Durability Studies of Solar Reflectors Used in Concentrating Solar Thermal Technologies under Corrosive Sulfurous Atmospheres

Concentrating solar thermal (CST) technologies are a feasible and promising option to tackle worldwide energy problems. These solar facilities are sometimes located near industrial sites, where their main components—including concentrating solar reflectors—are prone to significant degradation caused by corrosive agents, especially in the presence of sulfurous atmospheres such as H2S and SO2. This paper focuses on analyzing the influence of sulfurous atmospheres on the durability of reflector materials used in CST technologies. To this end, accelerated aging tests were performed on the most commonly used materials found in solar reflectors (i.e., thick silvered glass and aluminum-based reflectors) by applying the same concentrations of H2S and SO2 under the same conditions of temperature and relative humidity. The results showed that the solar reflectors based on a silver reflective layer are significantly corroded by H2S atmospheres—several corrosion defects were found in the samples tested. However, those based on aluminum were barely affected by sulfurous environments in the conditions tested. Nonetheless, the study suggests that both reflector types are suitable candidates, depending on the purpose of the CST technology in question and the specific environmental conditions

Acetic and formic acids emitted from wood samples and their effect on selected materials in museum environments

The concentrations of acetic acid and formic acid vapours emitted by a number of wood samples held in sealed environments were measured to assess differences between hardwood and softwood species. Three cases studies are reported where sodium formate, lead formate and acetate-based efflorescences were identified on glass, lead and calcareous artefacts held in heritage environments with elevated acetic acid and formic acid vapours. Simulated experiments were undertaken to assess the affect of formic acid vapour on limestone, egg shell, copper, lead and brass coupons and it was confirmed that porous limestone preferentially scavenged formic acid vapours from air

How to preserve lead artifacts for future generations

This paper discusses the advantages and disadvantages of different conservation treatments that have been developed over the years to protect the lead cultural heritage. The chemical and aesthetic points of view are looked at

Air pollutant levels in air-conditioned and naturally ventilated museums: a pilot study

An air-conditioned and a naturally ventilated museum in a highly polluted part of London were compared for effectiveness of pollution control. Nitrogen dioxide, sulphur dioxide and hydrogen sulphide concentrations were measured inside and outside using diffusion tubes. Airborne particles were measured using a Grimm laser counting device. It was found that the benefits normally attributed to air-conditioning with filtration were not as great as might be thought. Only nitrogen dioxide and particle levels were significantly lower in the air-conditioned museum than in the naturally ventilated museum