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Access to C(sp<sup>3</sup>)–C(sp<sup>2</sup>) and C(sp<sup>2</sup>)–C(sp<sup>2</sup>) Bond Formation via Sequential Intermolecular Carbopalladation of Multiple Carbon–Carbon Bonds
Abstract
A synthetic strategy of 4-benzyl-substituted 1,3-butadiene derivatives through Pd-catalyzed three-component coupling reaction of benzyl chlorides, alkynes, and monosubstituted alkenes is described. This tandem coupling reaction forms a C(sp<sup>3</sup>)–C(sp<sup>2</sup>) bond and a C(sp<sup>2</sup>)–C(sp<sup>2</sup>) bond sequentially in a single-step operation- Text
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- Biophysics
- Biochemistry
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- butadiene
- benzyl chlorides
- Access
- sequentially
- BondsA
- Multiple
- reaction forms
- strategy
- Formation
- derivative
- Bond
- monosubstituted alkenes
- tandem
- Sequential Intermolecular Carbopalladation
- alkyne
- bond