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A Polyoxometalate–Cyanometalate Multilayered Coordination Network
Abstract
The reaction of the ε-Keggin polyoxometalate (POM) [PMo12O36(OH)4{La(H2O)4}4]5+ with FeII(CN)64– under typical bench conditions at room temperature and ambient pressure has afforded the novel [ε-PMo12O37(OH)3{La(H2O)5(Fe(CN)6)0.25}4] network, which exhibits a three-dimensional multilayered structure. The compound has been fully characterized by synchrotron-radiation X-ray crystallography, IR spectroscopy, elemental analysis, and thermogravimetric analysis. This coordination network constitutes the first example of a cyanometalate bonded to a POM unit- Text
- Journal contribution
- Biophysics
- Biochemistry
- Marine Biology
- Mental Health
- Environmental Sciences not elsewhere classified
- Biological Sciences not elsewhere classified
- Chemical Sciences not elsewhere classified
- Physical Sciences not elsewhere classified
- exhibit
- Multilayered
- compound
- POM unit
- polyoxometalate
- thermogravimetric analysis
- cyanometalate
- PMo 12O
- crystallography
- NetworkThe
- coordination network
- FeII
- ambient pressure
- bench conditions
- IR spectroscopy
- room temperature
- Polyoxometalate
- Keggin
- Coordination
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Last time updated on 12/02/2018
This paper was published in The Francis Crick Institute.
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