz wafer was illuminated by a light bulb. Both methods gave consistent results with a smaller error for the optical method. In addition, the thermal expansion of the CCD detectors was characterized between -105 C and -40 C.Comment: Submitted to Review of Scientific Instrument

Coupled thermo-hydro-mechanical behaviour of a deep clay

An experimental study on Ypresian clays –one of the potential deep formations in Belgium for the geological disposal of heat-emitting radioactive waste– was undertaken to systematically study its thermal properties and coupled hydro-mechanical response during fast heating pulse tests. An accurate characterisation of the thermal properties is required for assessing the near-field perturbations around disposal galleries that the sedimentary host rock formation will undergo. A new experimental cell adapted to apply the high in situ stresses and with thermal flux sensors was used to directly measure the thermal conductivity at different sample orientations (heat flux orthogonal and parallel to bedding planes). A clear influence of the degree of saturation – despite being close to saturation – and anisotropic features on thermal conductivity have been detected. The study was complemented by performing fast heating pulse tests under constant volume on a new and fully-instrumented axisymmetric cell. The cell allowed recording the pore pressure build-up and dissipation along a heating pulse and under water-undrained conditions.Postprint (published version

Investigation of a liquid-fed water resistojet plume

Measurements of mass flux and flow angle were taken throughout the forward flow region of the exhaust of a liquid-fed water resistojet using a quartz crystal microbalance (QCM). The resistojet operated at a mass flow rate of 0.1 g/s with a power input of 330 Watts. Measured values were compared to theoretical predictions obtained by employing a source flow approximation. Excellent agreement between predicted and measured mass flux values was attained; however, this agreement was highly dependent on knowledge of nozzle flow conditions. Measurements of the temperature at which the exhaust condensed on the QCM were obtained as a function of incident mass flux

Interference of a first-order transition with the formation of a spin-Peierls state in alpha'-NaV2O5?

We present results of high-resolution thermal-expansion and specific-heat measurements on single crystalline alpha'-NaV2O5. We find clear evidence for two almost degenerate phase transitions associated with the formation of the dimerized state around 33K: A sharp first-order transition at T1=(33+-0.1)K slightly below the onset of a second-order transition at T2onset around (34+-0.1)K. The latter is accompanied by pronounced spontaneous strains. Our results are consistent with a structural transformation at T1 induced by the incipient spin-Peierls (SP) order parameter above T2=TSP.Comment: 5 pages, 7 figure

Investigation of single crystal ferrite thin films

Materials suitable for use in magnetic bubble domain memories were developed for aerospace applications. Practical techniques for the preparation of such materials in forms required for fabrication of computer memory devices were considered. The materials studied were epitaxial films of various compositions of the gallium-substituted yttrium gadolinium iron garnet system. The major emphasis was to determine their bubble properties and the conditions necessary for growing uncracked, high quality films