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cis-Dichloridobis[tris­(2-methyl­phen­oxy)phosphane-κP]palladium(II)

By Izabela Błaszczyk, Anna M. Trzeciak and Andrzej Gniewek

Abstract

In the title compound, [PdCl2(C21H21O3P)2], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol­ecules are linked by weak C—H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking inter­actions between the aromatic rings [shortest centroid–centroid distance = 3.758 (4) Å]

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3297231
Provided by: PubMed Central
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    Citations

    1. (2001). 79, 752–759. metal-organic compounds Acta Cryst.
    2. (1999). crystal structure, the molecules of the title complex are linked by a few weak hydrogen interactions of the C— H···Cl type (Desiraju & Steiner,
    3. (2012). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) xyz U iso*/Ueq Pd
    4. (1999). The Weak Hydrogen Bond in Structural Chemistry and Biology.

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