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NiS<sub>2</sub> nanoparticles and nanocomposites of NiS<sub>2</sub> with
reduced graphene oxide (NiS<sub>2</sub>@RGO) have been successfully
prepared via a facile hydrothermal reaction of nickel ions and sulfur
source in the absence or presence of graphene oxide. NiS<sub>2</sub>@RGO nanocomposites exhibit excellent electrocatalytic performance
for reduction of triiodide, owing to the improved conductivity and
positive synergetic effect between NiS<sub>2</sub> and RGO. As a consequence,
the dye-sensitized solar cell with the NiS<sub>2</sub>@RGO counter
electrode (CE) produces a power conversion efficiency of 8.55%, which
is higher than that (7.02%) for the DSSC with the NiS<sub>2</sub> CE,
higher than that (3.14%) for the DSSC with the RGO CE, and also higher
than that (8.15%) for the DSSC with the reference Pt CE under the
same conditions
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