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2,4,5-Trichloro­anilinium perchlorate 18-crown-6 clathrate

By Jie Xu

Abstract

In the title compound, C6H5Cl3N+·ClO4 −·C12H24O6, the perchlorate anion is disordered over two orientations in a 0.666 (17):0.334 (17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N—H⋯(O,O) hydrogen bonds to generate a supra­molecular complex. The macrocycle has approximate D 3d local symmetry

Topics: Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3295508
Provided by: PubMed Central

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Citations

  1. (2008). Acta Cryst. A64, 112–122. organic compounds Acta Cryst.
  2. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) xyzU iso*/Ueq Occ.
  3. (2008). The ClO4 - anion is disordered over sites and refined using the PART instruction in

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