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2-Allylphenyl glycosides as complementary building blocks for oligosaccharide and glycoconjugate synthesis

By Hemali D Premathilake and Alexei V Demchenko

Abstract

The O-allylphenyl (AP) anomeric moiety was investigated as a new leaving group that can be activated for chemical glycosylation under a variety of conditions, through both direct and remote pathways. Differentiation between the two activation pathways was achieved in a mechanistic study. The orthogonal-type activation of the AP moiety along with common thioglycosides allows for the execution of efficient oligosaccharide assembly

Topics: Full Research Paper
Publisher: Beilstein-Institut
OAI identifier: oai:pubmedcentral.nih.gov:3343285
Provided by: PubMed Central
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