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Metal–Organic Proximity in a Synthetic Pocket
Abstract
Proximity between a noninteractive organic substrate and a transition metal (<i>trans</i>-MCl<sub>2</sub>(PEt<sub>3</sub>)<sub>2</sub>; M = Pd or Pt) is achieved by their co-encapsulation within a synthetic cage, as revealed by X-ray crystallographic analysis and NOESY experiments. Through co-encapsulation with a Pd(II) complex, a terminal alkyne was activated within the cage to give a σ-alkynylpalladium complex- Text
- Journal contribution
- Medicine
- Cell Biology
- Molecular Biology
- Evolutionary Biology
- Space Science
- Environmental Sciences not elsewhere classified
- Chemical Sciences not elsewhere classified
- Pt
- analysis
- Pd
- NOESY experiments
- Synthetic PocketProximity
- transition metal
- cage
- terminal alkyne
- substrate
- alkynylpalladium
- noninteractive
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Last time updated on 12/02/2018
This paper was published in The Francis Crick Institute.
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