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oaioai:figshare.com:article/2196193

Iso-Selective Ring-Opening Polymerization of <i>rac</i>-Lactide Catalyzed by Crown Ether Complexes of Sodium and Potassium Naphthalenolates

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Publication date
2015
Publisher
Doi

    Abstract

    Two crown ether complexes of sodium and potassium naphthalenolates were synthesized and entirely characterized. The two complexes can iso-selectively catalyze the ring-opening polymerization (ROP) of <i>rac</i>-lactide at room temperature and afford polylactides with desired molecular weights and narrow PDIs; the best isotacticity (<i>P</i><sub>m</sub>) achieved was 0.73

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    The Francis Crick Institute

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    Last time updated on 12/02/2018

    This paper was published in The Francis Crick Institute.

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