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M<sub>12</sub>L<sub>24</sub> spherical complexes incorporating
24 free pyridine rings on their interior or exterior surfaces were
synthesized via the self-assembly of tridentate tris(pyridine) ligands
with Pd<sup>2+</sup> ions. Coordination of secondary metal ions in
the interior of the spherical framework was achieved through interactions
of 24 Ag<sup>+</sup> ions with the free endo pyridine rings
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