Equilibrium Chemical Engines

An equilibrium reversible cycle with a certain engine to transduce the energy of any chemical reaction into mechanical energy is proposed. The efficiency for chemical energy transduction is also defined so as to be compared with Carnot efficiency. Relevance to the study of protein motors is discussed. KEYWORDS: Chemical thermodynamics, Engine, Efficiency, Molecular machine.Comment: 5 pages, late

Equilibrium relationships for non-equilibrium chemical dependencies

In contrast to common opinion, it is shown that equilibrium constants determine the time-dependent behavior of particular ratios of concentrations for any system of reversible first-order reactions. Indeed, some special ratios actually coincide with the equilibrium constant at any moment in time. This is established for batch reactors, and similar relations hold for steady-state plug-flow reactors, replacing astronomic time by residence time. Such relationships can be termed time invariants of chemical kinetics

Coannihilation without chemical equilibrium

Chemical equilibrium is a commonly made assumption in the freeze-out calculation of coannihilating dark matter. We explore the possible failure of this assumption and find a new conversion-driven freeze-out mechanism. Considering a representative simplified model inspired by supersymmetry with a neutralino- and sbottom-like particle we find regions in parameter space with very small couplings accommodating the measured relic density. In this region freeze-out takes place out of chemical equilibrium and dark matter self-annihilation is thoroughly inefficient. The relic density is governed primarily by the size of the conversion terms in the Boltzmann equations. Due to the small dark matter coupling the parameter region is immune to direct detection but predicts an interesting signature of disappearing tracks or displaced vertices at the LHC. Unlike freeze-in or superWIMP scenarios, conversion-driven freeze-out is not sensitive to the initial conditions at the end of reheating.Comment: 12 pages + references, 10 figures; v2: Discussion of kinetic equilibrium extended, matches published versio

On chemical equilibrium in nuclear collisions

The data on average hadron multiplicities in central A+A collisions measured at CERN SPS are analysed with the ideal hadron gas model. It is shown that the full chemical equilibrium version of the model fails to describe the experimental results. The agreement of the data with the off-equilibrium version allowing for partial strangeness saturation is significantly better. The freeze-out temperature of about 180 MeV seems to be independent of the system size (from S+S to Pb+Pb) and in agreement with that extracted in e+e-, pp and p{\bar p} collisions. The strangeness suppression is discussed at both hadron and valence quark level. It is found that the hadronic strangeness saturation factor gamma_S increases from about 0.45 for pp interactions to about 0.7 for central A+A collisions with no significant change from S+S to Pb+Pb collisions. The quark strangeness suppression factor lambda_S is found to be about 0.2 for elementary collisions and about 0.4 for heavy ion collisions independently of collision energy and type of colliding syste

Aerotherm chemical equilibrium (ACE) computer program

Computer code was developed for calculating chemical quantities and qualities in equilibrium