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Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ3 N 1,N 2,N 6]zinc dioxane sesquisolvate

By Hadi D. Arman, Pavel Poplaukhin and Edward R. T. Tiekink


The asymmetric unit of the title compound, [Zn(C4H8NOS2)2(C18H12N6)]·1.5C4H8O2, comprises a Zn-containing mol­ecule and one and a half dioxane mol­ecules as one of the solvent mol­ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N3S2 donor set is defined by two monodentate dithio­carbamate ligands and two pyridine and one triazine N atom from the tridentate triazine ligand. Mol­ecules are connected into a supra­molecular array via O—H⋯S and O—H⋯N hydrogen bonds. These stack along the b axis and the solvent mol­ecules reside in the channels thus formed

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
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Provided by: PubMed Central

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