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textjournal article
oaioai:figshare.com:article/3444764

AgBF<sub>4</sub> catalyzed regio- and stereoselective synthesis of <i>trans</i> α-vinyl-β-amino esters via asymmetric addition of siyl dienolate to sulfinylimines

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Publication date
1 July 2016
Publisher
Doi

    Abstract

    AgBF4 catalyzed Mannich-type reactions of siyl dienolate with chiral aryl-substituted (S)-N-tert-butanesulfinylimines has been developed. A class of chiral trans α-vinyl-β-amino esters was obtained in moderate to excellent yields (up to 93%), good diastereoselectiveties (up to 92:8 dr), and complete α-site regioselectivity.</p

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    The Francis Crick Institute

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    Last time updated on 12/02/2018

    This paper was published in The Francis Crick Institute.

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