Location of Repository

Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN 3]copper(II)

By Long Li, Kai-Sheng Diao, Yu-Qiu Ding, Jin-Niu Tang and Dai-Yin Wang

Abstract

In the title complex, [CuCl2(C10H7N3S)(C2H5OH)], the CuII ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand, one O atom from an ethanol mol­ecule and two Cl atoms. In the crystal, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the complex mol­ecules into a layer parallel to (100). π–π inter­actions between the thia­zole rings are observed [centroid–centroid distance = 3.749 (3) Å]

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3343892
Provided by: PubMed Central
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://www.pubmedcentral.nih.g... (external link)
  • Suggested articles

    Preview

    Citations

    1. (2012). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) xy z U iso*/Ueq
    2. (1995). metal-organic compounds m508 Li et al. doi:10.1107/S1600536812013037 Acta Cryst.

    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.