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Bistability Loss as a Key Feature in Azobenzene (Non-)Switching on Metal Surfaces

Abstract

Coinage metal adsorbed azobenzene is investigated as a prototypical molecular switch. Switching capabilities are not just lost owing to excited-state quenching, but also because of changes in the ground-state energetics (see graph; black=gas phase, gray=Ag(111), yellow=Au(111)). Electron-demanding coadsorbates are suggested as a strategy to regain the switching function

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MPG.PuRe

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Last time updated on 26/08/2022

This paper was published in MPG.PuRe.

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