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oaioai:scholarworks.smith.edu:chm_facpubs-1081

One-Pot Anti-Markovnikov Hydroamination of Unactivated Alkenes by Hydrozirconation and Amination

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Publication date
6 September 2013
Publisher
Smith ScholarWorks
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    Abstract

    A one-pot anti-Markovnikov hydroamination of alkenes is reported. The synthesis of primary and secondary amines from unactivated olefins was accomplished in the presence of a variety of functional groups. Hydrozirconation, followed by amination with nitrogen electrophiles, provides exclusive anti-Markovnikov selectivity. Most products are isolated in high yields without the use of column chromatography

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    Last time updated on 21/10/2023

    This paper was published in Smith College: Smith ScholarWorks.

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