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4-Methyl­anilinium perchlorate 18-crown-6 clathrate

By Yu-Feng Wang


In the title compound, C7H10N+·ClO4 −·C12H24O6, the 4-methyl­anilinium cation inter­acts with an 18-crown-6 mol­ecule forming a rotator–stator-like structure through bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°

Topics: Organic Papers
Publisher: International Union of Crystallography
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Provided by: PubMed Central

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