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Base-Promoted Synthesis of <i>N</i>‑Substituted 1,2,3-Triazoles via Enaminone–Azide Cycloaddition Involving Regitz Diazo Transfer
Abstract
The domino reactions between NH-based secondary enaminones and tosyl azide have been developed for the synthesis of various <i>N</i>-substituted 1,2,3-triazoles by employing <i>t</i>-BuONa as the base promoter. Through a key Regitz diazo-transfer process with tosyl azide, the reactions proceed efficiently at room temperature with good substrate tolerance- Text
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- domino
- Enaminone
- NH-based
- Triazole
- triazole
- Substituted
- enaminone
- Synthesi
- BuONa
- Base-Promoted
- Regitz diazo-transfer process
- substrate
- tolerance
- promoter
- tosyl azide
- synthesis
- Cycloaddition
- Regitz Diazo Transfer
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Last time updated on 12/02/2018
This paper was published in The Francis Crick Institute.
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