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Dichlorido{1-[N-(5-chloro-2-oxidophen­yl)carboximido­yl]naphthalen-2-olato-κ3 O,N,O′}(methanol-κO)tin(IV)

By Gholam Hossein Shahverdizadeh, Seik Weng Ng, Edward R. T. Tiekink and Babak Mirtamizdoust

Abstract

In the title complex, [Sn(C17H10ClNO2)Cl2(CH3OH)], the SnIV atom features a distorted octa­hedral geometry defined by the O,N,O′-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supra­molecular helical chains along [100], mediated by O—H⋯O hydrogen bonds, feature in the crystal packing. Chains are linked by C—H⋯O, C—H⋯Cl and π–π [centroid–centroid distance = 3.598 (2) Å] inter­actions

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3297216
Provided by: PubMed Central
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