oaioai:centaur.reading.ac.uk:18735

In situ formation of ligand 2,2'-[(E)-diazene-1,2-diyldicarbonothioyl]diphenol and structural characterization of its binuclear rhodium(V) complex containing RhO2+

Authors
Publication date
1 January 2010
Publisher
The Royal Society of Chemistry
Doi

    Abstract

    The ligand 2,2'-[(E)-diazene-1,2-diyldicarbonothioyl]diphenol has been synthesised in situ by aerial oxidation of o-hydroxythiobenzhydrazide [H(htbh)] in presence of rhodium(III) in DMSO. Each ligand binds two RhO2+ ions through its N and S atoms and the O atom of its deprotonated hydroxy group. Each RhO2+ contains two cis-Rh = O bonds. The sixth coordination site of each rhodium(v) is occupied by the O of DMSO

      Similar works

      Full text

      thumbnail-image

      Central Archive at the University of Reading

      redirect
      oaioai:centaur.reading.ac.uk:1873...
      Last time updated on 01/07/2012

      This paper was published in Central Archive at the University of Reading.

      Having an issue?

      Is data on this page outdated, violates copyrights or anything else? Report the problem now and we will take corresponding actions after reviewing your request.