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Hydroxyphosphinylation Reaction of 3‑Cyclopropylideneprop-2-en-1-ones via C–P σ‑Bond Cleavage
Abstract
An unexpected hydroxyphosphinylation of 3-cyclopropylideneprop-2-en-1-ones with phosphines has been observed. This method provides a unique regio- and stereoselective synthesis of highly functionalized 1-dialkylphinyl-3-oxo-(1<i>Z</i>)-alkenyl cyclopropanols with important potentials. The reaction displays an unusual mechanistic featurea highly selective cleavage of C–P σ bonds in phosphines- Dataset
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- functionalized
- Hydroxyphosphinylation Reaction
- stereoselective synthesis
- potential
- CleavageAn
- phosphine
- method
- cleavage
- regio
- Cyclopropylideneprop
- reaction displays
- cyclopropanol
- Bond
- dialkylphinyl
- hydroxyphosphinylation
- cyclopropylideneprop
- bond
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Last time updated on 12/02/2018
This paper was published in The Francis Crick Institute.
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