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Dichlorido(ethanol-κO)[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN 3]copper(II)

By Long Li, Kai-Sheng Diao, Yu-Qiu Ding, Jin-Niu Tang and Dai-Yin Wang


In the title complex, [CuCl2(C10H7N3S)(C2H5OH)], the CuII ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligand, one O atom from an ethanol mol­ecule and two Cl atoms. In the crystal, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the complex mol­ecules into a layer parallel to (100). π–π inter­actions between the thia­zole rings are observed [centroid–centroid distance = 3.749 (3) Å]

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3343892
Provided by: PubMed Central
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